二甲酸

This design is low stretch of 30,000 tons of high-strength type polyester production workshop after preliminary design, high low stretch of polyester staple fiber dosage is in the biggest species, it is PTA or dimethyl terephthalic acid and glycol as raw materials via esterification or the ester exchange reaction and condensation of terephthalic acid polymer fibre - together into glycol, this design USES Germany JiMa process, high scientific and technological content, is a kind of high strength, good elasticity, and heat resistance, good abrasion resistance, corrosion resistant polyester.

帮忙把涤纶论文绪论翻译成英语，要求不用翻译软件，可以用软件查单词本设计是"年产30000吨高强低伸型涤纶短纤维后加工生产车间初步工艺设计"，高强低伸型涤纶短纤维是涤纶短纤维中用量最大的品种，它是以精对苯二甲酸或对苯二甲酸二甲酯和乙二醇为原料经酯化或酯交换和缩聚反应而制得的成纤高聚物——聚对苯二甲酸乙二醇酯，本设计采用德国吉玛工艺，科技含量较高，是一种强度高、弹性好、耐热性好、耐磨性好、耐腐蚀的涤纶短纤维。

The method was based on the aromatic hydroxylation of terephthalate by hydroxyl radical, produced from the homolysis of peroxynitrite in weak acid media, to yield a highly fluorescent product, 2-hydroxy-terephthalate, which was then detected fluorimetrically.

具体做法是将ONOO〓在pH 5.0的缓冲液中转化为其共轭酸ONOOH，而ONOOH本身不稳定，均裂生成·OH，·OH进攻对苯二甲酸生成强荧光产物2-羟基对苯二甲酸，利用荧光分析法测定2-羟基对苯二甲酸，从而间接确定ONOO〓的含量。

The invention relates to a process for producing polyethylene terephthalate 1, 3-propanediol, which comprises the following steps: using titanic acid ester as major catalyst, using germanium compounds and cobalt compounds as synergic catalyst, conducting esterification reaction for poly terephthalic acid and 1, 3-propanediol according to the molar 1:1.05-2.2 under the nitrogen pressure of 0.1-0.4MPa and 230-265 DEG C, or conducting ester exchanging reaction for poly terephthalic acid and 1, 3-propanediol according to the molar ratio 1:1.8-2.2 in 160-220 DEG C, decompressing reaction to high vacuum 10-150Pa, wherein the final temperature of reaction is 265-275 DEG C, recovering to normal pressure with nitrogen to obtain the PTT product.

本发明涉及一种生产聚对苯二甲酸1，3-丙二醇酯的方法，采用以钛酸酯为主催化剂，锗化合物和钴化合物为协同催化剂，对苯二甲酸二甲酯和1，3-丙二醇按摩尔1∶1.05-2.2，在0.1-0.4MPa氮气压力和230-265℃下进行酯化反应，或对苯二甲酸二甲酯和1，3-丙二醇按摩尔比1∶1.8-2.2，在160-220℃进行酯交换反应，将反应减压至高真空10-150Pa，反应终温在265-275℃，用氮气恢复到常压，得到本PTT产品；大大缩短了反应时间，直接聚合制备特性粘度在0.7-1.05dL/g的PTT切片，使反应产物色相良好，PTT产品可用于纤维加工及工程塑料领域。

The invention relates to a preparation process for synthesizing polyethylene terephthalate 1, 3- terephthalate catalyst, which comprises adding titanic acid ester, germanium compounds and cobalt compound into liquid dispersed phase of organic solution, wherein the total weight concentration is 4-10%, and preparing the catalyst through mechanical stirring or ultrasonic wave mixed ligand for 10-60 minutes in 0-120 DEG C, wherein the adding content of titanic acid ester, germanium compounds and cobalt compound are respectively 200-500ppm, 50-300ppm and 100-400ppm of reaction monomer mass of terephthalic acid or dimethyl terephthalate.

本发明涉及一种合成聚对苯二甲酸1，3-丙二醇酯催化剂的制备方法，将钛酸酯、锗化合物和钴化合物加入到有机溶剂的液体分散相中，总重量浓度为4～10％，在0-120℃通过机械搅拌或超声波混配10-60min制得；钛酸酯、锗化合物和钴化合物加入量分别是对苯二甲酸或对苯二甲酸二甲酯反应单体质量的200-500ppm、50-300ppm、100-400ppm；用此催化剂制备PTT产品，酯化和缩聚反应时间相对于单独使用钛酸四丁酯缩短了30-60min，产品特性粘数0.70-1.05dL/g，色相b值在2-6之间，切片可用于加工新型合成纤维及工程塑料产品。

As compared to isop, the coexistence of electron-donating -OH,-C(CH_3_3 or electron-withdrawing groups (-NO_2) groups in the dicarboxylate derivatives has a significant effect on the molecular self-assembly.

同间苯二甲酸相比较，含有取代基的5-羟基间苯二甲酸、5-硝基间苯二甲酸和5-叔丁基间苯二甲酸在一定程度上影响着配位聚合物的自组装。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸；再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯；以氟化钾为氟化剂，环丁砜为溶剂置换氟化，再与甲醇酯化得到四氟对苯二甲酸甲酯；以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇；以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物；在乙醇溶液中经镁粉还原得到4-甲基-2，3，5，6-四氟苄醇；甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯，总收率达43.6%。

The tray continuous desiccating system for drying the compound was devised based on analysis of the properties of 5-sodiosulfoisophthalic acid dimethylester before and after drying, and the structure, working principle, technical process and features of the desiccating system and its applications was introduced. From the comparison of efficiency, energy consumption, continuous operation and final product quality, the tray continuous desiccator was better in desiccation of 5-sodiosulfoisophthalic acid dimeth...

摘 要：通过对间苯二甲酸二甲酯-5-磺酸钠干燥前后物料性质的分析，提出了应用于间苯二甲酸二甲酯-5-磺酸钠干燥的盘式连续干燥系统，介绍了这种干燥设备的结构、工作原理，阐述了其工艺流程及工作特点，分析了这种干燥形式的优势及应用领域，并通过与另外一种干燥器-旋转闪蒸干燥器在工作效率、能耗、操作的连续性及干燥后产品的质量等方面的比较，表明了在间苯二甲酸二甲酯-5-磺酸钠干燥作业中这种干燥器是干燥设备的适宜选择。

By utilizing three benezenemulticarboxylate derivatives (H2chdc, H2aip, NaH2sip), we obtain 12 coordination polymers. Especially, compelexes 1 and 2 are based on one-dimensional ···OHInOHIn···chains as building units, while complex 3 is based on double four-ring [In8(μ2-O)4(μ2-H2O)8]16+, complex 4 is based on trinuclear In3(μ3-O)(CO2)6, complexes 11 and 12 are both based on nested bistranded helices.

选择了三类取代苯羧酸配体： 2，5-二羟基-1，4-对苯二甲酸(2，5-H2chdc)； 5-氨基间苯二甲酸(5-H2aip)； 5-磺酸基间苯二甲酸钠盐(5-NaH2sip)和InCl3反应合成了十二个配位化合物：其中1、2以···OHInOHIn···链为构筑单元， 3以双四元环[In8(μ2-O)4(μ2-H2O)8]16+为构筑单元，4以棱柱状三核铟In3(μ3-O)(CO2)6为构筑单元，而11、12以嵌套的双股螺旋链为构筑单元。

Phthalic acid esters are widely used in the many fields of industry. So many countries including China have come to pay attention to them and make up the codes for limiting the content in some products such as textile. By combining international codes, the thesis selects coating and textile that have close relative with people as objections. The research results are as follows:1. The thesis has established the textiles preparation method by a series of experimentations such as extraction solvent, extraction time, solid-phase extraction. The average recoveries of eleven phthalates are from 80.30% to 98.00%, and the relative standard deviations from 0.59% to 2.56%, the results show that this method is accurate and credible.2. The thesis set up the simultaneous determination of benzene, toluene, xylenes and phthalates in coatings.

邻苯二甲酸酯类化合物被广泛地应用在工业领域的各个方面，国际上已经开始重视邻苯二甲酸酯作为一种内分泌干扰素的危害性，对在一些产品中的用量作出了限制，但没有具体的分析测定方法，本论文结合国际法规选择了与人们生活密切相关的涂料和纺织品来研究其中邻苯二甲酸酯类环境激素的测定方法，研究内容如下：(1)通过对提取溶剂、提取方式、提取时间的选择实验以及固相萃取的一系列条件实验，首次建立了纺织品中测定邻苯二甲酸酯类环境激素的前处理方法，并对分析方法作了准确度、精密度验证。

The European Council for Plasticisers and Intermediates has rejected suggestions made by NGOs last week that three further phthalates DINP, DIDP and DNOP should be added to the REACH Candidate List, alongside the three - DEHP, DBP and BBP - already on it.

非政府组织认为既然邻苯二甲酸酯、邻苯二甲酸二丁酯以及邻苯二甲酸丁苄酯已经包含在清单中，那么，DINP， DIDP，DNOP 这3种物质也应当列入其中。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。