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二甲酸

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Suitable water-immiscible organic solvents include aromatic hydrocarbons, eg toluene, xylene, naphthalene, tetrahydronaphthalene and methyl naphthalene; chlorinated aromatic hydrocarbons, eg chlorobenzene, fluorobenzene, chloronaphthalene and bromonaphthalene; esters, eg butyl acetate, ethyl acetate, methyl benzoate, ethyl benzoate, benzyl benzoate, butyl benzoate, phenylethyl acetate, butyl lactate, benzyl lactate, diethyleneglycol dipropionate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di(2-ethylhexyl) phthalate; alcohols having six or more carbon atoms, eg hexanol, octanol, benzyl alcohol, phenyl ethanol, phenoxy ethanol, phenoxy propanol and phenoxy butanol; ethers having at least 5 carbon atoms, preferably C 5-14 ethers, eg anisole and phenetol; nitrocellulose, cellulose ether, cellulose acetate; low odour petroleum distillates; turpentine; white spirits; naphtha; isopropylbiphenyl; terpene; vegetable oil; mineral oil; essential oil; and natural oil; and mixtures of any two or more thereof.

适用于水互溶的有机溶剂包括芳香族碳氢化合物,如甲苯,二甲苯,萘,四氢萘和甲基萘;氯代芳香族碳氢化合物,如氯苯,氟,氯萘和萘;酯类,如醋酸丁酯,醋酸乙酯,苯甲酸甲酯,苯甲酸乙酯,苄酯,苯甲酸正丁酯,苯,醋酸丁酯乳酸,乳酸苄,二甘醇二丙酸酯,邻苯二甲酸二甲酯,邻苯二甲酸二乙酯,邻苯二甲酸二丁酯,二(2乙基己基)酯;醇有6个或更多碳原子,如己醇,辛醇,苯甲醇,苯乙醇,苯氧基乙醇,丙醇和苯氧基苯氧丁醇;醚至少有5个碳原子,最好荤5-14醚,如苯甲醚和phenetol;硝化棉,纤维素醚,醋酸纤维素,低气味石油蒸馏;松节油;白酒,石脑油isopropylbiphenyl;萜类,植物油,矿物油,挥发油;和天然油,以及任何两个或两个以上其混合物。

Research and application of treating waste water with carbinol by biochemical method ;2. Biochemical method and Fe-C method were used for the treatment of terephthalic acid wastewater.

采用生化法和铁碳法进行对苯二甲酸废水的处理研究,结果得出:CODCr=2000mg/L是微生物降解对苯二甲酸的抑制质量-体积分数;pH值为8~9时活性污泥处理对苯二甲酸废水比较理想;铁碳法处理对苯二甲酸废水35h后,CODCr的去除率达到了80%以上。

EH detected in Lanzhou reach of the Yellow River included naphthalene, phenanthrene, DBP, DEHP and benzothiazole and the detection rates of the five EH were 40%, 60%, 100%, 100% and 20% respectively.

结果 共定性检出有机类环境激素10种,即邻苯二甲酸二异丁酯、邻苯二甲酸正丁酯、邻苯二甲酸二(2-乙基己基)酯、邻苯二甲酸丁酯、邻苯二甲酸异辛基酯、邻苯二甲酸丁环己酯、苯并噻唑、萘、菲、苯并异噻唑。C断面检出的环境激素浓度最高,菲、DBP、DEHP浓度分别高达0.320、13.89、109.93μg/L.A断面次之,B断面检出的环境激素浓度与A断面相比有所下降,E断面检出的环境激素与其他断面相比,浓度相对较低,D断面所检出的环境激素与C断面比较,有一定下降,但下降不明显。

Results: A total of 18 kinds of SVOCs were qualitatively and quantitatively analyzed, the main compounds deteced were dimethylphthalate, diethylphthalate, dibuylphthalate, bis (2-ethylhexyl) phthalate, phenol, chrysene, benzo anthracene, benzo fluoranthene, benzo perylene, indeno (1, 2, 3-cd) pyrene, dibenzo anthraeene.

结果:定性定量检出邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、双(2-乙己基)邻苯二甲酸酯、邻苯二甲酸二辛酯、丁基苄基邻苯二甲酸酯、苯酚、4-甲基苯酚、萘、荧蒽、芘、屈、苯并蒽、苯并荧蒽、苯并荧蒽、苯并二萘嵌苯、茚并(1,2,3-cd)芘和二苯并蒽18种优先控制有机污染物。

Three aspects were included here:The derivatives of dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid were synthesized via three different routes:(1) four new compounds were synthesized via the reaction bet ween dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid, thionyl chloride and corresponding alcohol ;(2) first ,dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate wer e synthesized, then ,another four new compounds were obtained t hrough the alcoholysis under the catalyst ;(3) three acylamines were got through the ammonolysis betw een dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate and amines.

本论文分别通过三条不同的路线合成了1,4-二氢-3,6-二甲酸-s-四嗪的衍生物:(1)通过1,4-二氢-3,6-二甲酸-s-四嗪与氯化亚砜和相应的醇反应,制备了四个新化合物;(2)合成1,4-二氢-3,6-二甲酸甲酯-s-四嗪,在催化剂的作用下,与高沸点的醇进行酯交换反应,合成了四个新化合物;(3)合成1,4-二氢-3,6-二甲酸甲酯-s-四嗪后,与胺进行氨解反应,合成三个新的1,4-二氢-3,6-二甲酰胺-s-四嗪化合物。

The fish samples were cleaned up by Florisil, then analyzed by GC-EI-MS to determine eight phthalic acid esters, diethyl phthalate, dipropyl phthalate, dibutyl phthalate, butyl benzyl phthalate, dipentyl phthalate, dicyclohexyl phthalate, dihexyl phthalate and diethyl hexyl phthalate.

鱼肉样品以Florisil硅藻土层析柱净化后,经气相色谱-电子轰击离子源-质谱法分析其中8种邻苯二甲酸酯含量:邻苯二甲酸二乙酯、邻苯二甲酸二丙酯、邻苯二甲酸二丁酯、邻苯二甲酸丁基苄基酯、邻苯二甲酸二戊酯、邻苯二甲酸二环己基酯、邻苯二甲酸二己酯、邻苯二甲酸二(2-乙基己基)酯。

Gas chromatograph/mass spectrometer system was used to analyze polycyclic aromatic hydrocarbon (PAHs, including naphthalin, anthracene and fluoranthene) and phthalic acid ester [PAEs, including dimethyl phthalate, diethyl phthalate, diisobutyl phthalate and di(2-ethylhexyl) phthalate] concentration in water samples taken from every treatment units of a large-scale waterworks in a western city whose water source is the upstream of Yangtze river.

以多环芳烃(包括萘、蒽、荧蒽三种物质)和邻苯二甲酸酯包括邻苯二甲酸二甲酯(DMP、邻苯二甲酸二乙酯、邻苯二甲酸二异丁酯、邻苯二甲酸二(2-乙基己基)酯4种物质作为研究对象,采用GC-MS方法测定了以长江为原水的某大型城市给水厂各工艺段水样中的上述物质。

The crystallization behavior of polyethylene terephthalate ; random poly (ethylene/tetramethylene terephthalate) P (ET/BT ; poly (ethylene terephthalate/ isophthalate) P (ET/EI and poly (ethylene terephthalate/adipate) P (ET/EA copolyesters; and block polyethylene terephthalate/polyethylene glycol and polyethylene terephthalate/polytetramethylene glycol were studied by DLI ; DSC; WAXD; PLM and IR technique.

本文通过缩聚反应合成了不同分子量的聚对苯二甲酸乙二酯;聚对苯二甲酸酯P(ET/BT、聚(对苯二甲酸/间苯二甲酸)乙二醇酯P(ET/EI和聚乙二醇酯P(ET/EA等系列的无规共聚酯以及PET/PBG和PET/PEG等系列的嵌段共聚酯,并采用DLI、DSC、WAXD、IR和NMR等实验技术着重研究了它们的结晶行为与共聚酯的序列结构。

The crystallization behavior of polyethylene terephthalate ; random poly (ethylene/tetramethylene terephthalate) P (ET/BT ; poly (ethylene terephthalate/ isophthalate) P (ET/EI and poly (ethylene terephthalate/adipate) P (ET/EA copolyesters; and block polyethylene terephthalate/polyethylene glycol and polyethylene terephthalate/polytetramethylene glycol were studied by DLI ; DSC; WAXD; PLM and IR technique.

中文题名PET及其共聚酯的结晶行为副题名外文题名 The crystallization behavior of PET and its copolyesters 论文作者边界导师封麟先叶胜荣教授学科专业高分子化学与物理研究领域\研究方向学位级别博士学位授予单位浙江大学学位授予日期2001 论文页码总数10,159页关键词聚对苯甲酸乙二酯聚酯结晶馆藏号BSLW /2003 /O633 /1 本文通过缩聚反应合成了不同分子量的聚对苯二甲酸乙二酯;聚对苯二甲酸酯P(ET/BT、聚(对苯二甲酸/间苯二甲酸)乙二醇酯P(ET/EI和聚乙二醇酯P(ET/EA等系列的无规共聚酯以及PET/PBG和PET/PEG等系列的嵌段共聚酯,并采用DLI、DSC、WAXD、IR和NMR等实验技术着重研究了它们的结晶行为与共聚酯的序列结构。

Liquid chromatography was used to determine three kinds of phthalates including dimethyl phthalate,diethyl phthalateand dibutyl phthalatein cosmetics.

建立了用高效液相色谱法测定化妆品中邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯3种邻苯二甲酸酯类环境激素的方法。

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