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Suitable water-immiscible organic solvents include aromatic hydrocarbons, eg toluene, xylene, naphthalene, tetrahydronaphthalene and methyl naphthalene; chlorinated aromatic hydrocarbons, eg chlorobenzene, fluorobenzene, chloronaphthalene and bromonaphthalene; esters, eg butyl acetate, ethyl acetate, methyl benzoate, ethyl benzoate, benzyl benzoate, butyl benzoate, phenylethyl acetate, butyl lactate, benzyl lactate, diethyleneglycol dipropionate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di(2-ethylhexyl) phthalate; alcohols having six or more carbon atoms, eg hexanol, octanol, benzyl alcohol, phenyl ethanol, phenoxy ethanol, phenoxy propanol and phenoxy butanol; ethers having at least 5 carbon atoms, preferably C 5-14 ethers, eg anisole and phenetol; nitrocellulose, cellulose ether, cellulose acetate; low odour petroleum distillates; turpentine; white spirits; naphtha; isopropylbiphenyl; terpene; vegetable oil; mineral oil; essential oil; and natural oil; and mixtures of any two or more thereof.

适用于水互溶的有机溶剂包括芳香族碳氢化合物,如甲苯,二甲苯,萘,四氢萘和甲基萘;氯代芳香族碳氢化合物,如氯苯,氟,氯萘和萘;酯类,如醋酸丁酯,醋酸乙酯,苯甲酸甲酯,苯甲酸乙酯,苄酯,苯甲酸正丁酯,苯,醋酸丁酯乳酸,乳酸苄,二甘醇二丙酸酯,邻苯二甲酸二甲酯,邻苯二甲酸二乙酯,邻苯二甲酸二丁酯,二(2乙基己基)酯;醇有6个或更多碳原子,如己醇,辛醇,苯甲醇,苯乙醇,苯氧基乙醇,丙醇和苯氧基苯氧丁醇;醚至少有5个碳原子,最好荤5-14醚,如苯甲醚和phenetol;硝化棉,纤维素醚,醋酸纤维素,低气味石油蒸馏;松节油;白酒,石脑油isopropylbiphenyl;萜类,植物油,矿物油,挥发油;和天然油,以及任何两个或两个以上其混合物。

The syntheses and spectral characteristics of bism-methylbenzene maleate and bis-m-methylbenzene phthalate is reported in this paper.

报道了顺丁烯二酸二间甲苯酯和邻苯二甲酸二间甲苯酯的合成与光谱性质。

The binary and ternary experimental equilibrium data of the composites of mesitylene,1-methyl-2-ethylbenzene and 1,2,4-trimethylbenzene and the infinite activity coefficients γ~∞ are measured in the solvent of DBP .

以邻苯二甲酸二丁酯为萃取精馏溶剂,测定了邻甲乙苯—均三甲苯—偏三甲苯体系的二元及三元汽液平衡数据;编程关联了W ilson模型参数;采用物料平衡三对角矩阵法对萃取精馏过程进行了模拟,得出了萃取精馏塔的最佳操作条件,为萃取精馏法生产均三甲苯提供了基础数据。

In present study, a liquid-liquid extraction method was employed to extract the volatile components in mulberry fruit sparkling wine. The analysis with gas chromatography-mass spectrometry detected 69 peaks, among which 63 volatile components were identified. The first 9 volatile components with high relative content were benzyl alcohol, 2-methyl-1-butanol, mono-(2-ethylhexyl)-1, 2-benzene dicarboxylic acid, 3-methyl-1-butanol, toluene, acrylic acid butyl ester, 1H-indole-3-ethanol, isodecyl octyl phthalate and decyl octyl phthalate.

采用液-液萃取法提取桑椹汽酒中的挥发性成分,经气相色谱-质谱联机分析,共检测出69个峰,鉴定出63种挥发性化合物,其相对含量排在前9位的挥发性化合物分别是苯乙醇、2-甲基-1-丁醇、1,2-苯二酸单(2-乙基)己酯、3-甲基-1-丁醇、甲苯、丙烯酸丁酯、1H-吲哚-3-乙醇、邻苯二甲酸异癸基辛基二酯、邻苯二甲酸癸基辛基二酯。

Additionally LC-MS was also used in qualitative analysis of the reactionsystem for the synthesis of dipropyl toluene-2,4-dicarbamate TDC(Pr. The main side-reactions were condensation reactions between 3-amino-4-methyl N-propylphenylcarbamate with TU or toluene 2,4-bisurea.

同样,运用液质联用技术对甲苯-2,4-二氨基甲酸丙酯TDC合成反应进行了定性分析,确定了副产物并推测其主要副反应是中间产物3-氨基-4甲基苯氨基甲酸丙酯与TU和甲苯-2,4-二脲之间的缩合反应。

In order to achieve a rapid and accurate selection for extractive distillation solvent, and to acquire 1,2,3-trimethylbenzene with high purity from solvent oil via extractive distillation, the UNIFAC model was used to calculate the relative volatility of 1,2,3-trimethylbenzene to indane (the mass ratio of 1,2,3-trimethylbenzene to indane is 4∶1) in five different solvents, acetophenone, di-2-octylhexyl phthalate, glycol, dimethyl sulfoxide,sulfolane at 17.47 kPa.

为了快速准确地选择萃取精馏溶剂,由190#溶剂油萃取精馏获取高纯度连三甲苯,运用UNIFAC模型,计算了质量比为4∶1的连三甲苯-茚满体系在苯乙酮、乙二醇、邻苯二甲酸二辛酯、二甲基亚砜和环丁砜5种溶剂中在17.47 kPa下的相对挥发度。

Relative retentions of 12 S-compounds on 4 different liquid phases were given.

给出了十二种硫化物在沙鱼烷、苯二甲酸二壬酯、磷酸三甲苯酯及亚氨基二丙腈四种柱子上的相对保留值。

In the mixed solvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styrene oxide is good but the conversion of styrene is low due to the coordination to the catalyst of the solvent.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高,但由于溶剂对催化剂的配位作用抑制了催化剂的活性,苯乙烯转化率很低;当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后,苯乙烯的转化率提高,生成环氧苯乙烷的选择性不变。

In this thesis, this system is used for epoxidation of propylene and styrenewith good results. The solvent effect is investigated for epoxidation of styrene. In the mixedsolvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styreneoxide is good but the conversion of styrene is low due to the coordination to thecatalyst of the solvent. When part of dimethyl phthalate or phenyl ether is replacedby toluene, the conversion increases and the selectivity keeps constant.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高,但由于溶剂对催化剂的配位作用抑制了催化剂的活性,苯乙烯转化率很低;当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后,苯乙烯的转化率提高,生成环氧苯乙烷的选择性不变。

Underoptimal conditions, in toluene / dimethyl phthalate / TBP, after EAHQ was oxidizedwith 〓, then the catalyst and styrene were added, the conversion of styrene basedon EAHQ is 68%, the selectivity for styrene oxide based on styrene is 92% and theTON of the catalyst is 500; in toluene / phenyl ether / TBP, epoxidation of styrenewas performed with 〓 generated in situ, the conversion is 46%, the selectivity is94% and the product can be separated by distillation under reduced pressure.

优化条件下,甲苯/邻苯二甲酸二甲酯/TBP(2/2/1,体积比)中,EAHQ先用〓氧化完全后,再加入催化剂A和苯乙烯进行环氧化反应苯乙烯相对于EAHQ的转化率为68%,生成环氧苯乙烷的选择性为92%,催化剂A的TON达到500;甲苯/二苯醚/TBP(1/3/1,体积比)中,原位生成〓条件下苯乙烯相对于EAHQ的转化率为46%,生成环氧苯乙烷的选择性为94%,产物可通过减压蒸馏分离。

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