二烯烃

The preparation of potassium malonyloxyborohydride in situ and its seletive hydroborating alkene are described.

介绍了丙二酰氧基硼氢化钾的制备及其原位与烯烃的选择性硼氢化。

AIM: To synthesize 2 novel chiral ligands derived from cinchona alkaloids and study their catalytic performance in asymmetric dihydroxylation of 5 olefins.

目的：合成两种新的金鸡纳生物碱类衍生物配体并将其用于催化五种烯烃的不对称二羟化反应，考察催化效果。

The reaction of perfluoroalkyl bromide and a,w-perfluoralkylene dibromide in sulfinatodehalogenation system with olefins and the differences in behavior between perfluoroalkyl bromides and their corresponding iodides are reported.

本文报道溴代全氟烷和α，ω-二溴代全氟烷在亚磺化脱卤反应体系中与烯烃的反应及其与相应的碘代全氟烷的区别。

Based on GC and GC-MS analyses, the geochemical characteristics of these typical deep viscous oils are listed as follows:(1) strong preference of even n-alkanes over odd n-alkanes;(2) strong preference of phytane over pristane, i. e. Pr/Ph ratio＜＜1;(3) high abundance of gammacerane relative to C〓hopanes;(4) much more amounts of C〓 pentakishomohopanes than C〓 tetrakishomohopanes and even C〓 trishomohopanes.

罗家—垦西地区稠油饱和烃色谱、色谱-质谱分析结果展示：(1)正构烷烃具有明显的偶奇优势；(2)类异戊二烯烷烃具有较强的植烷优势，姥姣烷/植烷比值远小于1；(3)伽玛蜡烷相对含量(相对于C30藿烷)普遍很高；(4)C35升藿烷明显高于C34、甚至C33升藿烷；表现出膏盐湖相生物标志物的组成特征。

Seven major methods and their reaction characteristics for the synthesis of primary vicinal diamines starting from epoxides, and alkenes etc.

详细综述了从环氧化合物、烯烃等为起始原料合成一系列一级邻二胺的七条主要路线，并比较了各条反应路线的特点。

The effect of liquid isoprene rubber on properties of NR/BR compound,physical properties and thermal air aging property of its vulcanizate was investigated and compared to that of aromatic oil.

以液体聚异戊二烯橡胶为反应型增塑剂，研究LIR对NR/BR混炼胶性能、硫化胶物理性能和耐热空气老化性能的影响，并与添加芳烃油的NR/BR并用胶进行对比。

In part three oxidation of bromide with an ion-supportedbenzene in ionic liquids afforded a clean path for bromination of alkenes. It was found that this reaction is highly stereoselective.

在离子液体中使用离子支持的二乙酸碘苯氧化溴离子，提供了一条清洁的烯烃加溴途径，发现反应具有高的立体选择性。4。

In this catalyst system, the Knoevenagel condensations of a series of aromatic aldehydes with malononitrile or ethyl cyanoacetate were programmed and a mechanism was postulated as well. When aromatic aldehydes reacted with ethyl cyanoacetate, the corresponding alkenes proved to be E-isomers by 1H NMR.

在该反应体系中考察了一系列芳香醛和丙二氰、氰基乙酸乙酯的缩合反应，并推测了Knoevenagel缩合反应的机理，芳香醛与氰基乙酸乙酯缩合产物经1H NMR检测为E式烯烃。

The experiments for determining the reaction kinetics of Daqing atmospheric residue were performed in a continuous flow, expanded bed rector. Four-lumped reaction kinetic model was developed to account for various feed and product fractions of Daqing atmospheric residue (gases, gas oil, residue and coke). The amounts of olefins and alkyls in the gas products were further analyzed to determine reaction kinetics of gas product distributions. Hence, a combined five-lumped reaction kinetic model was obtained for catalytic pyrolysis of Daqing atmospheric residue. The kinetic constants both in four-lump model and five-lump model were evaluated. A simulator for catalytic pyrolysis process was developed by incorporating the five-lumped kinetic model into the hydrodynamic flow model.

其次利用改进的固定流化床装置考察大庆常压渣油催化裂解反应规律，筛选反应工艺参数；分析了催化裂解工艺存在的主要化学反应类型，提出了渣油一次反应和二次反应网络图；将反应原料油作为单独集总组分，而将产品中的轻质油、气体、焦炭分别作为集总，从而建立了四集总动力学模型；在此基础上，把气体产物中的目的产物低碳烯烃独立划分，得到五集总动力学模型；采用最小二乘法分析实验数据，分别得到四集总动力学模型和五集总动力学模型中各集总间相互反应转化的反应速率常数。

The coupling reaction of aryl iodides, bromides and chlorides with differentolefins catalyzed by catalyst 2 and 4 was studied. It was found that compounds 2 and 4 anchored on active carbon are efficient catalyst for the Heck reaction in the case of aryl bromides and aryl chlorides as substrates (Scheme 3). It is notable that catalyst 4 has higher efficiency for aryl chlorides.___^H Cat.2 or 4, Base HXSolution, 100C or 140

以化合物2和4为代表，重点研究了活性炭负载的二茂铁亚胺环钯化合物催化碘代苯、溴代苯和氯代苯与活泼烯烃之间的偶联反应(Scheme 3)，发现活性炭负载的二茂铁亚胺环钯化合物2和4均可用于催化多种溴代和氯

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。