二烯烃

Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1，1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3，4-二氯马来酰亚胺以及3，4-二氯香豆素进行增环反应的工作基础上，研究了3，4-二氯香豆素（1）和3，4-二氯马来酰亚胺（8）与5个α-苯基取代的环烯烃2-苯基苯并呋喃（15），3-苯基苯并呋喃（16），2，5-二苯基噁唑（17），2，5-二苯基噻唑（18），2-甲基-4-苯基噻唑（19），以及一个丁二烯——2，3-二甲氧基丁二烯（40）进行的芳香族增环反应。

Through mechanism analyzing on the process of producing HMT , it was known that because the resistance of isobutylene was small ,the yield of outgrowth in such a reaction system was little and the yield of reaction was as high as 86%. 2,3-dimethyI-butene-2 had the biggest resistance and lowest yield of reaction of 18%. 2,3-dimethyl-butene-l had bigger resistance than isobutylene and more outgrowth than isobutyles but its yield of reaction could reach 70%.

通过对上述三种烯烃合成HMT的研究可知，由于新己烯位阻小，反应中副反应少，收率高达86％：而2，3—二甲基—丁烯—2的位阻最大，反应中副反应最多，反应收率最高仅为18％；2，3—二甲基—丁烯—1的位阻比新己烯大，反应副产物比新己烯多，但反应收率仍可达70％。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分，我们研究了α，α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应，发现全氟苄基碘或溴及α，α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐；全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴；在烯烃存在下，全氟苄基碘则与烯烃发生加成反应，生成相应的1：1加成产物；在三价醋酸锰的作用下，部分芳香化合物如茴香醚，二甲氧基苯，吡啶，喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应，反应表现出一定的区域选择性，产率良好。

The results show that isobutene oligomerization is fast liquid-solid reaction. Under the temperature of 80 ℃～120 ℃ and pressure of 2.0 MPa, the products of oligomerization are mainly dimers and trimers of isobutene. The yield of trimers is higher than that of dimers and the mass fraction of trimers decreases with reaction temperature increasing. The yield of tetramers is much lower than that of dimmers and trimers. The tetramers are formed by reaction of isooctenes and C8 carbonium ion.

结果表明，异丁烯齐聚反应为快速液固相催化反应，在80 ℃～120 ℃，2.0 MPa的实验条件下，反应产物主要是异丁烯的二聚物和三聚物，且三聚物的收率远高于二聚物，两者的浓度比值随反应温度的升高而下降；少量四聚物的生成主要源于碳八烯烃与碳八正碳离子的反应。

It is seen that oxygen group function of additives is very remarkably in tribological characteristics, that is EP property of dihydroxy docosanoic acid without active element is very near to that of SO with active element sulfur.

双羟基廿二酸的极压性与不含氧基团的硫化烯烃十分接近，以液体石蜡为基础油，最大无卡咬负荷P〓值，前者为539N，后者为588N，再者相差49N，可以看出，氧基团的作用是十分显著的，即无活性元素的双羟基廿二酸的极压性可以十分接近于含活性元素的抗磨极压剂硫化烯烃。

The free-radical addition reaction of malonic ester with a series of alkenes under the uniform conditions has been studied.

在相同反应条件下，进行一系列烯烃与丙二酸二乙酯的加成反应，求得产率与烯烃结构间的定量关系，即反S型曲线。

The results of AD reactions are as follows:(1) When the AD reaction of eight olefins was performed at 0.5mo1% OsO〓 and 2mol% ligand 8 in PEG/NMO system, the diols were obtained in 78～90% yields and 78～96% ees (except for trans-5-decene and ally naphthyl ether).

催化结果如下：(1)在PEG/NMO体系中，将配体8用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.005/1时，化学产率为78～90％，除反式-5-癸烯和萘基烯丙基醚较低外，其它六种烯烃的相应二醇产物的ee值为78～96％。

The osmium-catalyzed asymmetric dihydroxylation of olefins provides one of the most effective methods for the preparation of vicinal diols. Almost all kinds of olefinic substrates can be transformed to the corresponding diols by means of AD reaction. The chiral osmium catalyst is generated in situ by the chiral ligand complexing with OsO〓 in the reaction.

手性锇催化剂催化的烯烃不对称二羟基化反应是合成手性邻二醇最有效的途径之一，可以将几乎所有类型的烯烃转变成相应的手性邻二醇，因此广泛地应用于药物、天然产物以及精细化工产品的合成。

The application markets of three kinds of isoolefines(isoprene, cyclopentadiene ,piperylene) from the cracking C5 fractions and their downstream derivatives were reviewed.

着重评述了裂解C5馏分资源中3种异构烯烃(异戊二烯、环戊二烯和间戊二烯)及其下游衍生物的应用市场，并剖析了我国裂解C5资源的利用现状及应用前景。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用，烯烃的硼氢化物在PTC条件下，插入∶CCl2 ，可得饱和羧酸；炔烃则难以与之硼氢化。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新