二烯烃

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

The industrial manufacturing technique, the trend of development of neohexene ,and the characteristics of these production technique were reviewed and analyzed in the paper, particularlyabout the selective dimerization of isobutylene and metathesis of βdiisobutylene with ethylene were introduced.

对新己烯生产技术的现状和今后的发展趋势进行了综述，分析了由异丁烯和乙烯生产新己烯的技术特征，讨论了烯烃二聚工艺和催化剂、烯烃复分解工艺及相应的催化剂，指出了各种工艺的优势和不足。

The process can convert over 95% isobutylene in C 4 olefin into diisobutylene or isooctene in the present of acid cation exchange resin catalyst,and partial 1-butylene also take part in the reaction.

介绍了一种混合碳四烯烃叠合利用的预反和催化蒸馏组合技术，该技术以酸性阳离子交换树脂为催化剂，可以将混合碳四烯烃中的95%以上的异丁烯叠合反应生成二异丁烯和异辛烯，且部分正丁烯也参与二聚或共聚。

The result shows at the mild condition chain olefin that nCl7, polyethylene can be cracked into solutions of ethane, propane, butane, benzene and toluene and other small molecular compounds, polyethylene reacted fluids are mainly composed of a-olefin at the range 12 to 38, by which α-ωdiene, saturated hydrocarbon and aromatic hydrocarbon, anthracene, phenanthrene of albocarbon series are contained.

结果表明，在温和条件下可以将链状烷烃如正十七烷烃、聚乙烯通过微波及炭催化剂的作用，裂解成乙烯、丙烷、丁烷、苯、甲苯等溶剂及小分子化合物。聚乙烯反应液体产物以碳数在12~38范围的α-烯烃为主，也产生α-ω二烯、饱和烃及芳烃，芳烃主要有萘系列、葱、菲等。

Results:The experiments showed that 59 components were identified,accounting for 72.91 percent of the total essential oil.The essential oil was mainly composed of dehydrocostuslactone、costunolide、cedrenol、α-elemene、1,3-cyclooctadiene、eudesmol、α-selinene、β-caryophyllene、-longifolene、3,4-octadiene,7-methyl-etc.Among them Lactones like Dehydrocostuslactone and costunolide are essential components.

结果：GC-MS法分析鉴定了木香挥发油中59个成分，其主要成分为去氢木香内酯、木香烃内酯、雪松烯醇、α-榄香烯、环辛二烯、桉叶醇、α-芹子烯、丁子香烯、长松叶烯、7-甲基-3，4辛二烯等，占挥发油总量的72.91%；首次发现木香挥发油及去氢木香内酯、木香烃内酯具有抑制ADP诱导的血小板聚集活性。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3，2-b]异喹啉-11-酮8和11H-苯并噻唑[3，2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈，丙烯酸甲酯，富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

The results showed that the yields of coke and dry gas decreased first and then increased ,and olefinic content in gasoline and C 3 olefinicity decreased by 2.0% and 1.2% respectively at the similar heavy oil conversion when the amount of que...

结果表明：在控制相近的重油转化深度下，终止剂用量占处理量 1 %、1 0 %和 1 6%时，焦炭和干气产率均先降低后增加，汽油中烯烃含量和C3 中烯烃质量分数则分别降低 2 。0和 1 。2个百分点，汽油中异正构烷烃比增加，二烯值降低，诱导期增加超过 1 0 0min ；终止剂注入点由提升管中部移至上部而其他条件不变时，汽油中烯烃和C3 中烯烃质量分数分别增加 4.2和 0 。6个百分点

Molybdophopsphoric Acid Catalysis in the Oxidative Cleavage of Olefins by the Hydrogen Peroxide Oxidative cleavage of the double bond could be catalyzed by H_3PMo_(12)O_(40) using H_2O_2 as oxidant, various trisubstituted olefins were oxidized to aldehydes or ketones in high yields. The system was not satisfied for electron-deficient olefins such as trans-(2-nitrovinyl) benzol or chalcone. The reaction of aliphatic olefins did not occur under the same conditions.

二、磷钼酸催化过氧化氢对烯烃的氧化断裂反应用过氧化氢(30％)作为氧化剂，磷钼酸可以催化氧化碳碳双键的断裂反应，三取代的烯烃被氧化生成醛或酮，产率较高；此体系对于缺电子烯烃如查尔酮，不饱和硝基化合物的断裂反应效果较差，脂肪族烯烃在此体系下的氧化并不发生。

Zinc diamyl dithiocarbamate antioxidant showed good synergism with antimony diakyl dithiocarbamate antiwear additive in improving the oxidation stability of modified soybean oils. The incipient oxidation temperature and induction period time of genetically modified soybean oils were improved significantly by adding polyalphaolefin and additives, and they were even better than that of the synthetic base oil PAO with the same additive formulation.

结果表明，改性大豆油的不饱和脂肪酸含量越高，其氧化安定性越差；抗氧剂二戊基二硫代氨基甲酸锌和抗磨剂二烷基二硫代氨基甲酸锑在改性大豆油中均表现出了良好的抗氧协同性能，尤其在基因改性大豆油中，聚-α-烯烃和添加剂的复配使其起始氧化温度和氧化诱导时间均超过了相同配方的聚-α-烯烃油样。

With 54# half-refined paraffin as raw material,the technology of the second injecting steam of ethane cracking is used for reference in the paraffin cracking process which avoides the coke produced in cracking furnace.

采用优质的54#半精炼石蜡，将乙烯裂解二次注汽技术融合在石蜡裂解技术中，避免了裂解炉结焦；考察了单程裂解、炉前甩残蜡循环裂解、炉后甩残蜡循环裂解在相同的工艺条件下的产品质量、产品收率及存在的问题；验证了新的炉后甩残蜡循环裂解是较好的工艺路线，在较高的水蜡比15%，高温600℃、低烃分压和短停留时间(2s左右)条件下，能生产出高质量的α-烯烃产品(总烯烃质量分数在97%以上，α-烯烃含量为88%)。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新