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In chapter three, the activating agents of ytterbium have been examined. Barbier-type reaction promoted by ytterbium metal was examined. The experimental results shown that the yield of Barbier reaction of imines with allylic bromide promoted by ytterbium is higher than that of aldehydes and ketones with allylic bromide under the same reaction conditions. In this chapter, the reductive cleavage of Se-Se and S-S bond induced by ytterbium metal was also studied.

首先研究了金属镱的活化剂以及活化方法,接着考察了金属镱促进的Barbier反应及其在合成高烯丙基胺和高烯丙基醇中的应用,以及影响该反应的主要因素;究了金属镱促进的二硫醚和二硒醚的S—S键和Se—Se键的还原断裂,继而与氯代烃,胺基甲酰氯反应生成相应的硫醚,硒醚,胺基甲酸硫代酯和硒代酯。

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章,我们研究了在水相介质中金属铟促进的烯丙基溴对1,1-二氰基-2-芳基乙烯的Michael加成反应,生成一个含碳碳双键和二个碳氮叁键的三官能团化合物,另外,金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联,生成砜。

Also useful are oil-soluble copper dithiocarbamates of the general formula Rc Rd z Cu, where z is 1 or 2, and Rc and Rd are the same or different hydrocarbyl radicals containing from 1 to 18, and preferably 2 to 12, carbon atoms, and including radicals such, for example, as alkyl, alkenyl, aryl, aralkyl, alkaryl and cycloaliphatic radicals.

化学通式为Rc Rd z Cu的油溶性二硫代氨基甲酸铜也适用,式中,z为1或2,Rc和Rd是含1~18(以2~12为宜)个碳原子的相同或不同的烃基,这类烃基的实例包括烷基、烯基、芳基、芳烷基、烷芳基和脂环基。

Also useful are oil-soluble copper dithiocarbamates of the general formula Rc RdzCu, where z is 1 or 2, and Rc and Rd are the same or different hydrocarbyl radicals containing from 1 to 18, and preferably 2 to 12, carbon atoms, and including radical s such, for example, as alkyl, alkenyl, aryl, aralkyl, alkaryl and cycloaliphatic radicals.

通用化学式为RcRdzCu的油溶性二硫代氨基甲酸铜,也非常有用。式中,z为1或2,Rc和Rd是含有1到18个碳原子(最好含有2-12个碳原子)的相同或不同的烃基根,并且包括烷基、链烯基、芳基、芳烷基、烷芳基和环脂基等。

Good thermal stability, High mechanical strength.Used as catalyst or catalyst carrier in the manufacturing of the important industrial products, such as cyanuramide, benzene anhydride, maleic acid anhydride, butadiene rubber, acrylic nitrite, etc.

用途:本产品在三聚氰胺、苯酐、顺丁烯二酸酐、顺丁橡胶、丙烯腈等重要工业品生产中用作催化剂及催化剂载体,也广泛用于石化产品的精制脱除芳烃,也可用于有机气体、液体的选择性吸附分离及离子交换脱除水中多价有害元素等。

A high molecular weight polyisobutenyl succinimide dispersant with high nitrogen content and good thermal and oxidative stabilities was developed.

采用氯化烃化工艺和后偶联反应技术开发了一种氮含量高、热稳定性和氧化稳定性好的高相对分子质量的聚异丁烯基丁二酰亚胺分散剂。

The studies found that compatibility between ZDDP and succinimide dispersants primarily depended upon active α-amino-group content in succinimides. The active α-amino-group content was affected by the alkylation and amination processes, and also affected by the structure of polyisobutylene in succinimides.

研究结果表明,丁二酰亚胺与 ZDDP 的相互作用主要取决于丁二酰亚胺中活泼的伯胺氮含量,而伯胺氮含量则决定于丁二酰亚胺在生产中的烃化、胺化工艺和聚异丁烯基的结构。

Progress in a variety of catalytic systems-catalyzed dimerizations of terminal alkynes to synthesize enynes is summarized.

综述了不同催化体系催化末端炔烃二聚反应合成共轭烯炔化合物的研究进展。

The trace amount of impurities,namely C5,tert-butyl alcohol,di-secondary butyl ether,methyl ethyl ketone and secondary butyl alcohol,in C4 hydrocarbon from butylene hydration tail gas were analysed by means of gas chromatograph with a column packed with sebaconitrile and polyethylene glycol-20M,and liquid-phase admission valve.

2m×4mm为填充柱,采用液相进样阀液态直接进样的填充柱气相色谱法分析了丁烯水合尾气C4烃中的C5、叔丁醇、二仲丁醚、甲乙酮及仲丁醇等微量杂质的含量。

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