二溴化苯

Sodium fatty alcohlo ether sulfate, S-80, fatty alcohol-polyoxyethylene ether and S-60 resulted in slow photodecomposition of rotenone in aqueous solution revealing a photo-extinction effect, sodium dodecylberzenesulfonate, tween-60, hexadecyl trimethyl ammonium bromide and poyl vinyl pyrrolidone made the photolysis of rotenone in aqueous solution fast showing an obvious photosensitized effect.

室内条件下研究了鱼藤酮水溶液存在不同表面活性剂时，鱼藤酮的紫外光降解，结果表明：脂肪醇聚氧乙烯醚硫酸钠、司本－80、长链脂肪醇聚氧乙烯醚和司本－60对鱼藤酮在水溶液中的光解速率表现出显著的光猝灭降解效应；十二烷基苯磺酸钠、吐温－60、十六烷基三甲基溴化铵和聚乙烯吡咯烷酮对鱼藤酮在水溶液中的降解表现出一定程度的光敏化作用。

Bromooctane was synthesized from potassium bromide(by-product of synthesizing 2-hydroxy-4-octyloxybenzophenone) and n- octanol using concentrated sulfuric acid as a catalyst.

以生产2-羟基-4-正辛氧基二苯甲酮的副产物溴化钾和正辛醇为原料，浓硫酸为催化剂，合成了溴代正辛烷。

The overall yield was 43.6%.The yield of reduce of ester was increased nearly one times than the past method because of KBH4-LiCl as the reducing agent instead of NaBH4. Changing the reaction conditions of bromization, the one-way yield enhanced 30%. The yield of reduce of the bromide was added by one times by improving the process. Tefluthrin was achieved by the catalytic esterification of DCC and DMAP.

优化后工艺对四氟对苯二甲酯的还原采用了廉价高效的还原试剂KBH4-LiCl，使收率比NaBH4法提高了近一倍；对溴化反应条件进行了优化，单程收率提高了30%；对溴化物还原条件的优化，使其收率提高了近一倍；采用了催化剂DCC和DMAP合成了最终产品七氟菊酯。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料，经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2，3，5，6-四氟苄醇，甲基苄醇与-(1RS，3RS)-3-(2-氯-3，3，3-三氟丙-1-丙烯基)-2，2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

The synthesis of poly{2-4-[bi(4-tetrabutylphenylamino]phenylphenylenenvinylene} was beginwith 4-tetrabutylbenzoic,through acylation、Hoffmann rearrangement、bromization、idionization、Ullmann reaction、bromization、condensepolymerization.

聚{2-[4-二(4-叔丁基苯胺基苯基]苯撑乙烯}是以对叔丁基苯甲酸为原料，经酰氯化、酰胺化、Hoffmann降解、碘化、Ullmann反应、溴化、缩聚反应得到。

The chemical structure of the product was characterized by means of the melting point and IR. The results show that tetraethylammonium bromide which was used as a phase transfer catalyst in this reaction had optimization effect on the interfacial diffusive reaction of BTC and PNP. Higher concentration of sodium hydroxide, lower temperature and a higher dosage of BTC produced a small amount of 4-nitrophenyl chloroformate, while lower concentration of sodium hydroxide and a lower dosage of BTC made reaction incomplete, which affected the yield.

结果表明，在碳酸二（4-硝基苯基）酯合成中使用的相转移催化剂四乙基溴化铵对受界面扩散控制的BTC气与对硝基酚钠反应有良好的相转移催化效果；氢氧化钠质量分数较低时，酚钠盐向溶有BTC的油相扩散速度较小，较高时会产生氯甲酸对硝基苯酯；温度较低、BTC量较高时，会产生少量氯甲酸对硝基苯酯，BTC用量较低会使反应不完全，这些都影响着收率。

Ib was synthesized by condensation of phthalic anhydride with 2-methylresorcinol in fused AlCl〓/NaCl (5∶1), followed by selective acetylation, methylation, NBS bromination and condensation with sodium ethoxide.

邻苯二甲酸酐在熔融的三氯化铝-氯化钠(5：1)中和-2，6-二羟基甲苯环合得1，3-二羟基-2-甲基蒽醌〓后经选择性乙酰化、甲基化、NBS溴化、乙醇钠缩合得1-甲氧基-2-乙氧甲基-3-羟基蒽醌。

Silver nanoparticles with average particle size ranging from 2 to 131nm were manipulatively synthesized starting from silver nitrate using 10 kinds of different functional group-containing organic modifiers, such as polyvinylpyrrolidone, tween-80, sodium dodecyl sulfate, sodium polyacrylate, polyethylene glycol, D-sorbitol, sodium dodecyl sulfonate, sodium dodecylbenzene sulfonate, polyvinyl alcohol, cetyltrimethylammonium bromide, at room temperature.

摘 要：选择10种含有不同官能团的有机物为表面修饰剂，如聚乙烯吡咯烷酮、吐温-80、十二烷基硫酸钠、聚丙烯酸钠、聚乙二醇、山梨醇、十二烷基磺酸钠、聚乙烯醇、十二烷基苯磺酸钠和十六烷基三甲基溴化铵等，在室温下进行了平均粒径在2～131nm范围内纳米银颗粒的控制合成研究。

First, the geometry optimization for 1-phenyldibenzophosphole and triphenylphosphine were carried out using quantum chemical AM1 method.

用量子化学AM1方法优化了1-苯基二苯并膦和三苯基膦的几何构型，比较了两种化合物的电子结构和空间结构，发现PDBP作为羰基合成铑膦催化剂的配体要优于三苯基膦；系统研究了PDBP的合成方法，其最佳合成条件为：在无水无氧的条件下，采用二乙胺锂与溴化四苯基膦摩尔比为3，反应温度为22 ℃，反应5 h，反应后酸化， pH值为1～2，产物收率可达到85％～88％。

One subject of the present work relates to a green chemistry synthesis of tetrabromobisphenol A wherein the combination of sodium bromide and sodium bromated as brominating agent which completely replaces conventional liquid bromine.

据文献报道，该产品在某些阻燃材料中将是十溴二苯醚的理想替代品之一，目前，仅有国外公司在销售该种产品，我国还没有实现真正的工业化生产，所以研制开发溴化环氧树脂阻燃剂具有重要意义，本文研究工作主要包括三方面的内容。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。