二溴化苯

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

The dual-site phase-transfer catalyst, 1,4-bisbenzene dibromide, was synthesized in toluene solution at 70℃ from p-xylylene dibromide and tributylamine.

双活性基相间转移触媒是由二溴对二甲苯与三丁胺以甲苯为溶剂在70℃下反应生成溴化1，4-二苯。

This article provided a new route to produce 4-dimethoxy phenethylamine. In basic condition, the product could be obtained through etherization, bromation, Grignard reaction, hydroxyethylation, esterification and Gabriel reaction with phenol as raw material, the overall yield is 45.0%.

提出了合成4-甲氧基苯乙胺的新方法，即在碱性条件下，苯酚首先与硫酸二甲酯反应，再选用高选择性的溴化剂溴化后，经格氏反应、羟乙基化反应和酯化反应，最后经Gabriel反应可以制备目标产物，反应总收率为45.0%。

Benzyl bromide was synthesized from potassium bromide ,a by-product from synthesis of 2-hydroxy-4-n-octyloxybenzophenone(UV-531),and benzoic alcohol in the presence of concentrated sulfuric acid.

溴化钾作为工业生产2-羟基-4-正辛氧基二苯甲酮的副产品，在浓硫酸存在的条件下，与苯甲醇进行反应合成苄基溴。

Study on an efficient process for the preparation of trifloxystrobin starting from 2-methylacetophenone bypartial oxidation,esterification,reaction with methoxyamine,bromization and condensation with 3'- acetophenone oxime.

以邻甲基苯乙酮为原料，经过高锰酸钾的碱性氧化，甲醇酯化，再与甲氧基胺盐酸盐肟化后，用N-溴丁二酰亚胺溴化，最后和间三氟甲基苯乙酮肟缩合得到目标产物肟菌酯。

Bromo-2′,4′-dichloroacetophenone was synthesized in three steps,w hich were bromization ,chlorination and acylation,from glacial acetic acid and m -dichlorobenzene.

以冰乙酸和间二氯苯为原料，经溴化、氯化、酰化三个步骤，制得 2—溴- 2′，4′-二氯苯乙酮，产率达 70 %。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下，利用2，4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应，合成了中间体4-丙氧基－2-羟基二苯甲酮，将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

The α-monobromination of 2-pentone,4-methyl acetophenone,4-methoxyacetophenone,6-methoxy-2-acetylnaphthane,2,2,5,5-tetramethyl-3-hexanone,cyclooctanone,cyclododecanone with respectively,were studied.

研究了离子液体三溴化1-丁基-3-甲基咪唑[Br3]对2-戊酮、4-甲基苯乙酮、4-甲氧基苯乙酮、6-甲氧基-2-乙酰基萘、2，2，5，5-4-甲基-3-己酮、环辛酮、环十二酮、丁醛等羰基化合物的α-溴化反应。

L-Phenylalanine was then obtained by alkylation of N- glycine ethyl ester with benzyl bromide in the presence of an asymmetric phase-transfer catalyst-N-benzyl-cinchonine chloride, followed by hydrolysis of the resulting product.

以甘氨酸乙酯盐酸盐和二苯甲酮为起始原料合成了N-二苯亚甲氨基乙酸乙酯，后者在手性相转移催化剂-N-苄基氯化辛可宁诱导下与烷基化试剂溴化苄发生不对称相转移催化烷基化反应，水解得到L-苯丙氨酸。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。