二水合的

The experimental results show that hydrophobic association increases obviously with increasing polymer concentration, hydrophobe content, hydrophobic side chain length and temperature. The Critical aggregate concentration of P(AM/NaAA/C_8AM) with different hydrophobic content is 1.5-3g/L. Strong ass...

结果表明，随聚合物浓度、疏水单体摩尔分数、疏水侧链长和温度的增加，疏水缔合作用增强；不同疏水单体含量的P(AM/NaAA/C8AM)的临界缔合浓度为1.5~3.0 g/L；表面活性剂十二烷基硫酸钠与P(AM/NaAA/C8AM)发生了强烈的疏水相互作用，形成混合胶束，得到SDS的临界胶束浓度为8×10-3 mol/L；由于聚合物链上羧基的存在，使其具有良好的 pH敏感性，随 pH值的增大，P(AM/NaAA/C8AM)的疏水缔合作用呈现先减弱后恒定再增强的变化。

The experimental results show that hydrophobic association increases obviously with increasing polymer concentration, hydrophobe content, hydrophobic side chain length and temperature. The Critical aggregate concentration of P (AM/NaAA/C8AM) with different hydrophobic content is 1.5~3g/L. Strong association between surfactant sodium dodecyl sulfate and P (AM/NaAA/C8AM) occurs through the formation of mixed micelles. The CMC of SDS is 8×10^(-3)mol/L. Moreover, because of the presence of-COOH group, the terpolymers have pH-responsive characterization. The hydrophobical association changes greatly with increasing pH.

结果表明，随聚合物浓度、疏水单体摩尔分数、疏水侧链长和温度的增加，疏水缔合作用增强；不同疏水单体含量的P(AM/NaAA/C8AM)的临界缔合浓度为1.5~3.0g/L；表面活性剂十二烷基硫酸钠与P(AM/NaAA/C8AM)发生了强烈的疏水相互作用，形成混合胶束，得到SDS的临界胶束浓度为8×l0^(-3)mol/L；由于聚合物链上羟基的存在，使其具有良好的pH敏感性，随pH值的增大，P(AM/NaAA/C8AM)的疏水缔合作用呈现先减弱后恒定再增强的变化。

Both crystallographically unique Zn atoms exit as an octahedral geometry. The four equatorial positions of Zn1 atom are occupied by the carboxylate-oxygen atoms of the two tartrates, and the two oxygens of the left four carboxylate-oxygen atoms coordinate to two different Zn2 atoms, respectively, forming infinite coordination polymer chains. The left two of the trans equatorial positions of Zn2 atom are completed with two oxygen atoms of two water molecules. The axial positions of both Zn atoms are occupied by the nitrogen atoms from different 4,4'-bipyridine molecules to give a 2D rectangular-grid layers with a cavity dimension of 0.51165(3)nm×1.13896(5) nm. A three dimensional network is formed by the crystallization water chains joined by the carboxylate-oxygen atoms through hydrogen-bonding interactions.

两个晶体学独立的Zn原子均为八面体构型，其中Zn1原子赤道配位点被2个酒石酸根中的4个羧酸根氧螯合配位， 2个酒石酸根中剩下的4个羧酸根氧中的2个分别与2个Zn2原子连接形成无限一维链， Zn2原子的另外2个反式赤道配位点被2个水分子氧占据，同时这两种Zn原子的轴向配位点均被4，4'-联吡啶的氮原子占据，形成具有矩形格子[0.51165(3) nm×1.13896(5) nm]的二维层状结构，游离的2个水分子通过氢键作用形成二聚体，并与酒石酸根中未与Zn配位的羧酸氧连接，把二维层状结构连接成三维网状的超分子结构。

A novel planar chiral diferrocenylimine-diols 6 was synthesized by the condensation of R, S(subscript p-1-(2-diphenyl hydroxyl methyl) ferrocenylethylamine [R, S(subscript p-4] with phthaldehyde in anhydrous ethanol, and was crystallographically characterized.

通过R，S(下标 p-1-（2-二苯基羟甲基）二茂铁乙胺[R，S(下标 p-4]和对苯二甲醛在无水乙醇中的缩合反应合成了一种新型平面手性双二茂铁亚胺二醇化合物6，并经X-射线衍射分析它的晶体结构。

Cycloalkylation of diethyl malonate and ethyl cyanoacetate with alkyl halide was investigated in the presence of toluene.

以甲苯为溶剂及带水剂，用粉末K2CO3代替常规使用的乙醇钠，在季铵盐和聚乙二醇混合相转移催化剂的存在下，含有活泼氢的丙二酸二乙酯和氰乙酸乙酯与二卤代物进行缩合反应，得到相应的环化物。

In the aqueous solution, Cu precipitates with ammonium thiocyanate and tetradecyl benzyl dimethylammonium chloride .

研究发现，在水溶液中Cu与硫氰酸铵、氯化十四烷基二甲基苄基铵形成不溶于水的三元缔合物，在少量氯化钠存在下此三元缔合物沉淀浮于水相上层并与水分成界面清晰的两相，分相过程中Cu被定量浮选。

Flame—retardant resin was prepared by the condensation and polymerization of phosphoric acid, trihydroxy methyl propane and epoxy chloropropane,the resin was then reacted with hexane diacid and diglycol under certain condition ,resulting in polyol containing 1.5% P and 17— 18% polyester polyol, which was foamed with polyisocyanate, water and catalyst by one— step method, producing fire...

通过磷酸、三羟甲基丙烷和环氧氯丙烷的缩合和聚合反应制得阻燃树脂，然后将它与己二酸、一缩二乙二醇在一定条件下反应制得含P1.5%和含Cl17～18%的聚酯多元醇，再将它与多异氰酸酯、水、催化剂等组分采用一步法发泡工艺制得阻燃聚氨酯软泡塑料。

Flame— retardant resin was prepared by the condensation and polymerization of phosphoric acid, trihydroxy methyl propane and epoxy chloropropane,the resin was then reacted with hexane diacid and diglycol under certain condition ,resulting in polyol containing 1.5% P and 17— 18% polyester polyol, which was foamed with polyisocyanate, water and catalyst by one— step method, producing fire—resistant PU soft foam.

通过磷酸、三羟甲基丙烷和环氧氯丙烷的缩合和聚合反应制得阻燃树脂，然后将它与己二酸、一缩二乙二醇在一定条件下反应制得含P1.5%和含Cl17～18%的聚酯多元醇，再将它与多异氰酸酯、水、催化剂等组分采用一步法发泡工艺制得阻燃聚氨酯软泡塑料。

The optimum conditions of synthesis were determined as follows:molar ratio of 2,4-di-t-amylphenol and anhydrous trimeric acetaldehyde 2∶1.2,amount of water 180 g,amount of emulsifier 0.5 g,and amount of catalyst 11.0 g at reacting temperature 80～83℃ for 5 h.

以2 ，4-二叔戊基苯酚、无水三聚乙醛为反应原料，采用含有表面活性剂、酸性催化剂的水作为反应溶剂，缩合反应合成2，2′-亚乙基双(4，6-二叔戊基苯酚)。

The synthesis of tetracosene by dimerizing tetrapropylene with waterless AlCl 3 and a complexant as catalyst was studied.

报道了一种以无水AlCl3 和络合剂制备的络合物催化剂，用于四聚丙烯二聚合成二十四碳烯，它与无水AlCl3 单独作催化剂相比，催化剂活性大大提高。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。