二氯化合物

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

P28 紫色 Formation of a peptide bond 肽键形成–4侧链具有的反应–形成二硫键-其它反应 Tyr,His,Arg Review Isoelectric Point Titration滴定 of an amino acid 滴定 Gly幻灯片 18 His Lys Glu Reaction of amino acids Section 4 Protein isolation and purification 蛋白质分离及提纯 Working With Proteins Experimental techniques for protein analysis and characterization Purification steps A cell contains many types of proteins In the lab we want to isolate a single protein for experiments Purification steps We first grow cells or isolate tissues that contain the protein of interest We break open the cells to produce a crude extract Use centrifugation离心 to separate soluble from insoluble material We fractionate 分离 the protein mixture based on properties of such as size, charge affinity or solubility.

丹磺酰氯与氨基酸反应生成荧光性质强和稳定的磺胺衍生物，用于多肽链NH 用于多肽链 3末端氨基酸的标记烃基化反应(1) 2，4-二硝基氟苯2，4-dinitrofluorobenzene，二硝基氟苯(二硝基氟苯 DNFB也叫做试剂。DNFB在弱碱性溶液也叫做Sanger试剂试剂中与氨基酸发生取代反应，生成黄色化合物二硝基二硝基苯基氨基酸(dinitro phenyl amino acid， DNP氨基酸氨基酸)苯基氨基酸氨基酸(2)苯异硫氰酸酯(phenylisothiocyanate， PITC)在弱碱性条件下，与氨基酸反应在弱碱性条件下，生成苯乙内酰硫脲 PTH衍生物，(phenylthiohydantoin， PTH)衍生物，即PTH-氨基酸，此反应又称之Edman反应，该反应是蛋白质或多肽氨基酸序列测定常用的反应。

New compounds of the type of N--N'-(2,4-dichlorophenyloxyacetyl)-semicarbazides were synthesized by a series of reactions of preparing organic isocyanates by Curtius rearrangement with 2,4- dichloro aryloxyacetic acid hydrazide using one-pot procedures.

以芳香取代酸为原料，用Curtius重排的方法合成异氰酸酯，直接与2，4-二氯苯氧乙酰肼作用，一锅法合成了4种N-取代芳基-N'-(2，4-二氯苯氧乙酰基)氨基脲类化合物。

The model preferably predicted the photocatalytic degradation of other compounds, such as trichloroethylene, tetrachloroethylene, p -di chlorobeneze and carbon tetrachloride.

模型较好地预测了其他化合物如三氯乙烯(TCE、四氯乙烯、对-二氯苯和四氯化碳的光催化降解。

DCA, or dichloroacetic acid, is an analogue of acetic acid in which chlorine atoms replace two of the three hydrogen atoms on the methyl group.

DCA也叫二氯乙酸或二氯醋酸，是一种类似乙酸的化合物，但乙基团上有两个氢原子被氯原子所取代。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物，通过&Click chemistry&，合成了具有1，2，3-三唑环结构单元的全氟环丁基类聚芳醚；利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应，制备了具有苯基氧膦结构单元的含氟聚芳醚；通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应，得到了具有PPO结构单元的含氟聚醚酰亚胺。

Organic chlorine compounds, including hexachlorethane , pentalin , hexachlorobutadiene, HCB, pentachlorobenzene, dioxin, gammexane, tetracarp, carbon tetrachloride , chloroform and etc.

有机氯化合物，包括六氯乙烷、五氯乙烷、六氯丁二烯、六氯苯、五氯苯、二恶英、六六六、四氯乙烯、四氯化碳和氯仿等污染物。

Pyridazine was prepared by hydrogenolysis of 3,6-dichloro pyridazine obtained via chlorination of 3,6- pyridazine diol with phosphorus oxychloride.

以顺丁烯二酸酐与盐酸肼为原料经缩合成环反应生成顺丁烯二酰肼，再用三氯氧磷氯化合成3，6-二氯哒嗪，最后经催化加氢制得标题化合物哒嗪。

The thermal property studies indicate that the mass loss of compound B was 54.39% at 242.2~750℃, and when the temperature was 1000℃, there was 25.11% char residue left, which showed that the title compound has a good thermal stability and char forming capability. Using acetonitrile as the solvent instead of trichloromethane or 1, 2-dichloethane gave higher yield. During the synthesis, the yield was very low when triethylamine was used as acid acceptor alone, and when a little amount of 4-dimethylaminopyridine was added at the same time, the yield could be 81%.

结果表明，所合成的化合物B的结构与预期的结构一致；热性能研究表明，化合物B在242.2~750℃质量损失为54.39%，1000℃时仍有25.11%的炭残渣，显示出优异的热稳定性和成炭性；在相同反应条件下，用乙腈作为溶剂的反应产率比使用氯仿和二氯乙烷为溶剂的高，并且在合成过程中，单独使用三乙胺作为缚酸剂时产率很低，而当同时加入少量4-二甲氨基吡啶时，产率可达81%。

By further comparing the retention time of the profounds and that of the impurities,the main impurities in triadimefon technical was conformed as following:First, 1-(4-bromophenoxy)-3,3-dimethyl-1 -(1H-1,2,4-triazol-1 -yl)-2-butanone;Second, 1-(2,4-dichlorophenoxy)-3,3-dimethyl-1 -(1H-1,2,4-triazol-1 -yl)-2-butanone;Third, 1,1 -bis(4-chlorophenoxy)-3,3 -dimethy 1-2-butanoneour conclusion is conformed right.

再经过化合物的保留时间与杂质保留时间的比照，证实了三唑酮原药中的主要杂质是：杂质Ⅰ：1-(4-溴苯氧基)-3，3-二甲基-1-(1H-1，2，4-三氮唑-1-基)-2-丁酮；杂质Ⅱ：1-(2，4-二氯苯氧基)-3，3-二甲基-1-(1H-1，2，4-三氮唑-1-基)-2-丁酮；杂质Ⅲ：1，1-二(4-氯苯氧基)-3，3-二甲基-2-丁酮。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。