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二氧戊环

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The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法,包括单体合成和聚合物的合成,聚合物的合成是在严格无氧无水条件下,在金属钴配合物三-三苯基磷氯化钴,加入环戊二烯钠单体,随后加入双内炔或双外炔共轭单体,反应后沉淀,过滤,洗涤,真空干燥,得到含环戊二烯茂钴有机金属钴的大分子聚合物。

Three alicyclic dianhydrides, 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 1,2,4,5-cyclopentanetetracarboxylic dianhydride, and 1,2, 4, 5-cydohexane tetracarboxylic dianhydride were polymerized with two aromatic diamines, 1,4-bis (4-amino-2-trifluoromethylphenoxy) benzene (6FAPB, a) and 4, 4'-bis(4-amino-2-trifluoromethyl phenoxy) biphenyl (6FBAB, b) respectively, via a two-step polycondensation procedure to afford two series of fluorinated semi-alicyclic polyimides.

分别将脂环族二酐单体1,2,3,4-环丁烷四酸二酐、1,2,4,5-环戊烷四酸二酐和1,2,4,5-环己烷四酸二酐与芳香族含氟二胺1,4-双(4-胺基-2-三氟甲基苯氧基)苯(6FAPB, a)和4,4'-双(4-胺基-2-三氟甲基苯氧基)联苯(6FBAB, b)反应制备两个系列的含氟半脂环族聚酰亚胺,研究了PI薄膜的热性能和光学性能。

The cytotoxicity of these compounds were valuated by MTT and SRB methods using three cancer cell lines: HL-60, A-549, P-388. Cyclo-shikonin, and cyclo-alkannin have high cytotoxicity against HL-60.The chiral center of side chain has no effect on their activity. 2- 1-(Acetyloxy-4-methyl-3-pentenyl -5, 8-dihydroxy-1, 4-naphthoquinone (105) has strong inhibition effect on P-388 cells. 2- 1-(isooctyloxy-4-methyl-3-pentenyl -5, 8-dihydroxy-1, 4-naphthoquinone (108) and 2- 1-(2-furoyloxy-4-methyl-3-pentenyl -5, 8-dihydroxy-1, 4-naphthoquinone (112) have high inhibition on A-549.Shikonin (1), alkannin (2), and their derivatives have the structural features of a planar chromophores and short side chain. We examined the ability to inhibit the telomerase.

抗肿瘤活性初步筛选测试采用小鼠白血病P-388肿瘤细胞和人肺癌A-549肿瘤细胞进行,结果表明侧链羟基的手性对抗肿瘤活性无明显影响;有数个化合物具有很好的体外抑制活性,特别是化合物2-(1-异辛酰氧基-4-甲基-3-戊烯基)-5,8-二羟基-1,4-萘醌(108)和2-[1-(2-呋喃甲酰氧基)-4-甲基-3-戊烯基]-5,8-二羟基-1,4-萘醌(112)体外显示对人肺癌A-549肿瘤细胞有强效;2-(1-乙酰氧基-4-甲基-3-戊烯基)-5,8-二羟基-1,4-萘醌(105)对小鼠白血病P-388肿瘤细胞有强效;环紫草素和环异紫草素对人白血病HL-60细胞有强烈抑制作用。

Dimethicone ,Cyclopentasiloxane,Dimethicone/Vinyl Dimethicone Crosspolymer,Polysilicone-11,Glycoproteins,Panax Ginseng Root Extract,Equisetum Arvense Extract,Silica Dimethyl Silylate ,Bisabolol,Tocopheryl Acetate ,Sodium Hyaluronate,Ursolic Acid,Atelocollagen,Sodium Chondroitin Sulfate,Ethylhexyl Methoxycinnamate,Polyglyceryl-2 Tetraisostearate ,Glycerin ,Water,Alcohol,Butylene Glycol ,Lecithin,Xanthan Gum ,Mica,Fragrance ,Benzyl Alcohol,Linalool ,Hydroxycitronellal,Alpha-Isomethyl Ionone ,Amyl Cinnamal,Hexyl Cinnamal,Palm Tree Extract,Geraniol,Benzyl Benzoate,Butylphenyl Methylpropional,Phenoxyethanol,Methylparaben,Isopropylparaben,Butylparaben ,Isobutyl Paraben,Titanium Dioxide,Carmine

地美司康,环戊硅氧烷,聚二甲基硅氧烷/乙烯基聚二甲硅氧烷交联聚合物,聚硅氧烷-11,糖蛋白,人参根萃取,问荆萃取,二甲基甲硅烷基化硅石,没药醇,醋酸盐维他命E,透明质酸钠,熊果酸,去端肽胶原,硫酸盐软骨素,4-甲氧基肉桂酸-2-乙基己基酯,聚甘油-2 四异硬脂酸酯,甘油,水,酒精,丁二醇,卵磷脂,山羊胶,云母,香料,苯甲醇,沉香醇,羟基香茅醛,α异甲基紫罗酮,戊基肉桂醛,己基肉桂醛,棕榈树萃取,香叶醇,苯甲酸苯甲酯,丁苯基甲基丙醛,苯氧乙醇,羟苯甲酯,羟苯丙酯,羟苯丁酯,二氧化钛,胭脂虫红

My company can provide pesticide, medicine, veterinary medicine intermediates, have 48 kinds of products (p-Bromo-p-Bromotoluene bromoform 1 - bromo-heptane Triethyl Citrate 1,2,3 - three Bromopropane 3 - Chlorine -4 - fluoro bromobenzene Bromotoluene ethylbenzene 4 - bromo -2 - bromo-ethyl-Chloroaniline 2 - bromo--5 - chloro-toluene 3 - bromo-C methyl 1,6 - dibromo-hexane 1 - bromo --4 - p-methoxy benzaldehyde o-bromo-acetic acid propyl bromide p-fluorotoluene dodecane four bromoethane of iodine bromide toluene tert-butane Tributyl Citrate 2 - bromo-p inter - Hydroxybenzaldehyde bromine butane 2 - bromo-propionic acid bromide veratryl aldehyde inter-bromo-trifluoro-n-hexane of toluene on Bromoxynil Bromotoluene toluene ethylbenzene o-bromophenol bromide Cyclohexane Cyclopentane bran bromate bromide Malay Dibutyl Ethyl Lactate Propylene between bromine bromine bromine between aniline o-anisidine o-fluorophenol difluorobenzonitrile to aminobenzaldehyde Bromotoluene aniline on Bromobenzaldehyde Bromotoluene acid) expressed the hope that customers contact us!

我公司可提供农药,医药,兽药中间体,有四十八种产品(对溴苯酚对溴甲苯溴仿 1-溴庚烷柠檬酸三乙酯 1,2,3-三溴丙烷 3-氯-4-氟溴苯对溴乙苯 4-溴-2-氯苯胺溴乙酸乙酯 2-溴-5-氯甲苯 3-溴丙酸甲酯 1,6-二溴己烷 1-溴-4-硝基苯邻甲氧基苯甲醛溴乙酸丙酯对氟甲苯溴代十二烷对碘甲苯四溴乙烷溴代叔丁烷柠檬酸三丁酯 2-溴氯苯间羟基苯甲醛溴丁烷 2-溴丙酸黎芦醛溴已烷间溴三氟甲苯对溴苯腈对溴乙苯邻溴甲苯溴代环已烷溴代环戊烷糠溴酸马来酸二丁酯溴丙烯乳酸乙酯间溴苯胺间溴苯甲醚邻氟苯酚邻氟苯腈对氨基苯甲醛对溴苯胺对溴苯甲醛对溴苯甲酸)希望广大客户与我司联系!

Mainly engaged in: Hydrogen-imide hydrochloride, o-chlorophenyl cyclopentanone, 3.4 dimethoxy ethyl benzene, butyn single potassium acid, potassium ethyl malonyl, Ding amide, amide isobutyraldehyde , allyl chloroacetate, isopropyl chloroacetate Benzyl aluminum, cyclopentene, cyanide-o-chlorophenyl, o-methyl chloride, sulfuric acid chloride, p-chlorophenol, imidazole, Pinacolone, one chlorine Pinacolone.

主要经营:盐酸氢亚胺、邻氯苯基环戊酮、3.4二甲氧基苯乙酯、丁炔二酸单钾盐、丙二酸单乙酯钾盐、丁酰胺、异丁酰胺、氯乙酸烯丙酯、氯乙酸苄酯异丙醇铝、环戊烯、邻氯苯氰、邻氯苯甲酯氯、硫酸氯、对氯苯酚、咪唑、频呐酮、一氯频呐酮。

Water,caprylic/capric triglyceride,mineral oil,butylene glycol,stearic acid,acetylated lanolin,glycerin,ethylhexyl methoxycinnamate,dimethicone,polyisoprene,triethanolamine,cyclopentasiloxane,butyl methoxydibenzoylmethane,titanium dioxide,persea gratissima oil unsaponifiables,sodium DNA,borago officinalis seed oil,oenothera biennis oil,simmondsia chinensisseed oil,hydrolyzed RNA,tocopheryl acetate,urea,hydrolyzed extensin,retinyl palmitate,sodium hyaluronate,helianthus annuusseed oil,tocopherol,ascorbyl palmitate,ascorbic acid,lanolin alcohol,c12-20 acid peg-8 ester,cyclotetrasiloxane,glyceryl stearate,dimethiconol,ceteareth-20,carbomer,magnesium aluminum silicate,propylene glycol,peg-8,silica,BHT,citric acid,phenoxyethanol,methylparaben,butylparaben,ethylparaben,isobutylparaben,propylparaben,chlorhexidine digluconate

水,辛酸/癸酸三酸甘油酯,矿物油,丁二醇,硬脂酸,乙醯化羊毛脂,甘油,4-甲氧基肉桂酸-2-乙基己基酯,地美司康,聚异戊烯,三乙醇胺,环戊硅氧烷,丁基甲氧基二苯甲醯基甲烷,二氧化钛,酪梨油,DNA 钠盐,琉璃苣種子植物油,月见草油,荷荷巴籽油,水解RNA,醋酸盐维他命E,尿素,水解伸展蛋白,维他命A酯,透明质酸钠,葵花籽油,维生素E,抗坏血酸棕榈酸酯,维生素C衍生物,羊毛脂醇,C12-20 酸 PEG-8酯,环四硅氧烷,甘油硬脂酸,聚二甲基硅氧烷醇,鲸蜡硬脂醇醚-20,卡波姆,硅酸镁铝,丙二醇,聚乙二醇-8,二氧化硅,二丁基羟基甲苯,柠檬酸,苯氧乙醇,羟苯甲酯,羟苯丁酯,羟苯乙酯,羟苯甲酸异丁酯,羟苯丙酯,洗必泰葡萄糖酸盐

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1,2-氧硼杂环戊烷与〓反应,再经PCC氧化,分子内缩合得到二氢茉莉酮。1,2-氧硼杂环戊烷的C-B键除氧化断裂之外,也能够在〓或KF作用下卤化断裂成碳卤键。

Advances in Research on Plants Reactions under Phosphate Starvation;2. Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述,综述重点是这类化合物的官能团M≡M参键的化学活性,全文包括R_2M_2_4的合成及结构,M≡M叁键与亲核试剂、与碳-碳重键,与氧或与金属羰基物等试剂的反应及其应用。

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