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They have close relationship as the former may provide new ideas and approaches for the later, while the later may be the simulation for the former and gives it helps in degradation products identification and mechanism explanation. It is necessary to choose a suitable system, which has high potential of treating EDs and close relationship to the natural environment, to combine the researches in the two aspects. Our group has been engaged in researches on the photochemical properties and application to water pollution control of different ferric species including Fe -OH complexes, Fe -polycarboxylate complexes, Ferric oxides and Fe -humic acid complexes. Fe -oxalate complexes system has higher efficiency than the other ferric species systems in photooxidation and degradation of organic compounds. This thesis is focused on the photodegradation of nine EDs estradiol (E2), estrone (E1), 17α-ethynyl estradiol (EE2), diethylstilbestrol , bisphenol-A , 4-Nonylphenol , 4-Octylphenol , di-n-butyl phthalate , and di (2-ethylhexyl) phthalate .

因此从处理效率和环境化学意义两方面考虑,结合本课题组在不同铁形态(包括Fe-OH配合物、Fe-多羧酸配合物、Fe氧化物、Fe-腐殖酸配合物等)的光化学特性及其在水污染控制中的应用方面较系统的研究工作基础,本论文选择了四类共9种典型的内分泌干扰物(雌二醇(E2)、雌酮(E1)、17α-乙炔基雌二醇(EE2)己雌酚、双酚A、壬基酚、辛基酚、酞酸二丁酯和酞酸二乙基己基酯),研究了它们在Fe-草酸盐配合物体系中的光降解效果,推测其降解机理,探索环境内分泌干扰物光氧化处理的新体系,同时为预测其在环境中的光降解行为提供了依据。

Metallurgy School, UST Beijing, Beijing 100083, China)ABSTRACT The negative thermal expansion in some complex oxides has beenattributed to transverse thermal motion of A-O-M linkage composed of two-coordinate oxygenbridge bond, and the librationsand tilts of essentially rigid polyhedral blocks in openframework structure. The isotopic NTE materials have been finding moresubstantialapplications in composites and other relative technique fields.

氧化物材料负热膨胀机理邢献然摘要氧化物的负热膨胀性是由于在其开放式的骨架结构中,有二配位的桥氧键产生横向热运动,以及引起的多面体热摆动和耦合作用使非键合M-M1键距变短,导致单胞体积缩小;各向同性NTE氧化物在复合材料及其相关技术领域具有更广泛的应用价值。

Diamino-3,5-dinitropyridine and 2,6-diamino-3,5-dinitropyridine-1-oxide was reacted with aqueous ammonia and KMnO4 under different conditions. Substitutions in the 4 position to the nitro group were obtained with high yields: 2,4,6-triamino-3,5-dinitropyridine (81.5%) and 2,4,6-triamino-3,5-dinitropyridine-1-oxide (85.4%).

以氨水为胺化剂,KMnO4为氧化剂,在不同反应条件下实现2,6-二氨基-3,5-二硝基吡啶和2,6-二氨基-3,5-二硝基吡啶-1-氧化物4位的氧化胺化反应,目标化合物2,4,6-三氨基-3,5-二硝基吡啶和2,4,6-三氨基-3,5-二硝基吡啶-1-氧化物的收率分别达到81.5%和85.4%。

There was a little difference betweenphotosynthesis characteristic of the two varieties,response of Jiamusi to low temperature andpoor light was more sensitive than that of Longjiao No.2 and decreased pronouncedly withdecreasing light.6.EC and MDA of pepper leaves increased under low temperature and poor light,therewere no significant differences between them with decreasing light at 21-23℃/8-10℃,butthey were increased dramatically at 15-20℃/5-6℃.So we can speculate that lowertemperature was the direct reason resulted in cell membrane lipid peroxidation.7.No significant difference of SOD activity was observed under suboptimal temperatureand poor light21-23℃/8-10℃;150μmol·m~(-2·s~(-1),but SOD and POD activity substantiallydeclined with lowering temperature and light as well as treatment time.8.Under suboptimal temperature and lower light,proline accumulated to increaseosmotic regulation capacity and alleviate chilling damage.Soluble carbohydrate of pepper leaves decreased progressively and significantly with decreasing temperature and lightintensity as well as longer treatment time.So we think that synthesis and transport ofphotosynthetic product were inhibited by low temperature and poor light as solublecarbohydrate was important component of photosynthetic product.

两个供试辣椒品种之间的光合特性略有差异,佳木斯对低温弱光的反应比陇椒2号敏感,尤其随光照降低,其光合作用显著降低。6、低温弱光胁迫下,辣椒叶片的相对电导率和丙二醛含量都有不同程度的提高,在偏低温下,随着光照减弱,相对电导率和丙二醛含量差异不显著;在极端低温下,随着光照进一步减弱,相对电导率和丙二醛含量明显提高,随着处理时间延长,同一温度下,随着光照降低,叶片丙二醛含量也显著增加,由此可初步判断,低温是导致细胞膜脂过氧化的直接原因。7、经偏低温较弱光21~23℃/8~10℃、150μmol·m~(-2·s~(-1)处理后,辣椒叶片的超氧化物歧化酶活性变化与对照无显著差异,但随着温度、光强的逐步降低和处理时间的延长,SOD、POD活性显著降低。8、在偏低温较弱光下,辣椒能积累更多的脯氨酸,增强渗透调节,减轻低温冷害。

In the first part, two novel methods were proposed for the determination of three kinds of organogermanium compounds βcarboxyethylgermanium sesquioxide,β- carboxyethylgermanium sesquioxide and di-(β-carboxyethyl) germanium hydroxide by using high performance ion-exchange and ion-exclusion chromatography.

第一部分采用高效离子交换和离子排斥色谱法,建立了两种测定三种有机锗化合物β-羧乙基锗倍半氧化物、β-羧乙基锗倍半氧化物、二-锗氢氧化物的新方法。

It is found that the increase in the diameter of oxide which grows during solidification is larger when the size of oxide before solidification and cooling rate during solidi...

此外,可以根据冷却速率和凝固后氧化物的直径判断氧化物是凝固前形成的一次氧化物还是凝固过程中产生的二次氧化物。

Moreover, its application as microwaveabsorber was primarily studied which lays a solid foundation for further investigations.The content, results and originalities of this research are as follows:1.3D self-assembled flowerlike hierarchical spheres of MnO_2 andγ-MnOOH nanobelts were prepared by a simple hydrothermal method, using KMnO_4 and H_2O as reactants, without any templates and surfactants.

本论文以倡导绿色环保为时代背景、以纳米科技的飞速发展为科学背景、以锰氧化物在二次电池和微波吸收领域的应用为着眼点,着重研究了各种不同形貌锰氧化物低维纳米材料的制备、生长机制及形貌控制,并初步研究了锰氧化物纳米材料的微波吸收特性,为进一步深入研究奠定基础。

These results indicate that cabbage phenolic extract and single phenolic acids,i.e.Ferulic acid,Sinapinic acid and Gallic acid,etc.

研究表明,卷心菜提取物以及单个酚酸(儿茶素、阿魏酸和香豆酸)可以抑制〓、〓—7,8—二氢二醇和四氯化碳在肝微粒体作用下的代谢,降低主要代谢产物〓—7,8—二氢二醇、〓—7,8—二氢二醇—9,10一环氧化物和丙二醛的生成量。

The current research status of metal oxides is described in detail, including titanium dioxides, manganese oxides iron oxides, cobalt oxides, copper oxides, zinc oxides, other metal oxides with single element and multiple elements metal oxides, along with the results obtained in our groups.

结合本课题组的研究成果,按照二氧化钦、锰氧化物、铁氧化物、钴氧化物、氧化铜、氧化锌、其他单一金属氧化物和多组分掺杂金属氧化物等顺序对其催化臭氧机理进行了阐述,并对今后催化臭氧的研究与应用进行了展望。

It is evolved in transforming epoxides into compounds with decreased chemical reactivity, increased water solubility [141], and altered biological activity by the addition of water.

它通过化学催化转化的方式降低外源环氧化物在体内的含量,保护细胞免受环氧化物的毒性,同时也代谢内源性脂肪足和芳香族环氧化物,生成对应的二醇[141]。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

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