二基取代了的

The efficient first asymmetric syntheses of-6β-hydroxy-7αH-eudesm-4-en-3-one, and its C-6 epimer were achieved starting from-dihydrocarvone, whichprovide a novel and efficient synthetic method to 6-oxgenated eudesmanes.

以-二氢香芹酮为原料，经五步反应，首次完成了6β-羟基-4(5)-烯-3-羰基桉烷及其6位差向异构体的立体选择合成，并为C-6位含氧官能团取代桉烷类化合物的合成提供了一种简便有效的方法。

Using 2,4,6-〓 as phase-transfer catalyst, ten symmetrical azobenzene were prepared with a saturated solution of potassium ferricyanide in 2N aqueous potassium hydroxide and dichloromethane.

用2，4，6-三叔丁基苯酚为相转移催化剂，芳胺类化合物在饱和铁氰化钾的氢氧化钾溶液和二氯甲烷的两相转移催化下合成了10个对称取代偶氮苯，并对反应机理也做了合理的解释。

In this paper, PPVs derivatives with alkoxyl as side-chain and PPVs derivatives containing oxadizole were synthesized; the monomers and polymers were characterized as well. It was studied systemically the influence of component and molecular structure of main-chain and side-chain or side-groups on polymer solubility, electroluminescent and photoluminescent properties, thermostability, and light-emission device performance.

合成了烷氧取代以及主链中含有噁二唑的PPV衍生物，详细研究了各种单体和相关聚合物的合成并对其结构与性能进行了表征，系统研究了聚合物主链、侧链或侧基的组成与结构特征对聚合物的可溶性、电致发光特性、光致发光特性、耐热性以及电致发光器件性能的影响。

In this dissertation, I will represent my studies on the nitration of Chalcone derivatives, reaction of epoxide ketone, and the aromatization of 3,5-disubstitued 2-isoxazolines with nitric oxide.

本文主要研究了：(1)NO与查尔酮及其衍生物的硝化反应，反应以较高的产率得到了a-硝基化合物；(2)NO对环氧酮的开环反应，反应生成了顺式羟基硝酸酯；(3)3，5-二取代的-2-异恶唑啉在NO作用下可以发生芳环化反应，生成了对应的2-异恶唑化合物。

The new reaction of disubstituted phosphinosilane would be available in many organic syntheses.

这类新型反应为二取代膦基硅烷类化合物的研究开辟了新方向。

Starting from 4-androstenedione, three novel 3-oxo-4-aza-5-androstene-17-oxime derivatives 7, 8 and 9 were synthesized through oxidation ring cleavage, amination ring closure, oximation,and substitution .

以4雄烯二酮为起始原料，经过氧化开环、氨解闭环、肟化、取代等4-步反应，合成了3个新的3-羰基-4-氮杂-5-雄甾烯-17肟衍生物7、8和9，并用质谱、1HNMR、13CNMR等测试手段对目标化合物的结构进行了表征

To explore new synthetic methods, we set out a careful investigation of the reaction of benzimidazolium salt with many nucleophilic agents, including the active aromatic compounds and heteratom nucleophilic agents, and found that the quaternary C=N is not so active; when benzimidazolium salt is reacted with big nitrogen nucleophilic agent? phthalimide, it does not give the expected addition product, instead, produces N-alkyl phthalimide through alkyl-transfermation from benzimidazolium salt to phthalimide.

为了开发新的合成方法，研究了苯并咪唑盐与各种亲核试剂（活泼芳环与杂原子亲核试剂）的反应，发现苯并咪唑盐不与活泼芳环及杂原子亲核试剂发生2位加成反应；在与体积较大的位阻型N亲核试剂邻苯二甲酚亚胺反应时，未得到亲核试剂与极化的C＝N的加成产物，而是得到N烷基化的邻苯二甲酰亚胺，进一步研究表明，苯并咪唑盐将1（3）位N上的烷基转移给了邻苯二甲酰亚胺，并讨论了其反应机理和取代基，溶剂效应。

This paper compared two kinds of rose families sorbus of different effective spots of total flavonids content. We get a better process of total flavonoids abstraction from the branch of Sorbus tianschanica,.Under the best process of total flavnoids ,two flavnoids were isolated from them. Preliminary affirmed two kinds of compounds belong to flavanone, two kinds of structure just substituent had a dissimilarity separately. This thesis was a part of a national natural science fund to subsidize.

除此，本论文还对新疆天山花楸的枝干总黄酮的提取工艺进行了研究，得到了最佳提取工艺，在最佳提取工艺的条件下对新疆天山花楸的枝干进行了系统的提取和硅胶柱层析，得到两种化合物，初步认定两种化合物属于二氢黄酮类，两种化合物的结构相似，只是个别取代基有所不同，本论文是国家自然科学基金资助项目。

A series of 3,5-disubstituted chiral hydantoins were prepared from D-amino acid and phenyl isocyanate in mixed solvent, and the catalyst was then supported on macroporous adsorption resins.

摘 要：以混合溶剂法由D 氨基酸和异氰酸酯制备一系列3，5 二取代手性海因，用大孔吸附树脂作载体，制成固载型手性催化剂，并考察了不同结构手性海因化合物在3 苯氧基苯甲醛氰醇化反应中的催化活性。

Finally, N ethey[3,3 dimethyl spiralindoline naphthoxazine]was synthesized by the addition of 1 nitroso 2 naphthol also,the photochromic mechanism of the substance and its photochromic phenomenon in ethanol were studied.

报道了以苯肼和 3 甲基 2 丁酮为原料首先合成 2 ，3 ，3 三甲基吲哚，吲哚再与碘乙烷亲核取代，碱化得费舍尔碱，最后与 1 亚硝基 2 萘酚作用合成N 乙基 [3 ，3 二甲基螺吲哚啉萘并恶嗪 ]的全过程，并研究了该物质的变色机理以及在乙醇溶剂中的光致变色现

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。