二基取代了的

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

Hydroxyl octanoic acid(1) was synthesized from heptaldehyde by a four-step reaction of nucleophilic substitution,displacement reaction,acid hydrolysis and deaminization.

以正庚醛为原料，经过亲核取代、置换反应、酸水解及碱化脱氨等4步反应合成了制备3，6-二己基-1，4-二氧杂-2，5-二酮的中间体——α-羟基辛酸(1)；1经对甲苯磺酸催化脱水得辛交酯。

Aniline compounds containing heptafluoroisopropyl was synthesized through taking sodium dithionite as evocating agent, and introducing heptafluoroisopropyl by free radical electrophilic substitution on benzene ring.

以连二亚硫酸钠为引发剂，在苯环上通过自由基亲电取代反应引入七氟异丙基，合成了一系列含七氟异丙基的苯胺类衍生物，研究了各种条件对反应的速度和收率的影响。

In this dissertation, two derivatives of aniline containing polyoxyethylene substituent m-phenylene diamino formyl alkylenediamine poly acetate and poly-3-aminobenzoate were designed and synthesized. And then, comb-shaped polyaniline grafted by PEO were prepared by chemical oxidation copolymerization. The structure of copolymers were characterized by FTIR, ultraviolet-visible spectrum, elemental analysis and TEM etc..

本文在设计并合成两种含聚氧乙烯取代基的苯胺衍生物——间苯二氨基甲酰己二氨基甲酸聚氧乙烯乙酸酯和3-聚氧化乙烯单甲醚基苯胺的基础上，采用化学氧化法将它们与苯胺进行共聚，制备出了聚氧乙烯接枝聚苯胺的梳型共聚物。

The structures and nonlinear second-order optical properties of phenothiazine derivatives substituted at nitrogen by different substituents have been studied.

研究了各种取代基在吩噻嗪的氮上取代后衍生物的结构和二阶非线性光学系数。

Methods Using 4-chloro-2-nitroaniline as a starting compound, followed by substitution, reductive cyclization, oxidation, and chlorination, to give the key intermediate 2,7-dichloroquinoxaline (7), which reacted with different phenolic compounds to afford quinoxaline derivatives.

方法以4氯2硝基苯胺为起始原料经取代、还原关环、氧化、和氯代合成了中间体2，7二氯喹喔啉(7)，再在喹喔啉的2位引入不同的取代酚结构单元，合成了一系列共9个新喹喔啉衍生物。

Bifluoro nitrobenzene was the raw material of synthesis of asymmetry chromotropic acid bisazo fluoroarsen reagent, By way of ammonia substitution, arsonation, reduction and coupled reactions, bisazo fluoroarsen was synthesized.

以2，4—二氟硝基苯为起始原料，经过氨取代、胂酸化、还原、偶联反应合成了偶氮氟胂Ⅰ，然后分别选择不同的取代苯胺与偶氮氟胂Ⅰ偶联，合成了一系列的不对称变色酸偶氮氟胂。

Double chain naphthyurea/thiourea piperazine derivatives complex with linear dicarboxylate anions with a high stability constant and 1∶1 stoichiometry of the complex-and the complex was formed through six hydrogen bonds.2 Photophysical behaviors and anion binding of three N,N-dimethylaminochalcone derivatives were studied.

二研究了三种N，N-二甲基氨基查耳酮衍生物的光物理行为及与阴离子的结合能力。4'位不同的取代基-氨基和苯脲基对查耳酮的的分子内电荷转移能力有一定的影响，它们减弱了查耳酮衍生物的分子内电荷转移能力，导致发射光谱蓝移。

A new monomer,4-hexanoxyl-4′-undecylene-[10]-acyloxyazobenzene was synthesized using the main materials:phenol,underlenic acid,1-bromo- n -hexane, p -nitrophenol,thionyl chloride,by the substitution,reduction,couping and diazotization methods.A new polymer was prepared by hydrosilation reaction of poly (methylhy-drosiloxane) with the monomer.

以苯酚、十一烯酸、正溴己烷、对硝基苯酚和二氯亚砜为主要原料，通过取代、还原、重氮化和偶合等反应，合成了一种新的液晶单体 4-己氧基-4′-十一烯-[10]-酰氧基偶氮苯，并与聚通过硅氢加成生成一种新的高分子液晶。

In this thesis, synthesis of fluoroalkyl-containing heterocycles from rhodium acetate catalyzed reactions of fluorinated α-diazo-β-ketoestes were studied in detail.

本论文系统地研究了氟烷基和二氟亚甲基取代的α-重氮羰基化合物的合成及其在醋酸铑催化下的反应。由此合成了一系列氟烷基和少氟取代的杂环化合物。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。