二基取代了的

In the reaction of substituted arylamine and sulfuric acid, and utilizes the feature of that said inert organic solvent is easy to form azeotrope with water to continuously deliver the water produced in the couse of reaction from the reactor.

本发明在取代芳胺与硫酸的反应中加入了一种惰性的有机溶剂，如：氯苯，二氯苯，三氯苯，硝基苯等，利用其易与水形成共沸物的特点，将反应生成的水不断地导出反应器。

In order to explore the relationship between structure and properties of hydroxyalkyl cellulose ether nitrate, molecular structures of nitrate ester of hydroxylethyl cellulose ether, nitrate ester of hydroxylpropyl cellulose and nitrate ester of cellulose glycerol ether with molar substitution of 1 were simulated by using Synthia module of Materials Studio, and their performances of nitrogen content, glass transition temperature and Young's modulus were predicted.

为探索羟烷基纤维素醚硝酸酯的结构与性能关系，借助Materials Studio软件中的Synthia模块模拟了摩尔取代度为1的羟乙基纤维素醚硝酸酯、羟丙基纤维素醚硝酸酯和二羟丙氧纤维素醚硝酸酯的结构，并预测了它们的含氮量、玻璃化转变温度和杨氏模量。

Three ketocoumarin dyes that has different substituent at 3-position were synthesized and the spectroscopic properties were investigated.

二。香豆素染料吸收与发射光谱的性质及作为荧光极性探针的研究合成了3个3-位不同取代基的香豆素染料，研究了它们在不同环境下的吸收与发射的光谱性质。

The effects of 1, 4-dinitropiperazine on the combustion characteristics and thermolysis of CMDB propellants were studied by differential scanning calorimetry and burning rate test.

用燃速测试和高压差示扫描量热法试验，研究了 N，N -二硝基哌嗪逐渐取代改性双基推进剂中的黑索今后，对推进剂燃烧性能和热分解特性的影响。

Second, using DBU as the base for enolization of propargylic esters of unsaturated acids 18e-k, we developed a tandem Ireland-Claisen rearrangement /isomerization reactions. It has been shown that the reaction sequence affords triene molecules 42a-b and 43a-b in moderated to high yields. Interestingly, with allyl hexa-3,5-dienoates 18i-j as the substrate, the rearranged products underwent further aromatization to give uniquely substituted benzyl acids 44a-b.

其次，以含有活泼质子的烯酸炔丙酯18e-k为底物，在DBU为烯醇化碱、TMSCl为硅试剂的条件下，底物18e-h发生了Ireland-Claisen重排/异构化串联反应，得到完全共轭的三烯类化合物42a-b及43a-b；而以己二烯酸炔丙基酯18i-j为底物时，重排/异构化后的产物进一步发生电环化等反应最终得到芳构化产物——取代苯甲酸类化合物44a-b。

This protocol could also be used for the selective reduction of the endocyclic double bond of the 3-electron withdrawing group substituted coumarins. This method is clean, mild, and efficient.2 ZrCl_4 / HEH was found to be a selective and efficient reagent combination for the direct reductive amination of electron rich aldehydes and ketones with weakly basic amines after scanning various catalysts such as InCl_3, BiCl_3, CF_3COOH and so on.

图一 1。我们用汉斯酯作为有机还原剂，乙醇为溶剂，实现了4-甲叉基噁嗯唑酮和吡唑酮环外双键的高选择性还原；此外，我们还将这一还原体系用于3-吸电子集团取代-3，4-二氢香豆素环内双键的选择性还原。

The nano-ionic liquid containing metal complex could be an effective catalyst for oxidative carbonylation of amines to carbamates and disubstituted ureas and for synthesis of unsymmetric ureas from amines and nitrobenzene, in which turn over frequencies exceeded 10000mol/mol/h.

以该系列纳米离子液体为催化剂高效的实现了胺类化合物催化氧化羰化制备氨基甲酸酯和二取代脲（转化频率＞10000mol/mol/h）以及胺与硝基苯通过一氧化碳羰化制备不对称脲的过程。

Three methods for the preparation of 1,2,4-trizolone~5 are provided. 22 compounds are prepared. 3, 4-disubstituted 1,2,4-trizolone-5 is prepared by reacting amide with ethyl hydrazine-fornate at 110癈 for 3h in the presence of phosphorus oxychloride, following neutralization and cyclization reaction, giving to 74.5 % yields,which is 30% more than the literature value.

以三氯氧磷为缩合剂，使酰胺和肼基甲酸乙酯在110℃反应3h，经碱中和、环化反应，合成3，4-二取代-1，2，4-三唑酮-5，两步反应总产率达74.5％，与文献报道值相比，高出了30％以上，在三唑酮类衍生物的合成方法中具有很大的突破性。

Using free radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as catalyst, the phase transfer catalyzed method of oxidation of anilines to 15 symmetrical azobenzenes with a saturated solution of potassium ferricyanide in 2N aqueous potassium hydroxide and dichloromethane was described for the first time.

用2，2，6，6-四甲基-4-羟基-1-哌啶氮氧自由基为催化剂，芳胺类化合物在饱和铁氰化钾的氢氧化钾溶液和二氯甲烷的两相转移催化下合成了15 个对称取代偶氮苯。

Density functional theory calculations at the B3LYP/6-31G level of theory were employed to study the mechanism and the potential energy surface of Diels-Alder reactions between Lewis base stabilized borabenzene and dienophiles.

采用密度泛函理论方法在B3LYP/6-31G水平上研究了Lewis碱稳定的硼代苯与一些亲二烯体的两种可能的Diels-Alder反应的微观机理和势能剖面，并研究了反应的溶剂效应和取代基效应。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。