二十二烷

The macrocyclic polyamines are a kind of excellent ligands and have a substantially high binding affinity with transition metal ions. Macrocyclic polyamine metal complexes as enzyme models are widely used in chemical biology, medicine and gene therapy. 1, 4, 7, 10-tetrazacyclododecane is a representative macrocyclic polyamines compound and shows high binding affinity with transition metal ions, such as Zn, Cu and Co. Their metal complexes especially multinuclear complexes were widely used in DNA, RNA recognition.

大环多胺化合物是一类性质独特的优秀配体，具有良好的金属配位能力，其金属配合物作为人工酶模型广泛应用于核酸结构及功能研究、基因表达与调控、抗癌药物的研制等生物、化学和医学领域。1，4，7，10-四氮杂十二烷是典型的大环多胺化合物，对过渡金属离子Zn， Cu and Co有良好的配位能力，这些金属配合物特别是多核金属配合物被广泛应用于DNA识别中。

The measurement of apparent volume change is described during cure reaction of a new spiro ortho -carbonate, 3, 9, di (p-methooxybenzyl)- 1, 5, 7, 11-tetraoxspiro (5,5) undecaneand epoxy resin, and the volume expansion ratio of this new monomer is culcu-lated,and its applications are approached.

叙述了新的螺环化合物3，9-二-1，5，7，11-四氧杂螺环[5，5]十一烷与环氧树脂进行固化反应时，其表现体积变化率的侧定方法，推算了这种新单体的体积膨胀率。

In Chapter 2, the study on PET of the donor/acceptor pair via the rigid bridge, heptacyclo [6.6.0.02,6.03,13.04,11.05,9.010,14] tetradecane, is presented. By using the GMH method, the electronic coupling matrix elements between ground and excited states are predicted.

在第二章，我们研究了对七环十四烷连接儿茶酚和二氰基乙烯构建的分子内光诱导电子转移体系；考察了吸收光谱随溶剂极性变化的影响，预测了该体系的电子转移机理，并利用广义的Mulliken-Hush公式，计算了基态和各激发态之间的电子转移耦合矩阵元。

A method is introduced for quantitative determination of 1,2-dichloride ethylane by gas chromatography with PEG-20M chromatographic column,FID and using undecane as internal standard.

介绍用气相色谱仪、以PEG-20M色谱柱和FID检测器对1，2-二氯乙烷进行的一种定量测定方法，其内标物选用正十一烷。

Synergisms of zwitterionic surfactant between the mixed surfactant system of SDS/ C12-C12 were investigated.

采用界面张力法考察了两性表面活性剂C12-C12在癸烷中与十二烷基硫酸钠的协同作用。

In addition, a further study was made of the technique of extraction, isolation and purification of GLA. The factional extraction used in the laboratory with n-hexane and ethanol was changed into the whole extraction of 6〓 solvent, which simplified production technique and reduced cost of production. The fungal lipid extracted from the fermentation in the medium-scale test was concentrated by the urea adducting method with methanol as solvent, at 75～80℃ for 3 hours. After GLA had been adducted twice, the content of GLA came up to 84. 25%, around a twelfth as much as the original concentration.

并对γ—亚麻酸的提取和分离纯化工艺进行了研究，将实验室中用正己烷和乙醇分步抽提的工艺改为用6〓溶剂一步抽提技术，从而简化了生产工艺，降低了生产成本；采用脲素包合法，以甲醇作为溶剂，温度控制在75～80℃，包合时间为3h，对中试发酵所提取的菌油进行了浓缩，γ—亚麻酸两次包合后，GLA含量达到84.25%，比原浓度浓缩了近十二倍。

Aluminum ; Acetone ; 2; 15-Hexadecanedion ; Computer simulation ; Aldol condensation

氧化铝；丙酮； 2； 15－十六烷二酮；计算机模拟；醛醇缩合

In order to study the aldol condensation of 2,15-hexadecanedione on the surface of aluminium, the intermolecular condensationmechanism of acetone occurring on aluminum was simulated by usingsemi-empirical AM1 method embodied in MOPAC 6.0 program package.

为了研究2，15-十六烷二酮在氧化铝表面的环合机理，选择小分子丙酮为模型化合物，用量子化学半经验AM1方法研究双分子丙酮在氧化铝表面的醛醇缩合机理。

In order to study the aldol condensation of 2.15-hexadecanedione on the surface of aluminium, the intermolecular condensation mechanism of acetone occurring on aluminum was simulated by using semi-empirical AM1 method embodied in MOPAC 6.0 program package. The optimized structures and geometry parameters of 5 transition complexes and 4 intermediates were given.First, 2 molecules of acetone coordinated with aluminum by electrostatic attraction.One atom of hydrogen of acetone migrated to aluminum because of t...

为了研究2，15－十六烷二酮在氧化铝表面的环合机理，选择小分子丙酮为模型化合物，用量子化学半经验AM1方法研究双分子丙酮在氧化铝表面的醛醇缩合机理，给出了反应过程中的5个过渡态和4个中间体的结构和几何参数，该催化反应可以认为是氧化铝分子与两分子丙酮分子发生静电络合作用，然后借助氧原子的负电荷导致脱氢并实现缩合，根据中间体的能量变化，推测有较稳定的铝复合物生成。

It is shown that the sphere-like body-centered cubic Eu2O3 and monoclinic Sm2O3 nanoparticles obtained with sodium dodecylsulfate as surfactant and the rod-like orthorhombic Eu2O3 and body-centered cubic Sm2O3 nanoparticles fabricated with polyvinylpyrrolidone as surfactant possessed a BET surface area of 44~49 and 34~37m^2/g, respectively.

结果表明，以十二烷基硫酸钠作表面活性剂所得产物为类球状体心立方晶相Eu2O3和单斜晶相Sm2O3纳米粒子，比表面积为44~49 平方公尺/g；而以聚乙烯吡咯烷酮作表面活性剂所得产物则是棒状正交晶相Eu2O3和体心立方晶相Sm2O3纳米粒子，比表面积为3437 平方公尺/g。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。