二十七烷

Thereinto, the content of eucalyptus oil was the most with 27.20%, the next was Terpinen-4-OL (21.27%), N-methyl-laurotetanine (6.32%), Hepladecanoic acid (4.33%), Phytol (3.53%), Ether linoleic acid (3.45%), 2,6-dimethyl-2,6-octadiene (2.96%) and so on.

其中，含量最高的是桉油(27.20%)，其次是松油烯－4-醇(21.27%)、N甲基山鸡椒痉挛碱(6.32%)、十七烷酸(4.33%)、叶绿醇(3.53%)、乙醚基亚油酸(3.45%)、2，6－二甲基－2，6-辛二烯(2.96%)等。

On the basis of the gas chromatographic analysis of n-alkane fingerprint, the method achieved good reliability with selecting seme characteristic alkanes (i.e.n-C17, n-C18, n-C20, pristane and phytane) as the criteria of identifying. The whole procedure was simple and facile while expending short time.

该鉴别方法基于样品的正构烷烃气相色谱指纹分析，选择既能表征油种固有特性，又受风化影响较小的正十七烷n-C_(17、正十八烷n-C_(18、姥鲛烷、植烷和正二十烷n-C_(20等特征烷烃作为判据，可信度大，而且整个操作流程短，较简便易行。

The results showed that the unsaturated fatty acid content of pecan kernel oil was 89 0%,and 13 kinds of unknown components such as nonadecaol,8 hexyl pentadecane,10 methyl eicosane,11,14 eicosadienoic acid,1 bromo 8 heptadecyne,9 hexyl heptadecane,tetracosane,13 docosenoic acid,1 bromo 7 nonadecyne,15 tetracosenoic acid,hexacosanoic acid,7 hexyl ei...

研究结果表明：山核桃仁油中的不饱和脂肪酸 w =89 0 %，未知成分是十九醇、8 己基十五烷、10 甲基二十烷、11，14 二十碳二烯酸、1溴 8 十七炔、9 己基十七烷、二十四烷、13 二十二碳烯酸、1 溴代 7 十九炔、15 二十四碳烯酸、二十六酸、7 己基二十烷、二十七烷共 13种，其中13 二十二碳烯酸、15 二十四碳烯酸、十九醇等具有较强的生理活性和药用价值

The cannas natural antistaling agent is separated by column separation methods and recrystallization. Fraction Ⅱ-2 is analyzed by GC-MS. Three compounds which are n-Octadecane, n- Heptacosane and Decanoic acid heptyl ester were identified.A new way of litchi preservation is provided in this paper.

本论文还对此美人蕉天然保鲜剂进行了分离研究，先对其乙醇提取物进行柱层析粗分，然后对组分Ⅱ进一步细分，对其中的组分Ⅱ-2进行了GC-MS分析，鉴定出3个物质，它们分别是正十八烷(n-Octadecane)、正二十七烷(n-Heptacosane)和癸酸庚酯。

The main components were myristic acid (19.37%), palmitic acid methyl ester(7.56%), lascorbic acid 2,6dihexadecanoate(6.27%), 8,11octadecadienoicacid methyl ester(5.22%), heptadecane(4.82%), lauryl ethoxylate(2.98%), 2isopropyl5methyl1heptanol (2.62%), tetracosanoic acid methyl ester(2.12%),2ethyl2methyltridecanol (2.08%), et al.

其化学成分主要为肉豆蔻酸(19.37%)，棕榈酸甲酯(7.56%)，2，6十六烷基1抗坏血酸酯(6.27%)，8，11十八碳二烯酸甲酯（5.22%），十七烷（4.82%），十二烷基乙氧基醚（2.98%），2异丙基5甲基1庚醇(2.62%)，二十四烷酸甲酯（2.12%），2乙基2甲基十三醇（2.08%）等。

SM6 and SM7 of uncrystal were analyzed through GC-MS, the results showedthat SM6 main contained unsaturated fatty aldehyde with fragrance, i.e.-2,4-decadienal(58%), tetradecanoic acid (55.78%), 2-decenal(50%), Phthalic acid isobutylundecyl ester(47%), 2, 4-Decadienal(41%), 2-Undecenal (31%), 2-Methyl-Z,Z-3, 13-octadecadi-enol(18.84%), and SM7 contained saturation alkanes, i.e. 1, 2-Benzenedicarboxylic acid, butyl cyclohexyl ester(23.90%), Triacontane(22.63%),Nonacosane(21.04%), Heptadecane(18.84%), Octacosane(13.58%). Toxicological experiments were done to insure the pigment safety.

并对紫红丝膜菌色素非晶体部分的黄色油状物SM6和紫色粉末物SM7作了GC-MS分析，结果显示SM6中主要为具有香气成分的不饱和脂肪醛，其中含量较高的依次为：-2，4-癸二烯醛(58％)、十四烷酸(55.78％)、2-癸烯醛(50％)、邻苯二甲酸异丁基十一烷酯(47％)、2，4-癸二烯(41％)、2-十一碳烯醛(31％)、2-甲基-Z，Z-3，13-十八碳二烯酸(18.45％)等；SM7中主要为饱和直链烷烃，其中含量较高的依次为：1，2-苯二羧酸丁基环己酯(23.90％)、三十烷(22.63％)、二十九烷(21.04％)、十七烷(18.84％)、二十八烷(13.58％)。

With intermediates 1,ω-hexadecanediol and ω-bromo pentadecanol as starting materials,ω-bromo hexadecanoic acid and ω-bromo octadecanoic acid were prepared in four and seven steps of reactions separately.

分别以1，ω-十五烷二酸和1，ω-十六烷二酸为原料，各经过四步有机反应，制备了ω-碘代十六烷酸及含十四、十五、十六碳原子的ω-溴代直链脂肪酸；再以中间产物15-溴代十五烷醇、1，ω-十六烷二醇为原料，各经过四步、七步有机反应，制备了ω-溴代十六烷酸及ω-溴代十八烷酸。

Result 16 kinds of fatty acids were separated from Anak chicken muscle and identified. Among them, 7 kinds fatty acids, including lauric acid, myristic acid, pen-tadecanoic acid, palmitic acid, margaric acid, stearic acid and eicosanoic acid, were saturated fatty acids and its content accounted for 38.55% of the total fatty acids; 9 kinds fatty acids, including 11-teteadecenoic acid, 9-hexadecenoic acid, 9-vaccenic acid, 9,12-octadecadienoic acid, 6,9,12-octadeca-trienoic acid, 11-eicosenoic acid, 10, l3-eicosenoic acid, 7,10, 13-eicosatriennoic acid and 5,8,11,14-arachidonic acid, were unsaturated fatty acids, and its content accounted for 61.45% of the total fatty acids.

结果］安卡鸡肌肉中共分离和鉴定出16种脂肪酸，其中饱和脂肪酸7种，包括月桂酸、豆蔻酸、十五烷酸、棕榈酸、十七烷酸、硬脂酸和花生酸，其含量占总脂肪酸的38.55%；不饱和脂肪酸9种，包括11-十四碳烯酸、9-十六碳烯酸、9-十八碳烯酸、9，12-十八碳二烯酸、6，9，12-十八碳三烯酸、11-二十碳烯酸、10，13-二十碳二烯酸、7，10，13-二十碳三烯酸以及5，8，11，14-二十碳四烯酸，共含量占总脂肪酸的61.45%。

Our study show that 9, 11-Octadecadienoic acid, methyl ester is the highest content of organic acid ester components in non-hydrocarbon fraction, higher content of 6-Octadecenoic acid, methyl ester reflects mainly terristrial source input, higher content of pentadecane acid, 14-methyl, methyl ester or Heptadeeanoic acid, 16-methyl, methyl ester shows mainly aquatic source input.

原油和岩石抽提物非烃中有机酸酯类化合物的有机地球化学研究报道很少，系统研究发现非烃有机酸酯中9，11-十八二烯酸甲酯含量最高，而次高峰的丰度可用作生源判识，陆源母质输入多的样品次高峰为6-十八单烯酸甲酯，水生母质供给多者次高峰为14-甲基十五烷酸甲酯或16-甲基十七烷酸甲酯。

In order to get the information of interaction between metal complex and DNA and select metal complexes which can cleave DNA effectively, twenty seven transition metal complexes containing O/N coordinate atoms have been synthesized in this thesis. We report the synthesis, crystal structure and properties of the complexes. One of the complexes is the first μ〓-oxalato tetranuclear Cu complex, in which there is ferromagnetic interaction between the copper atoms bridged by oxalate ions. Two trinuclear copper complexes containing partial cubane Cu〓O〓 cores have been synthesized and discussed the magnetic properties.

为了解金属配合物与DNA的相互作用及筛选能有效切割DNA的金属配合物，为无机药物合成及应用提供基础信息，本文利用十个含N、O原子的多齿配体设计合成了二十七个未见文献报道的过渡金属配合物，并解析了它们的晶体结构：其中包括首例μ〓-草酸根的四核铜配合物；合成了两个具有μ〓-OH〓三核缺角立方烷结构的Cu配合物；以HCBP衍生物为配体合成了七个过渡金属配合物；以SCN〓、N〓，C〓O〓等为桥联配体，以dmpyen为端基配体合成了十一个配合物。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。