二分子聚合物

The establishment and relaxation processes of the transient gratings, which are formed by two recording 514nm beams with different polarization directions, SS, PP, SP and ±45℃, are investigated. Using the weak absorption of the chromophores at 632. 8nm and the positive dichroism of the chromophores molecules, a kind of bi-photonic transient gratings, owing to the periodic distribution of Trans and Cis isomers, is established first time in azo-dye doped polymeric bulk sample.

实验考察了两束514nm的写入光在不同偏振情况下（SS，PP，SP和±45），在样品中形成的瞬态栅的建立和弛豫情况；利用偶氮生色团在632.8nm波段的微弱吸收和生色团分子的正二向色性，首次在块状偶氮聚合物材料中形成一种基于生色团反式和顺式异构体密度分布的双色光瞬态栅；利用瞬态栅的快速建立和弛豫，考察了其在衍射型全光开关方面的潜在应用。

By using different bidentate auxiliary ligands, a number of one- and two-dimensional azido-bridged coordination polymers and molecular magnets were synthesized, including some with novel structures, and the influences of the ligands on the structure and the magneto-structural correlations in some systems were analyzed.

以不同二齿配体为辅助配体合成了多种一维及二维叠氮桥配位聚合物和分子磁体，较系统地分析了辅助配体对结构的影响及部分体系的磁构关系，并获得几种新的叠氮桥联结构类型。

In this paper, according to principles of molecular design, Cu,Ag, Cu,Fe, Ni, Mn, and Co were selected as templates, 8,8'-Dithiodiquinoline,4-cyanopyridine,2,2'-Bipyridyl-3,3'-dicarboxylic acid, 4,4'-bipyridine as building blocks.

本课题通过分子设计，以Cu，Cu，Mn，Co，Ni，Fe，Ag为模板，以8，8'-二硫联喹啉，4-氰基吡啶，4，4'-联吡啶和2，2'-联吡啶-3，3'-二羧酸为构件，用溶剂热法合成新的配位聚合物，测定其晶体结构，并研究其导电性和热行为。

On the basis of above, we utilize the technology of interpenetrating polymer network to prepare the equimolar complex-forming semi-IPNs consisting of uncrosslinked PEG and crosslinked PAA.

在此基础上，利用互穿网络技术，以聚乙二醇分子为模板制备了等摩尔复合物形成的半互穿聚合物网络，包括了未交联的聚乙二醇和交联的聚丙烯酸。

The results showed that the LUMO values are -3.19eV for organic oxadiazole,-3.16eV for macromolecular oxadiazole and -3.21eV for Poly(1,3,4-oxadiazole) and their HOMO values are all under -6.0eV, hinting that they show good hole-blocking characteristics.

利用循环伏安法测定了三种不同类型衍生物的带隙和HOMO、LUMO能级，噁二唑类小分子、大分子、聚合物衍生物的LUMO能级分别为-3.19eV、-3.16eV、-3.21eV，有利于电子的注入，三种噁二唑衍生物的HOMO能级都在-6.0eV以下，对空穴也有很好的阻挡作用。

The replacement of toxic and volatile organic solvents as reaction media or an efficient catalyst with environmentally acceptable alternatives are an area of tremendous importance in modern organic synthesis. Basing the review about solid-phase synthesis with simple separation, the liquid phase organic synthesis supported by the solution polyethylene glycol and the chemical reactions in the medium of PEG, herein we are going to study the synthesis of 1-amidoalkyl-2 -naphthols in presence of the solution catalyst or the solid catalyst and the synthesis of thiourea in PEG-400 medium.

难溶性载体试剂参与下的固相合成使分离操作简单易行；可溶性聚乙二醇支载下的液相合成显示出液相反应的稳定高效性，同时兼顾大分子聚合物容易沉降分离的优点；无毒且稳定的小分子PEG作为反应介质，往往表现出醚和醇的双重性质和功能。

It was found that the content of Zn bound in polymeric matrix is all-important to the formation and optical activity for supramolecular aggregates.

由Et_2Zn和Et_2Zn／n-BuLi二元体系合成的聚合物在二价铜盐作用下发生独特的超分子聚集现象。

In this paper, according to principles of molecular design, Cu, Cu,Ag, Pd were selected as templates, and 2,2'-Bipyridyl-3,3'-dicarboxylic acid (H2bpdc) mainly acted as building blocks.

本课题通过分子设计，以Cu，Cu，Pd，Ag为模板，主要以2，2'-联吡啶-3，3'-二羧酸(H2bpdc)为构件，用溶剂热法合成新的配位聚合物，测定其晶体结构，并研究其导电性和热行为。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。