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A series of novel aromatic amide molecular tweezers with different chiral centers and cavities were designed and synthesized by using isophthalic acid as the spacer to bridge the different L-amino acid methyl esters under microwave irradiation.

以间苯二甲酸为隔离基,酰胺键桥联L-氨基酸甲酯构成手臂,在微波辐射下合成了具有不同手性中心和裂穴的新型手性芳酰胺类分子钳。

No tetracthyl thiuram (TETD or D2) molecule formed by oxidation on the surface. At the potential from -0.25 V on, the chemical adsorption of jamesonite occurred. In the presence of diethyldithiocarbamate, the interaction between jamesonite and diethyldithiocarbamate became obvious from 0.35 V on.

采用循环伏安电位扫描研究方法,研究了乙硫氮在脆硫锑铅矿表面的电化学作用机理,在其表面没有氧化形成四乙基二硫化秋兰姆(TETD或D2)分子;电极电位从-0.25V左右开始就在脆硫锑铅矿产生了化学吸附。

Three series of donor-acceptorπ-conjugated molecules 1, 2, and 3 have been designed and synthesized with a N, N-dimethylamino, Julolidine group (2,3,6,7-tetrahydro-1H, 5H-pyrido[3, 2, 1-ij]quinolinyl), or N, N-diphenylamino group as the donor moiety, a phenylvinyl or thienylvinyl unit as the bridge, and a bromide or aldehyde group as the acceptor moiety.

本文设计并合成了1、2、3三个系列的D-π-A型化合物(Donor-Acceptorπ-conjugated compounds),在化合物分子中引入久洛尼啶基团(2,3,6,7-tetrahydro-1H,5H-pyrido-[3,2,1-ij]quinolinyl),N,N-二甲基氨基,或N,N-二苯基氨基为供电子基团,以苯乙烯基或噻吩乙烯基为桥链,以溴原子或醛基为吸电子基团。

The results showed that the utilization ratio of polymer reached 100% and the conversion of leucoquinizarin was more than 99% determined by TLC.

合成反应中高分子利用率为100%,通过薄层色谱分析发现1,4—二羟基蒽醌隐色体的转化率基本达到100%。

Monofilm of silane on the surface of the glass substrates is prepared via the method of self-assembled monolayers, Hf (SO4)24H2O and HCI are used as raw materials, HfO2 thin films are prepared on the active groups of the alkyl silane by the liquid phase deposition.

利用自组装单层膜技术,在玻璃基板上生长有机硅烷单分子膜层,以Hf(SO4)24H2O和HCI配制HfO2前驱液,通过液相沉积在硅烷的功能性官能团上诱导生成二氧化铪薄膜。

Using N,N,N',N'-tetramethylethylenediamine and potassium persulphate as a redox initiation system, high molecular weight poly was synthesized by aqueous deposited polymerization.

以N,N,N',N'-四甲基乙二胺-过硫酸钾为氧化-还原引发体系,用水相沉淀聚合法合成了超高相对分子质量的聚醋酸乙烯。

A series of secondary pollutants with small molecule are produced from these reagents,such as ethanol,aldehyde,acetone,acetonitrile,propionitrile,isobutanol...

药剂在降解的过程中会产生乙醇、乙醛、丙酮、乙腈、丙腈、异丁醇、戊醇等一系列小分子二次污染物。

The cis-decalin 79 was obtained from 2-methoxy-4-methylphenol (77) via a sequence of reactions involving intermolecular Diels-Alder reaction of masked o-benzoquinone derived from 77 and ethyl vinyl ketone, silyl enol ether formation and Cope rearrangement.

第一部份:以2-甲氧基-4-甲基酚(77)为起始物,经由二乙醯基亚碘苯氧化、分子间Diels-Alder反应、烯醇矽醚的形成及Cope重排反应得到具有十氢萘骨架化合物79。

Objective To evaluate the effect of corneal topograph guided enhancement after photorefractive keratectomyin myopia.

目的:探讨在角膜地形图引导下的PRK术后二次准分子激光手术疗效。

Objective To evaluate the effect of corneal topograph guided enhancement after photorefractive keratectomyin myopia.

导读:探讨在角膜地形图引导下的PRK术后二次准分子激光手术疗效。

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