二分子的

First, the preparation of l,2-dichloro-4-nitrobenzene, which l-chloro-4-nitrobenzene reacted with chlorine in a self-designed chlorinator, in presence of Lewis acid catalyst,.was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield of l,2-diehloro-4-nitrobenzene was 83.26%.

为此，本文首先在自行设计的塔式氯化器中，以对硝基氯苯为原料，路易氏酸作催化剂，分子氯氯化合成3，4-二氯硝基苯(合成3-氯-4-氟-硝基苯的原料)，根据该氯化过程特征，利用正交试验设计方法结合单因素实验考察了有关因素对氯化过程的影响，优化得到了最佳的氯化工艺条件，3，4—二氯硝基苯的收率可达83.26％。

Tibetanum were more abundant, which can be used to broaden the genetic basis of common wheat. Cluster analysis exhibited that wild emmer had a closer consanguine relationship to hexaploid wheat, as compared to Aegilops tauschi. In addition, it was found that there was a closer genetic relationship in chloroplast genome of common wheat and T. petropavlavskyi, which indicated that T. petropavlavskyi probably derived from the backcross between common wheat and Polish wheat.

结果］与普通小麦相比，斯卑尔脱小麦和西藏半野生小麦等群体内的叶绿体遗传变异更丰富，可以作为普通小麦新的细胞质遗传变异来源；与粗山羊草相比，野生二粒小麦与六倍体小麦间存在更近的亲缘关系，这与前人关于二粒小麦是六倍体细胞质供体的研究结果相印证；研究还发现，新疆稻麦与普通小麦在叶绿体基因组上具有很近的亲缘关系，为新疆稻麦是由波兰小麦与普通小麦杂交再由普通小麦回交后产生的假说提供了分子水平上的证据。

By applying density functional theory, the relationships between the electron structures and the complexation of the two types of bis-β-diketone ligands (dithiol-γ-linked or alkyl-γ-linked) were investigated, based on the polarized continuum model of the self-consistent reaction field. Using the model B3LYP/6-31G**, the geometries of the ligands were optimized and the electron structure changes calculated.

基于自洽反应场中的极化连续介质模型，采用密度泛函理论B3LYP/6-31G**计算了以二硫醚和芳环为桥基的两类双β-二酮配体的空间构型和电子结构，结合其配合物晶体结构数据，研究配体分子电子结构与配位性的关联性。

The electrochemical property of PDT and PDT metal complexes were characterized by CV, from the result of CV, it can be found that PDT and PDT metal complexes possesses electrochemical activity, which arised from the heteroatom of molecules.

我们用循环伏安表征了对二苯甲醛缩氨基硫脲及其金属络合物的电化学性质，从循环伏安的结果来看，对二苯甲醛缩氨基硫脲及其金属络合物具有一定的电化学活性，并且这些电化学活性主要来自于分子中的杂原子。

Ferrocenecarboxylic-ssdeoxyribonucleic acid probe was made by chemically bounding FCA to terminal 5'-amino of oligonucleotide in the presence of a water-soluble carbodiimide. The hybridization reaction was conducted by immersing the immobilized-ssDNA electrode in FCA-ssDNA probe solution.

在偶联活化剂碳二亚胺的存在下，通过羧基二茂铁上的羧基与DNA分子上的氨基共价键合，将FCA标记在氨基修饰的寡聚核苷酸片段上，制备成FCA-ssDNA探针。

A new functional electroluminescent copolymer is reported in which chromophores and hexa segments alternate along the polymer backbone.

采用Wittig反应合成了一种分子主链由烷氧基取代的1，4二苯乙烯基苯聚对亚苯基亚乙烯基(PPV的三个单元的齐聚物与柔性隔离链段五缩六乙二醇组成的交替型蓝绿色发光共聚物。

The mechanisms of intramolecular biaryl nonphenolic coupling were explored by reactions of different 1,4-biaryl substituted butanes with DDQ in TFA.

通过对含不同取代基的芳环化合物、1，4-二芳基丁烷链上含不同取代基化合物与DDQ在TFA中进行非酚氧化偶合和重排反应的研究，对分子内的二芳基非酚氧化偶合反应机理作了深刻的探讨。

heological properties at a low shear rate range(10-2-10s-1) and the glass transition temperatures for PEK-C with different moleCular weithts have been studied by using a cone/plate rheometer and DSC' The activation energy for melt flow increases with Mw The dependence of Tg on molecular weight exhibits two linear range and the value of nitersect agrees with the critical molecular weight , Mc' which is first reported for PEK-C' Mc value obtained according to η0 is about 8× 104 g/mol and the relation between Mc and temperature was dis-cussed.

用锥权流变仪及DSC的方法研究了5种不同分子量的酞侧基聚芳醚酮在低剪切速率区（10－2－10s－1）的流变行为及其分子量与玻璃化转变温度的关系。结果表明，样品的粘流活化能随分子量的增加而增大，Tg随分子量的变化是二个线性区，其交点值与所求的样品的临界分子量值相对应。利用测得的零剪切粘度值（η0）首次求得了PEK—C的临界分子量值。同时也讨论了Mc与温度及η0和Tg与分子量的关系。

Quantitive coordinate solvent-DME was added during the preparation reaction or crystallization, sodium ion in complex 1, 2 and 4 will be extracted and become free one, thus new solvated anion-cation pair complexes [2Ln2][Na22] Ln = Nd (5, Sm (6), Yb (7) were formed.

在反应或者结晶的过程中加入一定量的乙二醇二甲醚，配合物1，2和4中与双芳氧鞠位的钠离子被DME分子萃取出来，生成阴阳离子对配合物[_2Ln_2][Na_2_2]Ln=Nd(5，Sm(6)，Yb(7)。

Their chaperone function is independent of and has promoting effects on the enzyme activities for the formation of disulfide bonds.

它们的分子伴侣功能独立于二硫键形成酶的活性并且对二硫键形成酶活性具有明显的促进作用。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新