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On the basis of above, we utilize the technology of interpenetrating polymer network to prepare the equimolar complex-forming semi-IPNs consisting of uncrosslinked PEG and crosslinked PAA.

在此基础上,利用互穿网络技术,以聚乙二醇分子为模板制备了等摩尔复合物形成的半互穿聚合物网络,包括了未交联的聚乙二醇和交联的聚丙烯酸。

Circular dichroism spectroscopy measurements also reveal that the ordered structure content of α-helical and β-structure of ovalbumin decrease, and the unfolded random structure is enhanced with increasing pressure; While the existence of dextran sulphate to the native ovalbumin, there are no apparent change on the secondary structure of ovalbumin; It seems same to glycinin.

圆二色性光谱分析表明,经超高压处理后,鸡蛋清蛋白分子中规则的二级结构减少,而部分规则的二级结构和无规卷曲含量增加。加入硫酸右旋糖苷的鸡蛋清蛋白溶液经超高压处理后其二级结构中各部分的含量变化不大:对于大豆豆球蛋白,加入硫酸右旋糖苷后,大豆豆球蛋白分子经超高压处理后其有序结构的减少及无规卷曲的增加都相对减缓。

Five novel asymmetrical molecular tweezers based on diethoxycarbonyl-and diphenyl glycoluril with different substituted groups of aromatic ringsand 1,2 -dihydro-indazol-3-one moiety as sidewalls were designed and synthesized.

合成了五个含单个1,2-二氢-引唑-3-酮和不同取代的苯环(H,OMe,Me,Br)为墙面的基于二乙基酯基甘脲和二苯基甘脲的不对称分子钳。

Second, a lot of artificial propagation experiments were performed between different gynogenetic clones to analyze whether or not genetic recombination occurs by utilizing the identified RAPD and SCAR markers. Direct molecular genetic evidence for gonochoristic reproduction was revealed in the gynogenetic silver crucian carp, and a previous hypothesis that the silver crucian carp might reproduce both gynogenetically and gonochoristically was conformed.

二是利用银鲫的克隆多样性和其种群中存在的雄性个体,设计大量的不同繁育组合,运用已鉴定的RAPD和SCAR分子标记,分析比较了不同繁育组合子代的DNA扩增情况,探讨了这些分子标记在各个交配子代中的重组分布规律。

We have investigated the conformational features of four short peptide fragments of Staphylococcal nuclease by homonuclear two-dimensional NMR and circular dichroism with a view to examining the early events in the folding process of SNase.

中文题名金黄色葡萄球菌核酸酶折叠起始位点:N-末端短肽段的NMR研究副题名外文题名 Folding initiation sites of staphylococcal nuclease:exploring the solution conformation of N-terminal fragments by nuclear magnetic resonance 论文作者戴继勋导师王金凤研究员学科专业分子生物学研究领域\研究方向学位级别博士学位授予单位中国科学院生物物理研究所学位授予日期2001 论文页码总数68页关键词金黄色葡萄球菌核酸酶蛋白质折叠核磁共振馆藏号BSLW /2001 /Q71 /89 本论文工作用四个金黄色葡萄球菌核酸酶N-末端短片段作为新生肽链折叠的模型,用同核二维核磁共振谱和远紫外圆二色谱研究了它们的溶液构象特征。

One class is CAAX-mimetic compounds with an imidazolyl residue on one end and a carboxylic group on the other connected by benzodiazepine scaffold at different positions.

连有咪唑基的苯并二氮杂草化合物,以苯并二氮杂草-2-酮为分子骨架,7位连接含有咪唑基的侧链,1位或3位连接含羧基或酯基的侧链。此类化合物模拟了CAAX配体。

But no electron transfer was found from the excited porphyrin moiety to the oxadiazole moiety. Moreover, cyclic voltammetric studies of the dyads 5a , 3b and 4b further indicated that electron transfer from the oxadiazole moiety to the porphyrin moiety was possible.

nm激发下不存在分子内卟啉基团向噁二唑基团的电子回传竞争;电化学性能测定进一步表明从噁二唑基团向卟啉基团的电子传递是可能的。

In thesecond chapter, eleven 1,3,4-oxadizoles bearing chiral pyrazolyl moieties(4a-k) andfive triazolotriazines bearing chiral pyrazolyl moieties(5a-e) were obtained from5-[(1"S)-1",2-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) with arylcar-bohydrazide or (5-aryl-1,2,4-triazin-3-yl)hydrazine through an intramolecular1,3-dipolar cycloaddition in the presence of the non-metal oxidant IBD.

其中第二章介绍了以D-葡萄糖为原料制得的5-[(1′S)-1′,2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)分别与芳基甲酰肼、(5-取代苯基-1,2,4-三嗪-3-基)肼反应,在无金属氧化剂—IBD引发下,发生分子内1,3-偶极环加成,采用&一锅煮&法合成了11种含手性吡唑基的1,3,4-噁二唑类化合物(4a-k)和5种含手性吡唑基的三唑并三嗪类化合物(5a-e)。

Its melting point is in the range of 40 deg.C-60 deg.C, and is dependent on the molecular weight of PCL and the mole ratio of PCL and EO, and its restorable deformation temperature is room temperature to 60 deg.

一种具有形状记忆功能的以聚为软段的聚氨酯,它用双羟基的聚与二异氰酸酯、小分子二醇反应而成。

By the nucleophilic substitution reaction of 6-O-tosyl-l,2:3,4-di-O- isopropylidene-a-Z-galactopyranose (3) with some substituted 1, 2,4- triazole-3-thiols (4a ~ 4c) or 1, 2, 3,4-tetrazole-5-thiols (5a~5f), nine 6-S-(substituted triazolyl or tetrazolyl)-l,2 : 3,4-di-O- isopropylidene-a-D-galactopyranoses (6a ~ 6i) were prepared in high yields. Their structures and configurations were analyzed and established by elemental analysis, IR, NMR, MS spectra.

报道了6-O-对甲苯磺酰基-1,2:3,4-二-O-异亚丙基-α-D吡喃型半乳糖(3)与取代的3-巯基三唑或5-巯基四唑4a-4c或5a-5f的亲核取代反应,合成了9个6-S--1,2:3,4-二-O-异亚丙基-α- D吡喃型半乳糖(6a-6i),通过元素分析,IR,NMR和MS确证了上述化合物的结构,并经分子模型计算进行了其构象分析。

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