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The effect of heterocycle in the molecules was similar to that of group -NH2, but the hydrogen on the nitrogen atoms could form the hydrogen bond between molecules which could effectively improve the thermal stability.

对于二维电荷转移体系,我们研究了氧桥Λ型分子,它含有两个D-π-A轴,属于典型的二维电荷转移体系,且它们的β_/β_<1。

The relation of interfacial adsorption equilibrium in the solution system was respectively tested and calculated with Gibbs equation and dynamic method .The conclusion showed that (1) the experiment result of dynamic method with was highly in coordination with the value which from theoretical calculation.(2) The surfactant molecule was in arrangement of monomolecular layer at the gas-liquid interface.

用吊环法测定了十二烷基硫酸钠水溶液不同浓度与其界面张力的关系,拟合得到的回归方程为σ=-0.9523 ln ~2C-24.534 ln C-81.411,同时还测得其临界胶束浓度值CMC为6.5×10~(-3M,运用吉布斯等温方程和动态法分别计算和测定了该溶液系统的界面吸附平衡关系,结论表明:(1)动态法测定结果基本吻合吉布斯方程的理论计算;(2)表面活性剂分子在气—液两相界面是以单分子层形式定向有序排列的。

The major researching subjects are the evolution of sex chromosome and genome in mammals, molecular mechanism of tumorigenesis and gene therapy on cancer, signaling in tumorigenesis, development and metastasis and cellular and molecular immunology, and so on.

本学位点的主要研究方向有:一、动物染色体进化与基因组学;二、肿瘤发生的分子机制与肿瘤的基因治疗;三、肿瘤的发生、发展及转移的信号转导调控;四、细胞与分子免疫学等。

Such one-dimensional chains interconnect via hydrogen bonding and π-π interaction to form an extended undulated sheet-like structure.

经配体桥联的两个金属离子的距离是6.703〓。这样的一维链通过配体的NH部分〓Cl及溶剂分子甲醇相互之间形成的氢键连接扩展成二维波浪状结构。甲醇分子被包容在层间。

A series of study methods which can not research in this field begin to exert important affection. On the basis of the previous research, the following major innovative work was carried out in this dissertation.(1) Several methods including fluorescence spectra, CD and FT-IR specta methods were used to study the interaction of isoquinoline alkaloid、isoflavones and Rhein with serum albumin, and the results from every method was in good agreement;(2) The binding constants、the numbers of binding site、the binding region and the interaction force involving in the interaction of drugs and serum albumin were confirmed by Scatchard equation and Vant Hoff equation.

基于研究生物大分子与小分子相互作用具有极其重要的意义,本博士论文在前人工作的基础上,主要进行了以下几方面的创新性研究:(1)利用荧光光谱法、圆二色谱法、红外光谱法以及分子模拟等多种方法相结合研究了异喹啉类生物碱,异黄酮类化合物以及大黄酸与人血清白蛋白的相互作用,获得了准确一致的信息;(2)根据Scatchard方程和Vant Hoff方程详细研究计算了异喹啉类生物碱以及大黄酸与蛋白质结合机理包括结合常数、结合位点数、结合区域、结合力。

It is pointed out that the biodegradability of modified sodium polyacrylate can be improved by introducing vinyl alcohol to its molecular chain.

综述了无磷洗涤助剂的开发进展,并对 4A沸石、偏硅酸钠、聚丙烯酸钠、沸石P、顺丁烯二酸酐丙烯酸共聚物钠盐、层状结晶二硅酸钠等助剂的性能作了评述;指出在改性聚丙烯酸钠分子链中引入乙烯醇能改善其生物降解

The influence of temperature on the spectra and nonlinear optics properties of the 4--4'-aminoazobenzene compound Langmuir-Blodgettfilms were investigated using UV-visible absorption spectra and second harmonic generation technique.

采用紫外-可见吸收谱和二次谐波产生技术研究了温度对4-硝基-4'-氨基偶氮苯分子Langmuir—Blodgett单层和多层膜的光谱和二阶非线性光学特性的影响。

To realize the molecular compositions and bio-spinning mechanisms of spidroin in spider major ampullate, the molecular weight and amino acid compositions of spidrion solution were measured and compared with that of dragline silk. The molecular conformations and morphologies of spidroin and dragline silk in different spinning phases were determined by circular dichroism spectroscopy and laser Raman spectroscopy.

本文以广泛分布于我国各地的大腹园蛛为对象,研究了大腹园蛛主腺体内丝蛋白溶液的分子量和氨基酸组成,并利用圆二色光谱和拉曼光谱分析了蜘蛛在不同成丝阶段丝蛋白的分子构象和聚集态结构的变化,以期了解蜘蛛主腺体内丝蛋白的分子组成及其生物纺丝机制。

The experimental results show that using the feed technique of "starved state" can raise the conversion ratio of monomers, shorten the reactive time and get polymers with much more even distribution of molecular weight; the technique of adding azobisisobutyronitrile as an initiator first and then benzoperoxide as another initiator at later Stage of experiment can get higher initiating efficiency than using one initiator only.

结果表明:采用&饥饿态&聚合工艺可提高单体转化率,缩短反应时间,且所得到聚合物相对分子质量分布均匀;选用偶氮二异丁腈和过氧化笨甲酰两种引发剂进行复配,比选用单一引发剂的引发效果好;选用酯酸丁酯、正丁醇和丙二醇甲醚丙酸酯作混合溶剂,当配比为2:1:1时聚合体系稳定,聚合物的固体质量分数可达70%,且粘度适中。

To enable the fabrication of a thermally stable ultralow dielectric constant film, specific precursor materials are used, such as, silane derivatives, for instance, diethoxymethylsilane and organic molecules, for instance, bicycloheptadiene and cyclopentene oxide.

为了制造热稳定的超低介电常数膜,使用特殊的前体材料,如硅烷衍生物例如二乙氧基甲基硅烷和有机分子例如双环庚二烯和环戊烯氧化物。

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