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It shown that PDC does not only catalyze the production of acetaldehyde (PDC's main activity), but also catalyzes an aldoltype condensation reaction in which the hydroxyethyl-ThDP intermediate of enzyme is condensed with a second acetaldehyde to form acetoin.

在研究中发现PDC不仅能催化产生乙醛,还具有醛连接酶的活性。即将二个乙醛分子缩合成3-羟基丁酮,尽管这个活性比产生乙醛的活性低得多。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺;NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢;NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

The Ehrlich-Schwoebel barriers of an adatom Cu diffusing down an island of fcc Cu are calculated by molecular dynamical simulation.The two-dimensional(2D) and three-dimensional(3D) ES barriers are calculated and compared with the results of Al.

利用分子动力学中的静态结构弛豫方法对Cu原子在面心立方铜的台阶表面扩散过程中的Ehrlich-Schwoebel势垒进行了模拟计算,研究了二维和三维ES势垒的差别,并将Cu与面心立方Al的结果进行了比较。

The result shows at the mild condition chain olefin that nCl7, polyethylene can be cracked into solutions of ethane, propane, butane, benzene and toluene and other small molecular compounds, polyethylene reacted fluids are mainly composed of a-olefin at the range 12 to 38, by which α-ωdiene, saturated hydrocarbon and aromatic hydrocarbon, anthracene, phenanthrene of albocarbon series are contained.

结果表明,在温和条件下可以将链状烷烃如正十七烷烃、聚乙烯通过微波及炭催化剂的作用,裂解成乙烯、丙烷、丁烷、苯、甲苯等溶剂及小分子化合物。聚乙烯反应液体产物以碳数在12~38范围的α-烯烃为主,也产生α-ω二烯、饱和烃及芳烃,芳烃主要有萘系列、葱、菲等。

4R,5S,6R-5,6-Bis-allyl-6-aldehyde-γ-hexanelactone I-145 was prepared from D-arabinose by six steps. Compound I-145 underwent Mukaiyama-type intramolecular aldolization to produce bicyclooctane I-147 stereospecifically.

我们以D-阿拉伯糖为起始原料,经六步反应,得到(4R,5S,6R)-5, 6-二烯丙氧基-6-醛基-γ-己酸内酯I-145,然后I-145发生分子内的Mukaiyama式aldol缩合反应,完全立体专一性地得到环化中间体I-147。

Multiple technology like local area network database separate operaton, real time data concentration and distribution mechanism, allopatric backup, and optical fiber virtual private network were used.

由此保证了固定无偿献血者的招募,保证了医疗急救用血的供应,为二十世纪末开展的血液集中化检测和医疗用血的检测应用分子生物学技术奠定了必须的基础。

The most commonly used method for the covalent binding of biomolecules onto 1-D nanostructures is through the diimide-activated amidation of carboxylic acid terminated nanostructures.

最常用的方法是通过端羧酸基纳米结构的二酰亚胺活化氨基化合物来进行生物分子与1-D纳米结构的共价结合。

The most commonly used method for the covalent binding of biomolecules onto 1-D nanostructures is through the diimide-activated amidation of carboxylic acid terminated nanostructures.

在一维纳米结构上共价结合生物分子最常用的做法是对纳米结构的C端进行二酰亚胺活化。

The synthesis of molecular beacon. CdTe QDs, DNA and EDC were added into the phosphate-buffered saline solution, reacted for 24 h at room temperature. In this period, carboxyl on the CdTe reacted with amido on DNA.

二、在PBS缓冲溶液中,将CdTe量子点、DNA和脱水剂EDC混合,于室温下反应24小时,CdTe量子点表面的羧基与DNA5'端的氨基缩合,合成分子灯塔探针。

Nonlinear optical organic materials have more advantages than inorganic materials. Based on the molecule design, a new D-π-A structure NLO chromophore molecule [4-nitro-4'-N,N-di aminoazobenzene] 3 with nitro, azobenzene and epoxy is synthesized.

以环氧氯丙烷、苯胺、对硝基偶氮苯胺为原料,设计并合成了一种具有推拉电子结构、含双环氧基的偶氮类有机非线性光学发色团分子4-硝基-4'-N,N-二缩水甘油氨基偶氮苯。

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弗四23 而在你们心思的灵里得以更新

Lao Qiu is the Chairman of China Qiuyang Translation Group and the head master of the Confucius School. He has committed himself to the research and promotion of the classics of China.

老秋先生为中国秋阳翻译集团的董事长和孔子商学院的院长,致力于国学的研究和推广。