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A novel bis (o-aminobenzophenone) s monomer is synthesized, and is used to get three different polyquinolines containing phenylamine moiety through Frieldlander reaction. The solubilities, thermal stabilities and luminescent properties of the polymers were evaluated. All the polymers are thermal-stable, and are soluble in common organic solvents. The emission of their thin film is from excimer emission.

合成了一种新型的二邻氨基二苯酮单体,通过Frieldlander反应,可以构造出不同结构的含有类三芳胺基元的发光聚喹啉,对其溶解性、热性能进行了研究,结果表明这类聚喹啉在常用有机溶剂中的溶解性有了很大提高,同时保持了聚喹啉较高的热稳定性;研究了它们在溶液态和薄膜态的紫外可见吸收光谱和荧光发射光谱,发现它们在薄膜态下的荧光发射主要来自于分子间激基复合物发射。

Herein, a series of compounds, BP-C〓-NBD (n=2, 3, 4, 5, 6, 8, 10), was synthesized. Nanosecond flash photolysis, phosphorescence emission and lifetime, as well as photoisomerization reaction of norbornadiene were used to understand the intramolecular triplet energy transfer in detail.

我们设计、合成了以多亚甲基连接的二苯酮与降冰片二烯(BP-C〓-NBD,n=2,3,4,5,6,8,10)系列化合物,利用纳秒时间分辨技术、低温磷光发射、磷光寿命以及光敏异构化的方法,对其分子内三重态能量传递过程进行了详细地研究。

Then the paper used the projection operator to structure the normal coordinate component,thus combined 15 normal vibration patterns of propadiene molecule.

先对丙二烯振动模式进行分类及构造投影算符,再用投影算符构造简正坐标分量,从而组合出丙二烯分子的15个简正振动模式。

In thesecond chapter, eleven 1,3,4-oxadizoles bearing chiral pyrazolyl moieties(4a-k) andfive triazolotriazines bearing chiral pyrazolyl moieties(5a-e) were obtained from5-[(1"S)-1",2-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) with arylcar-bohydrazide or (5-aryl-1,2,4-triazin-3-yl)hydrazine through an intramolecular1,3-dipolar cycloaddition in the presence of the non-metal oxidant IBD.

其中第二章介绍了以D-葡萄糖为原料制得的5-[(1′S)-1′,2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)分别与芳基甲酰肼、(5-取代苯基-1,2,4-三嗪-3-基)肼反应,在无金属氧化剂—IBD引发下,发生分子内1,3-偶极环加成,采用&一锅煮&法合成了11种含手性吡唑基的1,3,4-噁二唑类化合物(4a-k)和5种含手性吡唑基的三唑并三嗪类化合物(5a-e)。

Its melting point is in the range of 40 deg.C-60 deg.C, and is dependent on the molecular weight of PCL and the mole ratio of PCL and EO, and its restorable deformation temperature is room temperature to 60 deg.

一种具有形状记忆功能的以聚为软段的聚氨酯,它用双羟基的聚与二异氰酸酯、小分子二醇反应而成。

PETEDA was synthesized through pentaerythrityl tetrabromide and ethylenediamine's reacting by the aminolyzing reaction of alkyl halide. It was proved that the product contains a lot of amino groups analyzed by FTIR (Fourier Transform Infrared Spectroscopy) and ETA.

以四溴代季戊烷和乙二胺为原料,通过卤代烷胺解反应,合成了树枝状分子季戊四乙二胺,采用傅立叶变换红外光谱和元素分析对其进行了表征。

By the nucleophilic substitution reaction of 6-O-tosyl-l,2:3,4-di-O- isopropylidene-a-Z-galactopyranose (3) with some substituted 1, 2,4- triazole-3-thiols (4a ~ 4c) or 1, 2, 3,4-tetrazole-5-thiols (5a~5f), nine 6-S-(substituted triazolyl or tetrazolyl)-l,2 : 3,4-di-O- isopropylidene-a-D-galactopyranoses (6a ~ 6i) were prepared in high yields. Their structures and configurations were analyzed and established by elemental analysis, IR, NMR, MS spectra.

报道了6-O-对甲苯磺酰基-1,2:3,4-二-O-异亚丙基-α-D吡喃型半乳糖(3)与取代的3-巯基三唑或5-巯基四唑4a-4c或5a-5f的亲核取代反应,合成了9个6-S--1,2:3,4-二-O-异亚丙基-α- D吡喃型半乳糖(6a-6i),通过元素分析,IR,NMR和MS确证了上述化合物的结构,并经分子模型计算进行了其构象分析。

With regard to the current society, much hubbub in the European Union ban on the use of four kinds of children's toys, plasticizers, Jiangnan University, and Dr. LG Chemical in two epoxy esters, briefed the meeting on high molecular weight plasticizers, citrate butyl ester, such as trimellitic several environment-friendly non-toxic plasticizer that can be replaced ethylhexyl phthalate, ethylhexyl adipate, whether it is synthetic process, the source of raw materials are not a problem, but there are differences in price, but into the large-scale production, the price will be decreased substantially.

关于目前社会上闹得沸沸扬扬的欧盟禁止在儿童玩具中使用四种增塑剂,江南大学和LG化学的两位博士在会上介绍了环氧酯类高相对分子质量增塑剂、柠檬酸三丁酯、偏苯三酸酯等几种无毒环保型增塑剂,认为完全可以取代邻苯二甲酸乙基己酯、己二酸乙基己酯,无论是合成工艺、原料来源都不成问题,只是在价格上还有些差异,但进人大规模生产后,价格会有较大幅度下降。

The collision term is two bi-velocity non-dimensionalized reduced ngle tri-velocity model equation is transformed into a bi- h integrating weightedly the non-dimensionalized model equation about the third component of molecule velocity.

采用BGK模型和Shakov模型近似碰撞项,进而引入两个二速度无量纲简化分布函数,通过关于分子速度第三分量取矩积分,将三速度单一模型方程变换为二速度微分方程组。

It is an effective way to use the appropriate narrow bandgap nanosize semiconductors that is stable in chemical and biochemical conditions and not pollute the surroundings in reaction, which sensitizes nanocrysalline titanium dioxide carriers synchronously to prompt the utilization of the solar spectra and the efficiency of photocatalysis.

利用染料分子作表面敏化半导体材料和利用杂质掺杂来实现宽禁带半导体吸收光谱的扩展有一定的局限性,采用化学和生物惰性且对环境不产生二次污染的窄禁带半导体敏化同时考虑团簇颗粒粒径对载体性能的影响,是提高纳米二氧化钛光催化剂对阳光的吸收利用率和量子效率的有效方法。

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Lao Qiu is the Chairman of China Qiuyang Translation Group and the head master of the Confucius School. He has committed himself to the research and promotion of the classics of China.

老秋先生为中国秋阳翻译集团的董事长和孔子商学院的院长,致力于国学的研究和推广。