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Five novel asymmetrical molecular tweezers based on diethoxycarbonyl-and diphenyl glycoluril with different substituted groups of aromatic ringsand 1,2 -dihydro-indazol-3-one moiety as sidewalls were designed and synthesized.

合成了五个含单个1,2-二氢-引唑-3-酮和不同取代的苯环(H,OMe,Me,Br)为墙面的基于二乙基酯基甘脲和二苯基甘脲的不对称分子钳。

A new functional electroluminescent copolymer is reported in which chromophores and hexa segments alternate along the polymer backbone.

采用Wittig反应合成了一种分子主链由烷氧基取代的1,4二苯乙烯基苯聚对亚苯基亚乙烯基(PPV的三个单元的齐聚物与柔性隔离链段五缩六乙二醇组成的交替型蓝绿色发光共聚物。

We have investigated the conformational features of four short peptide fragments of Staphylococcal nuclease by homonuclear two-dimensional NMR and circular dichroism with a view to examining the early events in the folding process of SNase.

中文题名金黄色葡萄球菌核酸酶折叠起始位点:N-末端短肽段的NMR研究副题名外文题名 Folding initiation sites of staphylococcal nuclease:exploring the solution conformation of N-terminal fragments by nuclear magnetic resonance 论文作者戴继勋导师王金凤研究员学科专业分子生物学研究领域\研究方向学位级别博士学位授予单位中国科学院生物物理研究所学位授予日期2001 论文页码总数68页关键词金黄色葡萄球菌核酸酶蛋白质折叠核磁共振馆藏号BSLW /2001 /Q71 /89 本论文工作用四个金黄色葡萄球菌核酸酶N-末端短片段作为新生肽链折叠的模型,用同核二维核磁共振谱和远紫外圆二色谱研究了它们的溶液构象特征。

One class is CAAX-mimetic compounds with an imidazolyl residue on one end and a carboxylic group on the other connected by benzodiazepine scaffold at different positions.

连有咪唑基的苯并二氮杂草化合物,以苯并二氮杂草-2-酮为分子骨架,7位连接含有咪唑基的侧链,1位或3位连接含羧基或酯基的侧链。此类化合物模拟了CAAX配体。

Resorcinol was prepared from isophthalic acid through liquid-phase catalytic oxidation and subsequent hydrolysis using oxygen in the air as oxidizing agent in the presence of catalyst copper and promoter manganese.

崔建新;肖如亭(天津理工大学生物与化工学院)摘要:以间苯二甲酸为起始原料,在催化剂铜和助剂镁作用下,以空气中的分子氧作氧化剂,通过液相催化氧化继而水解制得间苯二酚。

There are two positive results, proton and sodium that has been reported previously, and three candidates including succinate, phosphate and melibiose that was found in this study.

根据节点连结度的分析,找到了五个候选协同输送系统中的中心小分子,其中两个为已知的阳性资料,氢离子与钠离子,其余三个分别为琥珀酸盐,磷酸,蜜二糖,其中以蜜二糖为中心的输送系统只有一个,并不符合本篇所定义的协同输送系统,故舍弃之。

The first part is to synthesize 5-formyl -8- quinolinol from 8-uinolinol and chloroform , using ethanol as a solvent. Then analysizing the 5-formyl-8-quinolinol by IR. The second part is , according to ideas of molecule designing, to synthesize the new self-assembly Inorganic-Organic coordination polymers Co(u2-bpyV2O6,(C4H4N2)Ni2(H2O)2-V4Ol2,(Cl2Hl2N2)Co-V2O6 using Cu, Ni, and Co as templating, 4-cyano-pyridine(4-CNPy), 4,4-bipyridine,pyrazine, l,2-bis(4-pyridyl)ethane, 5-formyl -8- quinolinol as building blocks and Ammonium Metavanadate (NH4VO3) as subordinate building blocks by Hydrothermal , analysizing their content of element determining their structures by X-Ray diffraction.

本课题实验分为两部分:一是配体的合成,以8-羟基喹啉、三氯甲烷为原料,以乙醇为溶剂,合成了5—甲醛基—8羟基喹啉并且对其进行了IR的分析测定;二是配位聚合物的合成,通过分子设计,采用溶剂热法以Cu、Ni、Co为中心离子,以5—甲醛基—8羟基喹啉、4,4-联吡啶、吡嗪、1,2-二吡啶基乙烷为配体,以偏钒酸根(VO_3~-)为辅助配体,通过水热法自组装合成了新的3-D网状结构配位聚合物Co(μ_2-bpy)V_2O_6,(C_4H_4N_2)Ni_2(H_2O)_2·V_4O_(12),C_(12H_(12)N_2Co·V_2O_6,并对其进行了元素分析和晶体结构的测定。

The present invention discloses a polycarboxylic acid copolymer which is obtained by copolymerization of monomer components comprising a polyalkyleneimine unsaturated monomer (A2) and an unsaturated carboxylic acid monomer, the polyalkylene glycol unsaturated monomer (A2) having an oxyalkylene group bonded to a polyhydric alcohol residue, and the monomer component containing an unsaturated monocarboxylic acid monomer.

公开了一种多元羧酸共聚物,它是通过单体组分共聚制得的,所述单体组分包括聚二醇不饱和单体(A2)和不饱和一元羧酸单体,所述聚二醇不饱和单体(A2)具有使氧化烯基结合到多元醇残基上的结构,所述多元醇残基平均每个分子具有不少于3个羟基。

The DFT (B3LYP/6-31+G**) method was used to study the conformations and isomerization of the isolated and monohydrated 2',3'-dideoxy-2',3'-didehydroguanosine (D4G) molecules in gas phase.

采用密度泛函方法在B3LYP/6-31+G**水平上研究了2',3'-二脱氧-2',3'-二去氢鸟嘌呤核苷分子(D4G)的构象。

The DFT B3LYP/6-31+G(superscript ** method was used to study the conformations and isomerization of the isolated and monohydrated 2', 3'-dideoxy-2', 3'-didehydroguanosine (D4G) molecules in gas phase.

采用密度泛函方法在B3LYP/6-31+G水平上研究了2',3'-二脱氧-2',3'-二去氢鸟嘌呤核苷分子(D4G)的构象。

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