二分子

Then,the core molecule was used as a coupling agent to condensate with polyethylene glycolsof different molecular weight or polyethylene glycol monomethyl etherin the presence of stannous octoate as catalyst and diphenyl ether as azeotropic agent to remove water.

在辛酸亚锡催化下，以二苯醚为共沸脱水剂，将三官能度小分子TMP-SK3作为偶联剂，进一步与不同分子量的端羟基聚乙二醇和聚乙二醇单甲醚缩合，减压下共沸脱水，制备了以TMP-SK3为核，PEG或PEGm为臂的三臂星形大分子。

In this work , 1,8-octodiol, the starting material, reacted with 40% hydrobromic acid to produce 8-bromooctan-1-ol, with the catalytic action of PPTs, its hydroxyl group was protected by 2,3-dihydropyran. Then it coupled with 1-heptaalkyne, by means of P-2 nickel as catalyst, stereoselectivity catalysis hydrogenated, with the catalytic action of acid to take off extremital 2, 3-dihydropyran which protected hydroxy group, then used PCC to oxidize alcohol into corresponding aldehyde.

以1，8-辛二醇为原料，与40%氢溴酸进行单溴代反应，得到8-溴-1-辛醇，在对甲苯磺酸吡啶盐的催化下与2，3-二氢吡喃反应，保护分子中的羟基，再与1-庚炔进行偶联，以P-2镍为催化剂立体选择性催化加氢，酸性条件下脱末端的2，3-二氢吡喃对羟基的保护，使用氯铬酸吡啶盐将醇氧化成醛。

The organic template N, N'-diisopropylethylenediamine is believed to be formed through a reaction between isopropylamine and the solvent ethylene glycol.

结构中的有机模板剂N，N'-二异丙基乙二胺被认为是在合成过程中由异丙胺和溶剂乙二醇分子通过脱水生成。

Non-doped red-emitting electrofluorescent single-layer organic light-emitting devices based on an ambipolar small molecule, 4, 9-bis 4-(2, 2-diphenylvinyl phenyl naphtho[2, 3-c][1, 2, 5] thiadiazole, were studied.

以双极性小分子4， 9-二（4-（2， 2-二苯乙烯基）苯基）萘并[2， 3-c][1， 2， 5]噻二唑为发光层，制备得到了单层非掺杂红色荧光有机发光二极管。

The main research now is focused on the polymerization of difluoramino substituted oxetane monomers, the preparation of neopentyl difluoramino nitrato plasticizers, and the molecular design and synthesis of cyclic N2 nitramino geminal difluoramino oxidizers.

目前该领域的研究工作主要集中在二氟氨基取代环氧丁烷聚合物合成，新戊基二氟氨基硝酸酯增塑剂制备，以及环N2硝胺基偕二氟氨基氧化剂的分子设计与合成上。

Three single crystals of N-nitrobenzene, N-acyl dehydroabietic hydrazine 7c single water compounds, N, N-acyl dehydroabietic hydrazine 7l and 2,5 - dehydroabietic-1, 3,4 - oxadiazole 8g were obtained for the first time. X-ray diffraction analysis of these crystals showed dehydroabietic acid skeletons were contained in these crystal molecules.

首次得到N-去氢枞基，N-对硝基苯基双酰肼7c一水化合物、N，N-二去氢枞基双酰肼7l和2，5-二去氢枞基-1，3，4-噁二唑8g 3个单晶，并用X射线单晶衍射进行了解析，晶体中均含有去氢枞酸分子骨架。

In the third chapter, the synthesis of5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde oxime(2) from5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) and phenyl-hydrazine were introduced firstly. The synthesis of nine dioxapyrrolino[3,4-c]pyrazoles containing chiral pyrazolyl moiety(6a-i) from 2 with N-substituted-phenylmaleimide by nonmetal oxidant IBD-initiated intermolecular 1,3-dipolarcycloaddition was described in detail.

第三章首先以5-[(1′S)-1′，2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)和苯肼为原料，合成了化合物5-(1′S)-1′，2′-二乙酰氧基乙基1-1-苯基吡唑-3-醛-苯腙(2)；再用化合物(2)与N-取代苯基马来酰亚胺反应，利用无金属氧化剂—IBD引发1，3-偶极反应，发生分子间的环加成，合成了9种新型手性吡唑连二氧代吡咯啉并

The polymerized film has better antiwear lifethan the unpolymerized film because polymerization enhances the strenthof the thin film.

并用超分子自组装法将其与甲基丙烯酸十二醇酯和双甲基丙烯酸己二醇酯在玻璃基片上共组装成二氧化钛/有机物复合薄膜。

They are a group of chemicals, which include 75 different chlorinated molecules of dibenzo-p-dioxin and 135 chlorinated dibenzofurans.

他们是一组化学物质，其中包括75种不同氯化分子二苯并-对二恶英和135氯化氯二苯并呋喃。

The main intermediates were detected during decomposition,such as acetic acid,oxalic acid,malonic acid,phenol,3-hydroxyhypnone,naphthalene,benzene sulfonic acid,phthalic acid,β-naphthalene etc . by ultraviolet-visiblespectroscopy,ion chromatographand gas chromatograph coupled with mass spectrophotometertechniques.The possible degradation pathway of Acid Orange Ⅱ was also speculated,that was,hydroxyl radical reacted with the azo linkage-bearing carbon of naphthol-ring,and the C—N cleaved,the azo-dye decolored and mineralized.

运用紫外光谱、离子色谱、色谱-质谱联用等方法，测定出酸性橙Ⅱ的主要降解产物有乙酸、乙二酸、丙二酸、苯酚、3-羟基苯乙酮、萘、苯磺酸、邻苯二甲酸、β-萘酚等，并依此推测酸性橙Ⅱ的降解机理，即羟基自由基攻击酸性橙Ⅱ分子上与萘环相连的C—N键，导致C—N键的断裂，进而染料脱色矿化。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。