二分子

Some new lignans of dibenzocycloheptadiene and benzofuran analogues were first synthesized successfully by intramolecular nonphenolic oxidative coupling and rearrangement of the 1,4-biaryl-2,3-dimethyl-2,3epoxide substituted butanes with DDQ in TFA.

以DDQ为非酚氧化偶合试剂与1，4-二芳基-2，3-环氧类化合物进行分子内的非酚氧化偶合反应，首次合成了二苯骈环庚二烯类和苯骈呋喃类的新型木脂素，其结构由不同光谱和X-单晶衍射所确证。

HDI's molecular structure is a special saturated straight chain and it has highly unsaturated double bonds.It has such very lively and chemical properties that can be used to form polyurea with water. And it also reacts with polyurethane to form polyol, reacts with amine to biuret.

己二异氰酸酯分子具有特殊的直链饱和结构和含有高度不饱和双键的异氰酸酯基团，化学性质非常活泼，能够与水生成聚二脲，与多元醇反应生成聚胺酯，与胺反应生成缩二脲。

Vibrational circular dichroism is a useful technology to measure the circular dichroism of chiral molecules in the IR region, which remarkably expands the application of circular dichroism to the determination of AC.

振动圆二色谱是在红外波长区域测定分子圆二色性的一种新方法，极大地扩展了圆二色谱的应用范围。

Optically active cyclophane s, such as helical molecules and three-dimensional, cagelike cyclophanes have been the subject of extensive investigation from the standpoints of structural chemistry and material science.

本论文在大量的文献调研和本实验室过去研究结果的基础上，设计了由2，2'-二取代-1，1'-联萘和2，6-二取代吡啶，1，4-二取代苯，4，4'-二取代联苯三种不同连接桥通过炔键链接构筑的拓扑有趣的光学活性环芳化合物-四联萘笼状分子。

Crystal structural analysis reveals that, because water molecules bond to Cu atoms, the dhbd ligand can only adopt a hydroxyl oxygen atom to bridge two reversed U-shaped subunits into a novel centrosymmetric dual-U-shaped tetranuclear Cu structure. Each U-shaped frame consists of two crystallographically distinct Cu atoms, two dpphen ligands and one coordinated water molecule.

晶体结构分析表明，由于水的配位阻断， 2，3-二羟基丁二酸根仅通过单羟基氧桥联两个U形双核亚单元形成具有一个对称中心的双U形四核结构，其中U型亚单元包含晶体学上不对称的2个Cu原子、1个2，3-二羟基丁二酸根、2个4，7-二苯基-1，10-邻菲咯啉和1个配位H2O分子。

High relative molecular mass poly was synthesized by direct polycondensation of succinic acid and 1,4-butanediol in decalin solution at 140～200 ℃ for 12～14 h.

以丁二酸和丁二醇为原料，十氢萘为溶剂，在140~200℃反应12~14 h，进行直接聚合，合成了高相对分子质量聚丁二酸丁二醇酯。

And then the intermolecular reductive cyclization reaction of N,N-diethyl-o-nitrobenzenesulfonamide with nitriles promoted by samarium diiodide was studied. 2H-1,2,4-Benzothiadiazine 1,1-Dioxides were prepared in good yields under mild and neutral conditions.

然后研究了二碘化钐促进的邻硝基N，N-二乙基苯磺酰胺与腈发生的分子间交叉还原偶联反应，一步合成了2H-1，2，4-苯并噻二嗪-1，1-二氧化物。

Studing on samarium diiodide promoted asymmetric intramolecular reducing coupling reactions, we have made the resolution of the racemic biaryl dials by using enantiomeric N-tert-butanesulfinamine as the resolving reagent successfully and thus obtained a series of axially chiral biaryl dials with high enantiomeric excess.

中文摘要在二碘化钐促进的分子内不对称还原偶联反应中，我们不仅对联芳基二醛底物的合成路线进行了优化，还发现N-叔丁基亚磺酰胺辅基可以作为手性试剂，成功地对联芳基骨架二醛化合物进行拆分，得到高对映体过量的轴手性二醛类化合物。

The obtained CBC was further reacted with stearic acid at 140℃ and hexadecyl alcohol at 180℃ in turn to form citric acid-beta-butylene glycol-citric acidstearic acid-hexadecyl alcohol claw large molecule.

以1，3-丁二醇、柠檬酸为原料，设计、合成了以1，3-丁二醇为核心的柠檬酸－1，3-丁二醇－柠檬酸爪状物小分子；再用酯化反应依次与带有功能化集团的硬酯酸、十六醇接枝合成了多元酯类爪形大分子柠檬酸－1，3-丁二醇－柠檬酸－硬酯酸－十六醇。

The diode laser at 657 nm has the characteristics of lower cost and higher power than that at 633 nm. Therefore, we use the 657 nm ECDL to investigate the saturation spectrum of the hyperfine structure components of P(84) 5-5 transition of 127I2 at 657.483 nm for frequency stabilization of our ECDL laser.

nm 波段的二极体雷射比起633 nm 波段的二极体雷射拥有较低的费用和较高的功率，因此，我们使用657 nm 波段的外腔二极体雷射来研究657.483 nm 波段之碘分子跃迁P(84 5-5 transition of 127I2，并将我们的外腔二极体雷射稳频在此跃迁的超精细结构成分上。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。