二元腈

The coexistence curves and light scattering data for a critical solution of benzonitrile + octane have been reported. The critical exponents relating to the difference in the density variables between two coexisting phasesβ, the osmotic compressibilityγ, and the correlation length v have been deduced and the values were consistent with the 3D-Ising value in the range close to the critical point. The experimental results of the coexistence curves have also been analyzed to examine the Wegner correction terms and the behavior of the diameter of the coexistence curves.

用折射率法和不同角度的光散射法测量了苯甲腈+正辛烷二元体系在临界温度附近的液-液共存曲线和一相区不同温度下的渗透压缩系数及关联长度，得到与共存曲线相关的临界指数β，与渗透压缩系数相关的的临界指数γ和与关联长度相关的的临界指数γ，发现在近临界点体系符合3D-Ising模型，讨论了共存曲线直径和Wagner校正项。

The HPLC finger print of TGDGBX was set up by HPLC-DAD: the chromatographic column,Diamonsil C18(250 mm×4.6 mm, 5μm, 30℃)and bidimensional gradient elution using methyl cyanide-water (flowing speed 1.0 mL·min-1,λ=203 nm). 180 Wistar rats were randomly divided into normal control group, model group, cortisone group, and TGDGBX (16,32 and 64 mg·kg-1) groups respectively.

采用HPLC-DAD，Diamonsil C18色谱柱(250 mm×4.6 mm， 5μm)，乙腈―水二元梯度洗脱，流速1.0 mL·min-1，(λ=203 nm)，柱温为30℃，建立了当归补血总苷的HPLC指纹图谱。180只Wistar大鼠随机分为正常对照组、模型对照组、强的松组和当归补血总苷大、中、小剂量组，每组30只。

And it was used in the synthesis of long-chain dicarboxylic acid dinitril e with ammonia and tridecane dicarboxylic acid as reactants.

用TLC、IR、GC-MS检测产物的纯度和结构，并合成了一系列长链二元腈。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺；NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢；NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

For the saturated aromatic aldehydes with malononitrile and barbituric acidit, the reaction was found to proceed very efficiently at room temperature giving excellent yields under ultrasonic irradiation, while for α,β-unsaturated aldehydes as well as p-phthalaldehyde with malononitrile and barbituric acid the reaction also proceeded smoothly at room temperature with good yields.

在超声波辐射下，不仅饱和芳香醛与丙二腈、巴比妥酸的一锅反应在室温下能高收率地进行，而对于α，β-不饱和醛以及二元醛与丙二腈、巴比妥酸的一锅反应也能在室温下顺利进行，获得较高的收率。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行，获得了很高的收率；而对于杂环芳醛、α，β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合，需在50~65℃下进行，也取得了很高的收率；对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行，获得中等以上的收率。

Methods: In alkaline condition, reaction between amino acids and phenylisothiocyanate formed a derivant of phenylisothiocyanate-amino acid. For RP-HPLC, the Diamonsil C18 column 250 mm×4.6 mm,5 μm） and binary gradient elution were used. The mobile phase A was 0.1 mol/L sodium acetate solution-acetonitrile (93∶7） and the mobile phase B was acetonitrile-water（80∶20）. The detecting wavelength was 254 nm.

在碱性条件下，氨基酸与异硫氰酸苯酯反应，生成异硫氰酸苯–氨基酸的衍生物，采用 Diamonsil C18色谱柱（250 mm×4.6 mm，5 μm），用二元梯度洗脱方式，流动相A为0.1 mol/L乙酸钠–乙腈（93∶7），流动相B为乙腈–水（80∶20），检测波长254 nm。

A micro-monolithic column was prepared by in-situ free radical polymerization of stearyl methacrylate with ethylene glycol dimethacrylate in the presence of the initiator AIBN and a mixture of porogens including iso-amyl alcohol and 1,4-butanediol.

以甲基丙烯酸碳酰十八酯为单体，乙叉二甲基丙烯酸酯为交联剂，异戊醇和1，4-丁二醇为二元致孔剂，偶氮二异丁腈为引发剂，原位制备了具有强疏水性的SMA整体微柱，并利用此整体微柱在普通高效液相色谱仪上测定滴眼液中氧氟沙星的含量。

VLE data at different pressures of alcohols– nitriles (the number of the carbons is below 5) binary systems were calculated by Wilson equations.

在上述基础上，利用Wilson模型对5个碳以下的醇类和腈类组成的33种二元物系进行汽液平衡(来源：ABC56论文网www.abclunwen.com)数据的推算。

A method for simultaneous determination of oxytetracycline, tetracycline, chlortetracycline and choramphenicol in seafood was successfully developed using high performance liquid chromatography with ammonium acetate/water and acetonitrile as the mobile phase. The results showed that the four antibiotics were well separated under the optimum conditions, with the limits of detection being 32 μg/kg for oxytetracycline, 15 μg/kg for tetracycline, 23 μg/kg for chlortetracycline, and 19 μg/kg for choramphenicol. The recovery of standard additions was 76~92% and the relative standard deviation was 0.8-4.5%. The method is rapid, sensitive, accurate and reliable and can be applied in the analysis of antibiotic residues in seafood.

建立了同时检测海产品中土霉素、四环素、金霉素、氯霉素残留的高效液相色谱分析方法，以醋酸铵-醋酸/水缓冲液和乙腈作为流动相，通过二元梯度洗脱，使四种抗生素获得了较好的分离，以基线噪音的3倍计算，土霉素、四环素、金霉素、氯霉素最低检出浓度分别为32μg/kg、15μg/kg、23μg/kg、19μg/kg，在添加浓度范围内，四种抗生素的加标回收率为76~92%，相对标准偏差为0.8~4.5%，该方法快速、灵敏、准确，可靠性高，可用于海产品中抗生素残留的色谱分析。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失