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While all the phenyl groups in tetraphenylphenyl groups or benzophenanthrene groups are not coplanar. At the same time, by density function theory, the electronic energy gap between HOMO and LUMO frontier molecular orbitals of condensed aromatics are calculated and the Eg of acenaphthenyl groups in C_2 gum is the smallest, which explains the reason why C_2 gum has the best radiation protection effects.

利用甲基三氯硅烷和溴苯的格氏反应合成了甲基苯基二氯硅烷,用核磁分析证实了格氏反应中高沸点副产物为甲基二苯基氯硅烷;通过甲基苯基二氯硅烷和二甲基二氯硅烷的共水解,再裂解而制得含Me_2SiO链节的甲基苯基环硅氧烷混合物,进而利用碱胶开环聚合得到甲基苯基硅橡胶生胶;也可通过甲基苯基二氯硅烷水解所得甲基苯基环硅氧烷D_3~(3Ph、D_4~(4Ph_)与D_4开环聚合制得甲基苯基硅橡胶生胶。

Quick vulcanization adjuvant, and said adjuvant includes dithioalchol benzothiazole, dibenzothiazole disulfide, tetra methylthiuram disulfide, zinc methyl phenyl dithio carbamate and ethyleen thiourea.

助剂是:二硫醇基苯并噻唑、二硫化二苯并噻唑、二硫化四甲基秋兰姆、甲基苯基二硫代氨基甲酸锌、乙烯硫脲。

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分:一是电荷转移复合物的研究;二是丙烯酰氧基化不饱和聚酯的合成,表征,Ar-UPE/二缩乙二醇二乙烯基醚(DVE-3)体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究;三是氨酯改性的不饱和聚酯的合成,表征,PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究;四是乙烯基醚封端的聚氨酯的合成,表征,VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

Is a research and development, production, trade and service-based economy of foreign trade entities, chemical raw materials to the professional operation of the main company's existing production of AC blowing agent, ferric chloride, hydrated Hydrazine, p-nitrophenol, m-phenylenediamine, phosphorus trichloride, phosphorus oxychloride, 2,4 - diamino benzene sulfonate, sodium dichloro isocyanurate, N-methyl-o-phenylenediamine Second hydrochloride fine chemical products such as the ability, and are obtained ISO9001 international quality system certification.

济南华尔沃进出口贸易有限公司是一家集研发、生产、贸易、服务于一体的外贸型经济实体,以专业经营化工原料为主,公司现有生产AC发泡剂、三氯化铁、水合肼、对硝基苯酚、间苯二胺、三氯化磷、三氯氧磷、2,4—二氨基苯磺酸钠、二氯异氰脲酸钠、N-甲基邻苯二胺二盐酸盐等精细化工产品的能力,并且均以取得ISO9001国际质量体系认证。

Diethyl bis malonate was synthesized and analyzed by chemical ionization mass spectrum.

以丙二酸二乙酯为原料,合成了2, 2-二羟甲基丙二酸二乙酯。

Five of their single crystals were obtained and their structures were determined by X-ray diffraction. By comparison, it was found that dithiocabamate complexes often formed an exactly planar MS4 unit, such as [Mo(R2dtc)2]; and also formed a special MS 5 unit, such as [Cu2(R2dtc)4], the copper atom lies in a distorted square-pyramidal environment.Four kinds of heteropoly acids were prepared and characterized; a series of solid superacid catalyst of supported heteropoly acid were prepared and characterized; regioselectivites of chlorobenzene mononitration with nitric acid with different heteropoly acid on different supports and reaction conditions have been investigated.

培养并解析了5个该类配合物的单晶结构,通过比较,发现二硫代氨基甲酸盐与过渡金属容易形成四配位结构,金属原子与4个硫原子共平面,比如二乙基二硫代氨基甲酸钼;也能形成比较特殊的五配位结构,比如二乙基二硫代氨基甲酸双核铜,Cu原子与5个S原子相连,处于一个变形的四方锥结构的配位环境。

The results showed that myristic acid(14∶0) and linoleic acid (18∶2) were significantly increased,and positively correlated with the levels of TC, TG, LDL-C and apoB;while the levels of docosahexaenoic acid (DHA,22∶6),arachidonic acid (20∶4) and docosatetraenoic acid (22∶4) and stearic acid(18∶0) are significantly decreased, and inversely correlated with the levels of TC, TG, LDL-C and apoB in patients with hyperlipemia.

结果表明:患者肉豆蔻酸(14∶0)和亚油酸(18∶2)明显增高,与总胆固醇、甘油三酯、低密度脂蛋白-胆固醇和载脂蛋白B水平呈正相关;而二十二碳六烯酸(DHA,22∶6)、二十碳四烯酸(AA,20∶4)和二十二碳四烯酸(22∶4)以及硬脂酸(18∶0)明显降低,与TC、TG、LDL-C和apoB水平呈负相关。

The results showed that myristic acid(14∶0) and linoleic acid (18∶2) were significantly increased,and positively correlated with the levels of TC, TG, LDLC and apoB;while the levels of docosahexaenoic acid (DHA,22∶6),arachidonic acid (20∶4) and docosatetraenoic acid (22∶4) an...

结果表明:患者肉豆蔻酸(140)和亚油酸(182)明显增高,与总胆固醇、甘油三酯、低密度脂蛋白-胆固醇和载脂蛋白B水平呈正相关;而二十二碳六烯酸(DHA,226)、二十碳四烯酸(AA,204)和二十二碳四烯酸(224)以及硬脂酸(180)明显降低,与TC、TG、LDL-C和apoB水平呈负相关。

Diethylene glycol dibenzoate octyl is the latest developed high-performance PVC plasticizers, can effectively substitute for DOP ester, dibutyl.

二甘醇二苯甲酸辛酯是最新研制出的PVC高效增塑剂,能够有效替代邻苯二甲酸二辛酯、二丁酯。

Macrocycle with one pyridyl unit and one aryl oxdiazole unitCondensation of Ts-amino acids with 2,6-bishydroxymethyl pyridinegave di-esters in the presence of DCC and TsOH in pyridine. DMAP,another acylation catalyst was also discussed in our esterification.

二。含一个吡啶环和一个二苯基噁二唑单元:直接采用Ts保护的氨基酸与吡啶二醇在吡啶-TsOH反应体系中,在DCC作用下生成吡啶二醇二酯,讨论了酯化过程中不同酰基化试剂的应用。

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