二二二

Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1，1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3，4-二氯马来酰亚胺以及3，4-二氯香豆素进行增环反应的工作基础上，研究了3，4-二氯香豆素（1）和3，4-二氯马来酰亚胺（8）与5个α-苯基取代的环烯烃2-苯基苯并呋喃（15），3-苯基苯并呋喃（16），2，5-二苯基噁唑（17），2，5-二苯基噻唑（18），2-甲基-4-苯基噻唑（19），以及一个丁二烯——2，3-二甲氧基丁二烯（40）进行的芳香族增环反应。

Methods: The twelve volatile halogenated hydrocarbons (1, 1-dichloroethene, dicloromethane, trans-1, 2-dichloroethene, cis-1, 2-dichloroethene, chloroform-1, 1, 1-trichloroethane-1, 2-dichloroethane, tetrachloromethane, bromodichloromethane, dibromochloromethane, tetrachloroentene and bromoform) in drinking water were determined by headspace capillary gas chromatography.

采用顶空毛细管柱气相色谱法测定饮用水中1，1-二氯乙烯、二氯甲烷、反－1，2-二氯乙烯、顺－1，2-二氯乙烯、三氯甲烷、1，1，1-三氯乙烷、1，2-二氯乙烷、四氯化碳、一溴二氯甲烷、二溴一氯甲烷、四氯乙烯及三溴甲烷等12种挥发性卤代有机物。

A series of fluorenyl cardo polyimides were prepared by "one step" polycondensation of these cardo diamines with the dianhydrides4,4\'-oxydiphthalic anhydride(ODPA,3,3\'4,4\'-benzophenonetetracarboxylic dianhydride, 3,3\',4,4\'-biphenyl tetracarboylic dianhydrideand pyromellitic dianhydriderespectively.

由五种Cardo型二胺单体分别与3，3\'，4，4\'-二苯醚四酸二酐、3，3\'，4，4\'-二苯甲酮四酸二酐、3，3\'，4，4\'-联苯四酸二酐和均苯四甲酸二酐采用一步法溶液聚合制备了一系列芴基Cardo型可溶性聚酰亚胺。

We focused the study on the synthesis methods of quinoxaline, nitration of its aromatic ring and chlorination of its heterocycle. In this paper, we thought about environmental protection, the cost of material, the feasibility of industrialization, workup easily, and obtained 2,3(1H,4H)-quinoxalinedion, 6-nitro-2,3(1H,4H)-quinoxalinedion, 6,7-dinitro-2,3(1H,4H)–quinoxalinedion, 2,3-dichlo- roquinoxaline, 6–nitro-2,3-dichloroquinoxaline,and 6,7- initro-2,3-dichloro-quinoxaline. A more reasonable, easily, efficient and simple reactive route to synthesize above-mentioned compounds was developed by systematically investigating the yield, the purity and physical character of intermediates.

本文针对喹喔啉及其芳环硝化、杂环氯代的合成进行研究，主要考虑了环保性、原料成本、产业化的可行性、反应操作的简便性等问题，获得了2，3(1H，4H)-喹喔啉二酮、6-硝基-2，3(1H，4H)-喹喔啉二酮、6，7-二硝基-2，3(1H，4H)-喹喔啉二酮、2，3-二氯喹喔啉、6-硝基-2，3-二氯喹喔啉和6，7-二硝基-2，3-二氯喹喔啉等六个中间体，考察了反应产物的产率、纯度和性状等因素，得到了更为合理、方便、实用、简洁的可供产业化的合成路线。

The DSC results showed that calcium carbonate,sodium benzoate and terephthalic acid were the nucleating agents of polypropylene with high thermal stability of the nucleating effect,while the thermal stability of nucleating effect of pimelic acid,suberic acid,azelaic acid,and the two component nucleating agents suberic acid/calcium carbonate and azelaic acid/calcium carbonate were poor.

研究了碳酸钙、苯甲酸钠、对苯二甲酸和脂肪二元酸：庚二酸、辛二酸、壬二酸及其与碳酸钙组成的双组分成核剂对聚丙烯结晶成核效果的热稳定性。结果表明，高熔点物质碳酸钙、对苯二甲酸、苯甲酸钠的成核效果的热稳定性高，而脂肪二元酸的成核热稳定性低。庚二酸与碳酸钙组成的双组分成核剂的成核热稳定性高，但辛二酸、壬二酸与碳酸钙组成的双组分成核剂的成核热稳定性没有得到改善。

It summarizes the current advancements in the aboveOmentioned field in terms of eight aspects :①relations between L2 speech perception and production ,②L2 phonological studies ,③L2 speech segmental studies ,④L2 speech acquisition models ,⑤L2 speech suprasegmental studies ,⑥L1 transfer in L2phonological acquisition ,⑦nonO linguistic factors in L2 phonological acquisition ,and ⑧L2 speech instruction.

本文主要探讨了国外第二语言语音习得研究近年来的进展，着重涉及以下8 个方面：①二语口头话语感知与表达的关系、②二语口头话语的音系学研究、③二语口头话语的语段理论研究、④二语音系理论模型的构建、⑤二语口头话语的超音段研究、⑥二语音系习得中的母语迁移、⑦非语言因素对二语音系习得的影响、⑧二语语音教学研究。

Water,c12-20 acid peg-8 ester,octyldodecanol,cetearyl isononanoate,butylene glycol,biosaccaride gum-1,peg-40 hydrogenated caster oil,ethylhexyl menthoxycinnamate,phenoxyethanol,potassium cetyl phosphate,macadamia ternifolia seed oil,dimethicone,carbomer,propylene glycol,glyceryl stearate,cocoglycerides,butyrospermum parkii,c12-13 alkyl lactate,methylparaben,benzophenone-3,pentadecalactone,sorbic acid,citrus aurantium dulcis oil,sodium hydroxyde,tocopheryl acetate,disodium edta,iris germanica root extract,retinyl palmitate,equisetum arvense extract,butylparaben,peg-8,propylparaben,ethylparaben,sodium hyaluronate,chlorhexidine digluconate,citrus aurantium amaraoil,tocopherol,ascorbyl palmitate,citric acid,ascorbic acid,limonene,linalool

水，c12-20 acid peg-8 ester，辛基十二烷醇，鲸蜡硬脂醇异壬酸酯，丁烯二醇，多醣物质，PEG-40氢化蓖麻油，4-甲氧基肉桂酸-2-乙基己基酯，苯氧乙醇，十六烷基磷酸钾，澳洲胡桃子油，地美司康，卡波姆，丙烯乙二醇，甘油硬脂酸，椰油脂酸甘油酯类，牛油果，c12-13烷醇乳酸酯，对羟基苯甲酸甲酯，二苯甲酮-3 ，环十五内酯，山梨酸，甜橙油，氢氧化钠，维生素E醋酸酯，乙二胺四乙酸二钠，鸢尾花萃取，维他命A酯，问荆萃取，对羟基苯甲酸丁酯，聚乙二醇- 8，羟苯丙酯，羟苯乙酯，透明质酸钠，洗必泰葡萄糖酸盐，苦橙油，维生素E ，维生素C棕榈酸酯，柠檬酸，抗坏血酸，柠檬精油，沉香醇水：几乎所有护肤品成分第一位都是水。辛基十二烷醇：界面活性剂、乳化剂、稠化剂，有一定刺激性

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

The crystallization behavior of polyethylene terephthalate ; random poly (ethylene/tetramethylene terephthalate) P (ET/BT ; poly (ethylene terephthalate/ isophthalate) P (ET/EI and poly (ethylene terephthalate/adipate) P (ET/EA copolyesters; and block polyethylene terephthalate/polyethylene glycol and polyethylene terephthalate/polytetramethylene glycol were studied by DLI ; DSC; WAXD; PLM and IR technique.

中文题名PET及其共聚酯的结晶行为副题名外文题名 The crystallization behavior of PET and its copolyesters 论文作者边界导师封麟先叶胜荣教授学科专业高分子化学与物理研究领域\研究方向学位级别博士学位授予单位浙江大学学位授予日期2001 论文页码总数10，159页关键词聚对苯甲酸乙二酯聚酯结晶馆藏号BSLW /2003 /O633 /1 本文通过缩聚反应合成了不同分子量的聚对苯二甲酸乙二酯；聚对苯二甲酸酯P(ET／BT、聚（对苯二甲酸／间苯二甲酸）乙二醇酯P(ET／EI和聚乙二醇酯P(ET／EA等系列的无规共聚酯以及PET／PBG和PET／PEG等系列的嵌段共聚酯，并采用DLI、DSC、WAXD、IR和NMR等实验技术着重研究了它们的结晶行为与共聚酯的序列结构。

In comparison with the anaerobic batch fermentation of 1,3-propanediol from saponified glycerol, the bioprocess of two successive microbial fermentations for the production of 1,3-propanediol was feasible. The yield of 1,3-propanedio was higher than that of 1,3-propanediol directly from saponified glycero with 15 h in the two-stage fermentation in a 18h batch fermentation.

玉米淀粉。微生物发酵1，3一丙二醇(1，3-propanediol，简称1，3一PD)是一种重要的化工原料，与乙二醇、l，2一丙二醇和1，4一丁二醇有着相似的性质和用途，但又有许多其他二醇所不具备的优点，尤其是1，3-PD与对苯二甲酸合成的新型聚酯——聚对苯二甲酸丙二酯所展示的许多优良特性，使1，3一PD的研究开发日趋活跃。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。