二乙胺

We have had the extensive studies on theα-acetyl-α-carbamoyl ketene--acetals and its further applications, for example, their adols condensations with aldehydes giveα-alkenoyl-α-carbamoyl ketene--acetals which can be utilized as the 1,5-bielectronic five-carbon components to react with various binucleophlilic species in a [5+1] annulation.

我们小组在以前的工作中对α-乙酰基-α-胺甲酰基二硫缩烯酮在合成中的应用进行了深入的研究，如与醛缩合生成α-烯酰基-α-胺甲酰基二硫缩烯酮，将其作为1，5-双亲电五碳合成子的[5+1]成环策略等。

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料，在氢化钠存在下反应，合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应，用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2，4-咪唑啉-二酮、1，2，4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

N-(1-Naphthyl)ethylenediamine dihydrochloride solution was injected into the mixed flow of the water sample and sulfanilamide solution. Red dye formed by the reactions was spectrophotometrically detected at lλmax 540 nm.

将N-(1-萘基)乙二胺二盐酸盐溶液注入到水样和对氨基苯磺酰胺溶液的混合流，在lλmax 540nm处对反应形成的红色染料进行分光光度检测。

N-1-Naphthylethylenediamine dihydrochloride solution was injected into the mixed flow of the water sample and sulfanilamide solution. Red dye formed by the reactions was spectrophotometrically detected at lλmax 540 nm.

将N-1-萘基乙二胺二盐酸盐溶液注入到水样和对氨基苯磺酰胺溶液的混合流，在lλmax 540nm处对反应形成的红色染料进行分光光度检测。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行，获得了很高的收率；而对于杂环芳醛、α，β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合，需在50~65℃下进行，也取得了很高的收率；对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行，获得中等以上的收率。

The preparation of grafted derivant of tertiary amine: it is prepared by the reacting of above (1) product and (2) product heated in water bath at 40℃ within 10min.

聚环氧氯丙烷乙二醇哌啶接支衍生物的制备：将上面制备的聚环氧氯丙烷乙二醇与0.25mol环氧丙基哌啶叔胺于40℃水浴条件下进行接支反应。

The pegylated polylactide-poly glycolide nanoparticle, whose surface was co-modified withmaleimide-polyethylene glycol and methoxy-polyethylene glycol, was made by double-emulsion and solvent evaporation method andcovalently conjugated with thiolated lactoferrin via its maleimide functionalgroup.

第一章首先由复乳／溶媒蒸发法制备马来酰亚胺—聚乙二醇(Maleimide-PEG，MAL-PEG)和甲氧基聚乙二醇表面共修饰的聚乳酸-聚羟基乙酸纳米粒，然后通过其表面MAL-PEG与巯基化Lf共价连接而制备Lf-NP_。

A GC headspace injection method for the determination of residual organic solvents such as methanol, ethanol, acetonitrile, dichloromethane, ethylacetate, 4 methyl 2 pentanone, toluene, DMF, chloroform and tetrahydrofuran in tazobactam was established.

建立了气相色谱顶空进样法测定三唑巴坦中甲醇、乙醇、乙腈、二氯甲烷、乙酸乙酯、甲基异丁基酮、甲苯、N ，N′-二甲基甲酰胺、氯仿和四氢呋喃等有机溶剂的残留量。

Methods: After the sample being digested, because of ethylenediamine-hydrochloric acid, aluminium, chrome azurol S, the polyethylene glycol octyl phenyl ether together with hexadecylpyridine bromide form a steady blue quaternion system, whose absorbance and aluminium content is direct ratio within some consistence range.

样品经消化后，在乙二胺－盐酸缓冲介质存在下，铝与铬天青S和聚乙二醇辛基苯醚及溴代十六烷基吡啶形成稳定蓝色四元体系，在一定浓度范围内，其吸光度与铝含量成正比。

Synthesis of methylene-4,4'-di catalyzed by zinc oxide Various metal oxide were investigated in the synthesis of methylene-4,4'-di from ethyl carbamate, and a serious of ZnO/SiO2 catalysts were prepared by deposition-precipitation method.

氧化锌为催化剂合成4，4'-二环己基甲烷二氨基甲酸乙酯以氨基甲酸乙酯和4，4'-二环己基甲烷二胺的反应体系为研究对象，在考察多种金属氧化物活性的基础上，使用沉积沉淀法制备了一系列硅胶负载氧化锌催化剂，并对其催化性能进行了研究。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。