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New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明:1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体;2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下:(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2,3-双(2,6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2,6-二[1-(2,4,6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上,研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响,研究表明: 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理,可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体; 2、BET,XRD,IR,SEM,GPC和DSC研究表明,脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

With polyoxyethylene nonyl phenol ethers (OP-10) as emulsifier and dodecyl benzene sulfonic acid as catalyst, hydroxy organosilicon microemulsion was prepared through octamethylcyclotetrasiloxane (D4) open-ring polymerization under certain conditions.

以壬基酚聚氧乙烯醚(OR-10)作乳化剂,十二烷基苯磺酸为催化剂,通过八甲基环四硅氧烷(D4)开环聚合,在一定条件下合成了端在基聚二甲基硅氧烷微乳液。

The tool of Discover in the international popular software Materials Studio and the advanced COMPASS force field are adopted to simulate mechanical properties of PETN and PETN-based PBX at different temperatures, which is coated with four fluorine-containing polymers.

选择聚偏二氟乙烯、聚三氟氯乙烯、F2311和F2314作为粘结剂,对PETN及其与这4种含氟聚合物组成的PBX,用国际上流行的Materials Studio软件中的DISCOVER模块,以先进的COMPASS力场,主要模拟研究了PETN基PBX在不同温度下的力学性能。

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明,磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应,可以在颗粒表面引入少量羧基;磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应,可以在颗粒表面接枝不同分子链长度的末端羟基;磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基;磁性聚丙烯酸甲酯颗粒通过乙二胺或1,6己二胺的胺解反应可以得到表面氨基,继而与一氯乙酸反应可以引入亚胺二乙酸基团。

Quick vulcanization adjuvant, and said adjuvant includes dithioalchol benzothiazole, dibenzothiazole disulfide, tetra methylthiuram disulfide, zinc methyl phenyl dithio carbamate and ethyleen thiourea.

助剂是:二硫醇基苯并噻唑、二硫化二苯并噻唑、二硫化四甲基秋兰姆、甲基苯基二硫代氨基甲酸锌、乙烯硫脲。

R-1,c-2, t-3, t-4-1,3-bis(4-biphenyl)-2,4-di(4-pyridyl)cyclobutane was obtained in diluted sulfuric acid by photodimerization reaction.

通过反-1-(4-联苯基)-2-(4-吡啶基)乙烯在稀硫酸中的光二聚反应合成了r-1,c-2,t-3,t-4-1,3-双(4-联苯基)-2,4-二(4-吡啶基)环丁烷。

The invention relates to a pipeline polyurea outer anticorrosive coating and the making method thereof, making heated prepolymerization reaction on dibenzo-methane diisocyanate, carbodiimide diisocyanate, polyether binary alcohol and polyether trihydric alcohol to prepare prepolymer solution A, and making end amino polyethylene oxide ether, dimethyl sulfur-based toluene diamine, diethyl diamine, iso-propyl titanate solution, polyacrylate, carbon black, titanium dioxide and lightweight calcium carbonate into solution B, and as using, respectively heating the solutions A and B to 65 deg.C and then mixing them, then quickly spraying and curing to form a coat.

本发明涉及一种管道用聚脲外防腐涂料及制造方法,由二苯基甲烷二异氰酸酯、碳化二亚胺化二异氰酸酯、聚醚二元醇和聚醚三元醇通过加热预聚反应制成预聚物的A液、由端氨基聚氧化乙烯醚、二甲硫基甲苯二胺、二乙基甲苯二胺、钛酸异丙酯溶液、聚丙烯酸酯溶液、碳黑、钛白粉和轻质碳酸钙配制而成的B液组成,使用时将A液和B液分别加热至65℃后混合,然后快速喷涂固化形成涂层。

Treatment of polystyrene-supported selenium ,bromide with lithium acetylides afforded polystyrene-supported selenoacetylene, which reacted with dicyclohexylborane giving a way for stereoselective synthesis of polymer-supported- vinylic selenides .

聚苯乙烯负载硒溴与炔基锂反应合成聚苯乙烯负载炔基硒醚,再与二环己基硼烷反应制得聚苯乙烯负载顺式烯基硒醚;此负载型烯基硒醚在NiCl2(PPh3)2存在下与格氏试剂发生偶联反应,提供了一种有效的-1,2-二取代乙烯的固相有机合成方法

I for Hong Kong and Taiwan-owned business enterprises in the chemical industry more than twenty years of marketing, agent distribution Chemical famous brand, the main service items are as follows: methanol, ethanol, ethylene glycol, n-butyl alcohol, isobutyl alcohol, isopropyl alcohol, ice acetic acid, vinyl acetate, acetic acid acetate, acetic acid Ding resin, styrene, toluene, phthalic anhydride, xylene, acetone, butanone, cyclohexanone, DMF, sulfuric acid, methyl isobutyl ketone, glycol ether, three toluene, octyl resin, melamine, and so on.

我公司为港台商独资企业,于化工行业行销二十余年,代理经销国外著名化工品牌,主要服务项目如下:甲醇、乙醇、乙二醇、正丁醇、异丁醇、异丙醇、冰醋酸、醋酸乙烯、醋酸乙脂、醋酸丁脂、苯乙烯、甲苯、苯酐、二甲苯、丙酮、丁酮、环己酮、DMF、硫酸、甲基异丁基酮、乙二醇丁醚、三甲苯、二辛脂、三聚氰胺,等等。

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歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车,和一双合并为一移交&整个lotta爱&。

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