二乙烯基

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分：一是电荷转移复合物的研究；二是丙烯酰氧基化不饱和聚酯的合成，表征，Ar-UPE/二缩乙二醇二乙烯基醚（DVE-3）体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究；三是氨酯改性的不饱和聚酯的合成，表征，PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究；四是乙烯基醚封端的聚氨酯的合成，表征，VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

For the reaction between divinyl sulfone and N-ethylethylene-diamine or N-methylpropane-1, 3-diamine , no cross-linking occurred when the feed ratio of A〓 to BB'〓 was 1/1. When the feed ratio of DV to NDA or NPA is 3/2, no cross-linking occurred too in organic solvents such as DMSO, DMF and NMP, while cross-linking does occur in water.

对于二乙烯基砜与N-乙基乙二胺或N-甲基-1，3-丙二胺的反应，当加料配比为1／1时，反应在水和有机溶剂中不会凝胶；当配比为3／2时，反应在有机溶剂中亦不凝胶，而在水中反应时，会经过一种&假凝胶&过程，并最终发生凝胶。

Bis vinyl phenyl terminated polydimethylsiloxane was synthesized by the hydrosilylation of bis dimethylhydrogen siloxyl terminated PDMS with m divinyl benzene. The structure of the VTPDMS was characterized by 1H NMR.

通过双二甲基氢硅氧封端的聚二甲基硅氧烷与间二乙烯基苯的硅氢加成反应制备了双乙烯基苯封端的聚二甲基硅氧烷，用1H NMR对其结构进行了表征。

Results showed that the monomer conversion increased slightly in the presence of the crosslinking agents The size of particles decreased slowh as the amount of cmsslinking agent increased.and the size distribution of the particles broadened at a higher amount of cmsslinking agent Divinyl benzene was more effective than ethyl glycol dimethyl methacrylate to make polymer crosslinked.During alkali treatment process,void latex particles can be obtained when no DVB or less than 0.5 wt％ of EGDMA was used,while muhihollow structure was generated when DVB or more than 1.0 wt％ of EGDMA was introduced.The volume expansion of the particles decreased with increasing the amount of emsslinkirlg agents.

结果表明，体系中加入交联剂后，单体转化率都有不同程度的提高；随交联剂用量的增加，乳胶粒粒径略有减小，交联剂用量较高时，乳胶粒粒径分布加宽；二乙烯基苯的交联效率稍高于双甲基丙烯酸乙二醇酯；不加入交联剂及EGDMA用量低于0.5%时，处理后乳胶粒呈空腔结构，加入DVB及EGDMA用量高于1.0%时，处理后乳胶粒呈多孔结构，并且乳胶粒体积增量随交联剂用量的增加而减小。

Two novel A-it-A' type benzothiazole-based derivatives with benzothiazolyl, phenyl-acetyl or pyridine cation groups as π electron acceptor, diethenylphenyl as π conjugated bridge: 4-(2-benzothiazolyl) ethenylchalcone (1) and 4-{4-[2-(benzothiazole-2-yl) ethenyl] styryl}-N-methylpyridinium iodide (2) were synthesized.

以苯并噻唑、苯乙酰基和吡啶阳离子为电子受体，二乙烯基苯为共扼桥，合成了两个新的A-π-A'型苯并噻唑衍生物：4-（2-苯并噻唑）－乙烯基查尔酮(1)和4-｛4-［2-乙烯基］苯乙烯基｝－N-甲基吡啶碘盐(2)。

Two novel A-π-A′ type benzothiazole-based derivatives with benzothiazolyl,phenyl-acetyl or pyridine cation groups as π electron acceptor,diethenylphenyl as π conjugated bridge: 4-(2-benzothiazolyl)ethenylchalcone(1) and 4-{4-[2-(benzothiazole-2-yl)ethenyl]styryl}-N-methylpyridinium iodide(2) were synthesized.

以苯并噻唑、苯乙酰基和吡啶阳离子为电子受体，二乙烯基苯为共轭桥，合成了两个新的A-π-A′型苯并噻唑衍生物：4-(2-苯并噻唑)-乙烯基查尔酮(1)和4-{4-[2-乙烯基]苯乙烯基}-N-甲基吡啶碘盐(2)。

In the polymerization procedure,S--α-phenyl ethylamine was used as target template molecules,methacrylic acid was selected as functional monomers, ethylene glycol dimethacrylate or divinylbenzene as crosslinker, azobisisobutyronitrile or benzophenone was used as irritator.

以S--α-苯乙胺为模板，甲基丙烯酸为功能单体，分别以二甲基丙烯酸乙二醇酯、二乙烯基苯为交联剂，偶氮二异丁睛或二苯甲酮为引发剂，采用了本体聚合法、悬浮聚合法合成了一系列的S--α-苯乙胺印迹聚合物。

Hydrophobic-hydrophilic macroporous polydivinylbenzene/polyacrylethylenediamine interpenetrating polymer networks (PDVB/PAEM IPN) were prepared by the sequential suspension polymerization method. These were composed of two networks, of which one was hydrophobic and the other was hydrophilic. The objective of this work was to study the adsorption thermodynamics and adsorption kinetics of this hydrophobic- hydrophilic IPN. The focus was on adsorption isotherms of vanillin at different temperatures, and these fit well into the Freundlich adsorption isotherm. The isosteric adsorption enthalpy, adsorption Gibbs free energies and the adsorption entropy could be calculated according to thermodynamic functions.

采用分步悬浮聚合法制备了具有疏水性能的聚二乙烯基苯(polydivinylbenzene， PDVB)为第一网，具有亲水性能的聚丙烯酰乙二胺(polyacrylethylenediamine， PAEM)为第二网的疏水／亲水大孔聚二乙烯基苯／聚丙烯酰乙二胺互穿聚合物网络(interpenetrating polymer networks， IPN)，研究这类疏水／亲水IPN组成的树脂对吸附质的吸附热力学和吸附动力学；测定了该树脂对香兰素在不同温度下的吸附等温线，吸附等温线符合Freundlich等温吸附方程，利用热力学函数关系计算出了吸附焓、自由能和熵变。

Therefore it can he inferred that diethylenetriamine oxycellulose synthesized have the function of adsorbability for uric acid and As.

由此可知所研制二乙烯基三胺基氧化纤维素具有分别吸附尿酸和三价砷的功能。

Tris-(1-aziridinyl)- phosphine oxide and 2-[bis-(2-chloroethyl)-amino]-tetrahydro-1, 3, 2-oxazaphospholidine-2-oxide(Ⅲ, B-518) possess inhibitory action against a variety of animal tumours and have been used clinically. Recently, bis-(1-aziridinyl)-phosphinyl carbamic acid ethyl ester(Ⅱ, AB-100) was found to possess significant activity with low toxicity on experimental animal tumours.

双(2-氯乙基)氨基磷酰二氯与乙烯亚胺在脱水苯或对氧六环中并在三乙胺的存在下进行缩合，生成N，N-双(2-氯乙基)-N′，N-二乙烯基-磷酰胺；与双巯基或双氨基化合物作用，则生成相应的环状磷酰胺、磷酰胺酯以及磷酰胺硫代酯氮芥类化合物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。