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Uncured natural rubber is sticky, easily deforms when warm, and is brittle when cold. In this state it cannot be used to make articles with a good level of elasticity .

一般需经过硫化的橡胶品种有丁二烯、氯丁二烯、异戊二烯的1,4-聚合物--顺丁、异戊、氯丁橡胶,以及共聚物丁苯、丁基和丁腈橡胶等。

Formylation and diformylation of dithieno [2,3-b:3',2'-d] thiophene were prepared by two methods. Firstly, aromatic carbanions were prepared by 1 Br/Li exchange of bromo dithieno[2,3-b:3',2'-d]thiophene with n-BuLi in THF at low temperature; 2 deprotonation of dithieno[2,3-b:3',2'-d]thiophene with LDA.

二噻吩并[2,3-b:3',2'-d]噻吩单醛与双醛的制备首先通过两种方法产生芳基负离子:1溴代并三噻吩在四氢呋喃中与正丁基锂发生的溴锂交换;2用LDA对二噻吩并[2,3-b:3',2'-d]噻吩去质子化作用。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明,在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中,于90℃下,己烯与三乙氧基硅烷反应的转化率为100%,β加成物的选择性可达89.0%,而用Rh(PPh_3)_3Cl作为反应的催化剂,在纯离子液体BMImPF_6中,就可以高效催化烯烃与三乙氧基氢硅烷的加成反应,过渡金属Rh(PPh_3)_3Cl,Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系,不仅解决了产物与催化剂分离困难这一难题,同时,离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl,Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性,特别是β加成物的选择性。

Diethylene gly- col butylmethyl ether was synthesized through the Williamson reaction between butyl bro- mide (n-C_4 H_9 Br) and CH_3 OCH_2 CH_2OCH_2 CH_2 ONa.

通过正溴丁烷与二乙二醇单甲醚钠的Williamson反应合成了二乙二醇甲基丁基醚。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3,4-二溴马来酰亚胺进行N-甲基化反应合成3,4-二溴-N-甲基马来酰亚胺的同时,以碳酸二甲酯为甲基化试剂,对3,4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究;考察了1,4-二氮杂双环[2.2.2]辛烷,1,8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响,并应用碳酸二甲酯为甲基化试剂,合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物,使用六齿配体合成了一系列含有两个〓单元四核笼状化合物,并用各种谱学手段表征了它们,还研究了它们的物理化学性质确定了〓L=N,N,N',N'-四(苯骈咪唑基-1,4-丁二胺和〓,〓四-1,4-丁二胺化合物的晶体结构,它们含有两个〓单元,其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

The average epoxy value and the average viscosity of such diluent were 0.502×10-2eq/g and 3.2 mPa.s(25 ℃) respectively. It was an ideal diluent and could be used instead of active diluent such as butyl epihydrin etc. and non-active diluent such as dibutyl phthalate etc. in epoxy resin industry. The preparation of the epoxy diluent by fusel oil could not only settle the problem of environmental pollution caused by fusel oil drainage, but also produce economic and social benefits.

结果表明,杂醇油制备的环氧树脂活性稀释剂环氧值平均为0.502×10-2eq/g,环氧值适中;粘度平均值为3.2 mPa.s(25 ℃),粘度较小,为比较理想的环氧树脂活性稀释剂;该环氧树脂活性稀释剂可望代替环氧丙烷丁基醚等活性稀释剂和邻苯二甲酸二丁酯等非活性稀释剂应用于环氧树脂工业;可解决酿酒企业和酒精厂下脚料杂醇油排放带来的环境污染问题。

Preferred examples of thermal initiators include persulphates especially sodium and ammonium persulphate, peroxides especially benzoyl peroxide, t-butyl hydroperoxide and lauryl peroxide, and azos, especially azobisisobutyronitrile.

热发起者首选的例子包括硫酸盐,尤其是钠,过硫酸铵的,过氧化物尤其是过氧化苯甲酰的吨丁基过氧化氢和十二烷基过氧化物,和azos,尤其是二异丁腈。

Segmented polyester polyurethaneurea based n 4, 4'-disphenylmethane diisocyanate, ethylene diamine and polybutylene adipate elastomers and their deuterated polymers were studied by means of IR spectroscopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯的嵌段聚酯型聚脲氨酯弹性体及其氘化產物进行了研究。

The conductivity and the molar conductivity of the ionic liquid in actone, water, DMF, acetic acid were investigated at different temperatures.

利用磷酸三丁酯与N-甲基咪唑在恒温150℃下一步合成了离子液体1-丁基-3-甲基咪唑磷酸二丁酯,考察了其在丙酮,水,DMF,乙酸溶剂中的电导率及摩尔电导率。

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Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

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