乳酰胺

The cationic diamide softener can be emulsified by emulsifying agent, and the emulsion of cationic diamide softene can be used as softening agent in Papermaking. The results showed that the emulsion of the cationic diamide softener is stable and homogeneous when the dosage of emulsifying agent cetyltrimethylammonium chloride is 10% in the emulsifying process.

摘 要：以硬脂酸和二乙烯三胺经酰化反应制得二硬脂酰化物，用环氧氯丙烷阳离子化后，再加入乳化剂乳化，可制得带有反应性基团环氧基的新型双酰胺阳离子乳液型纸张柔软剂。

In this paper the emulsion of polyacrylamide was synthesized in the polyglycol solutions, acryl amide and acrylic acid sodium was used as the monomer. In more detail, we investigated the effect of the concentration of the monomers, the ratio of monomer and PEG, the ratio of monomers, temperature, and emulsifier on the stability of the HPAM emulsion and the molecular weight of the HPAM.

为了提高聚丙烯酰胺相对分子质量，以丙烯酰胺与丙烯酸钠为原料，在聚乙二醇水溶液中合成了聚丙烯酰胺水包水乳液，考察了初始单体质量分数、共聚单体与聚乙二醇摩尔比、共聚单体摩尔比、聚合反应温度、乳化剂种类及其浓度对HPAM水包水乳液稳定性及相对分子质量的影响，所得共聚产物相对分子质量可达1.5×10^7。

In this Ph. D. dissertation, reverse microemulsion method was fully used infabricating and modifying polyacrylamide with functional and high-relative moleculeweight. The copolymerization of 2-acrylamide-2-methylpxopanesulfonic acid, fluorescent monomer 4-methoxy-N-(2-N\', N\'-dimethylamino ethyl)naphthalimide alkyl chloride quaternary ammonium salt, fluorescentmonomer 4-(N\'-methyl-1-piperazinylallyl)-N-butyl-naphthalimide chloride quaternaryammonium salt, Cationic monomer dimethylethylammonium bromide and hydrophobical monomer octadecylacrylate with acrylamide and properties of the copolymers werestudied. The interaction between five polymers and Al_2O_3(012) crystal surface have beensimulated by Materials Studio 3.0 program package, binding energies and non-bondinteraction energies and deformation energies have also been acquired.

本文以制备具有较高相对分子质量和功能型PAM为研究目的，将反相微乳液法运用到其制备及改性的有关环节，通过反相微乳液聚合工艺，将几种改性功能单体2-丙烯酰胺基-2-甲基-丙磺酸、荧光单体2-(4-甲氧基-1，8-萘二甲酰亚胺基)-乙基二甲基烯丙基氯化铵、荧光单体4-(N'-甲基-1-哌嗪基)-N-丁基-1，8-萘烯丙氯季铵盐、阳离子单体丙烯酰氧乙基-二甲基-乙基溴化铵和疏水单体丙烯酸十八酯与AM共聚，制备AMPS改性PAM、荧光示踪型PAM、阳离子单体DMB改性PAM和OA改性PAM等四类不同功能单体改性PAM，并研究其应用性能。

The formation of microemulsion system containing emulsifier,acrylamide,2-ethyltrimethyl ammonium chloride,sodium-2-acrylamido-2-methyl-propane-sulfonate and hexamethylene was studied.

对复配乳化剂(span+tw een)、丙烯酰胺、(2-甲基丙烯酰氧乙基)三甲基氯化铵、2-丙烯酰胺基-2-甲基丙磺酸钠和环己烷组成的微乳液体系进行了研究，研究了单体总质量浓度、AM摩尔含量和阴阳离子单体配比改变对形成微乳液需要的适宜H LB值和最小乳化剂用量的影响。

Firstly, Copolymerization of acrylamide and styrene was carried out in a microemulsion system, in which AM aqueous solution was the continue phase and St was the dispersed phase using ST-80 as surfactants respectively, then hydroxamic functions were prepared with hydroxylamine salt at temperatures of from 60℃ to 90℃.

首先以丙烯酰胺水溶液为连续相，以苯乙烯为分散相，ST-80为乳化剂制成微乳液，在15℃~35℃合成丙烯酰胺与苯乙烯的共聚物；然后采用程序控温方式，在60℃~90℃用硫酸羟胺将共聚物羟肟化合成了一种带有苯环结构的嵌段型氧肟酸类聚合物材料。

At 15-35℃, copolymerization of acrylamide and styene was carried out in a microemulsion system, in which AM aqueous solution was the continuous phase and St was the dispersed phase using ST-80 as surfactants, respectively. Hydroxamic functions were prepared with hydroxylamine salt at temperatures from 60℃ to 90℃.

以丙烯酰胺水溶液为连续相，苯乙烯为分散相，ST-80为乳化剂制成微乳液，在15~35℃下合成丙烯酰胺与苯乙烯的共聚物，采用程序控温方式，在60~90℃下使用硫酸羟胺将共聚物羟肟化得到产物。

Copolymer of acrylamide and acryloyloxyethyl trimethyl ammonium chloride was prepared by dispersion polymerization in a salt solution.

摘 要：以丙烯酰胺和丙烯酰氧乙基三甲基氯化铵为共聚单体，采用分散聚合法在无机盐水溶液中制备了性能稳定的阳离子聚丙烯酰胺乳液。

The paper copolymerizes cationic polyacrylamide by aqueous solution copolymerization copolymerization and inverse emulsion copolymerization, and determines the art of it. On the base of determination, makes experiments on the conditions for copolymerization of cationic polyacrylamide, and attain wastewater's flocculant with perfect performances.

本文分别用水溶液共聚法和反相乳液聚合法合成了阳离子聚丙烯酰胺，并对合成的工艺条件进行了探索，在此基础上，对阳离子聚丙烯酰胺合成不同的条件进行了应用实验，筛选出了性能较好污水处理剂阳离子聚丙烯酰胺。

Aiming at the shortcomings of high formaldehyde content and low soaping and crocking fastnesses of currently used pigment printing binder,by60Co-γ radiation polymerization process,the waterborne polyacrylate emulsion containing active keto groups was synthesized from acrylate monomers and diacetone acrylamide.

针对目前所用涂料印花黏合剂存在的色牢度低和甲醛含量高的缺陷，采用钴60-γ辐射法聚合工艺，利用丙烯酸酯单体、双丙酮丙烯酰胺合成出含活性酮羰基的丙烯酸酯乳液；然后同含端酰肼基聚氨酯乳液按一定的比例混合，制备出酮肼交联型丙烯酸酯聚氨酯复合乳液。

Two new methods about preparation of nano-inorganic coated polymer microsphere have been found. The research mainly focused on controlled precipitation of inorganic precurdors onto the polymer microspheres, technique of preparation and size distribution of transition metal oxides and sulfides emulsion particles, nano-paticles''surface modification and the HLB values adjustment, emulsification of oil-soluble monomer in inorganic colloid and emulsion stability, emulsion polymerization that inorganic particles act as medi-phase, the preparation of inorganic nano-particle/polymer hybrid microspheres, preparation of hybrid materials in inverse emulsion, inverse emulsion polymerization of acrylamide and its phase behavior. Inorganic nano-particles we studied concerning TiO2、SiO2、Fe3O4、ZnO、ZnS、Ag and black carbon. Also we studied the morphology and capability of the hybrid materials.

主要内容有：无机物在高分子乳胶模板体系的界面定位沉积研究；过渡金属氧化物、硫化物纳米胶体粒子的制备工艺与胶粒尺寸分布研究；纳米粒子的表面修饰及其亲水亲油平衡值的调制；油溶性单体在无机胶体中的乳化行为与乳液稳定性研究；以无机纳米粒子做中介相的乳液聚合与无机纳米粒子/高分子复合微球制备研究；反相体系中杂化材料的制备；丙烯酰胺水溶液反相乳液聚合、相行为与稳定性；丙烯酰胺反相体系中无机粒子的制备研究；涉及到TiO2、SiO2、Fe3O4、ZnO、ZnS、Ag、碳黑等纳米无机物，系统考察了相关材料的形态与性能，为其应用开发奠定了基础。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。