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乙醇醛

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Firstly, 24 chiral Schiff base ligands were prepared and evaluated for theasymmetric HDA reaction between Brassard diene with benzaldehyde. Theresults revealed that the ligand derived from 3,5-di-tert-butylsalicylaldehydewith (1R,2S)-2-amino-1,2-diphenyl-1-ethanol shows an excellent chiralinduction in the reaction.

首先合成了 24 个手性三齿席夫碱配体,并应用于 Brassard 二烯与苯甲醛的不对称 Hetero-Diels-Alder 反应,结果表明,3,5-二叔丁基水杨醛与(1R,2S)-1,2-二苯基-2-氨基-乙醇生成的单席夫碱显示出优秀的手性诱导能力。

And the characteristics of body their trace components are as follows: Luzhou-flavour liquor has ethyl caproate the main flavour component with its content 160~250mg/100ml (above 40% of total ester); Fen-flavour liquor has ethyl acetate the main body flavour component, above 50% of total ester, and the content of ethyl lactate and ethyl acetate above 90% of total ester; Tte main body flavour component of Maotai-flavour liquor is still uncertain, and it has higher furfural content (260mg/100ml); Sanhua-flavour liquor,β-phenethyl alcohol is a special characteristic for it and the content of ethyl lactate is 73% of total ester; In other flavour liquors,the specific flavouring components vary because of different types.

其微量成分特征为:浓香型白酒以己酸乙酯为主,含量在160~250mg/100ml,占总酯40%以上;清香型白酒以乙酸乙酯为主体香,占总酯的50%以上,乙酸乙酯与乳酸乙酯的含量占总酯90%以上;酱香型白酒的主体香暂无定论,其糠醛含量较高,达260mg/100ml;米香型白酒以β-苯乙醇为特征成分,乳酸乙酯含量占总酯高达73%。其他香型白酒因门类不同,以数种成分为其特征。

Water,c12-20 acid peg-8 ester,caprylic/capric triglyceride,proplylene glycol,ppg-15 stearyl ether,chondrus crispus,iris germanica(orris extract/cells),centaurea cyanus,macadamia ternifolia,buxus chinensis,triethanolamine,potassium cetyl phosphate,butyrospermum parkii,c12-13 alkyl lactate,carbomer,phenoxyethanol,methylparaben,imidazolidinyl urea,glyceryl hydroxystearin,tocopheryl acetate.retinyl palmitate,sodium hyaluronate,biosaccharide gum-1,propylparaben,disodium edta,ethylparaben,pentadecalactone,hydroxystearic acid,tetradecyloctadecanoic acid,tetradecyleicosanoic acid,hexadecyleicosanoic acid,butylparaben,isobutylparaben,chlorhexidine digluconate,tocopherol,lecithin,ascorbyl palmitate,glyceryl stearate,glyceryl oleate,BHT,citric acid.

水,C12-20 酸 PEG-8酯,辛酸/癸酸三酸甘油酯,丙二醇,PPG-15 硬脂基醚,卡拉胶萃取,德国鸢尾花提取物/细胞,矢车菊提取物,澳洲坚果油,荷荷巴油,三乙醇胺,十六烷基磷酸钾,牛油果,c12-13烷醇乳酸酯,卡波姆,苯氧乙醇,羟苯甲酯,尿素醛,甘油羟基硬脂酸酯,醋酸盐维他命E,维他命A酯,透明质酸钠,多醣物质,羟苯丙酯,乙酸乙二胺二钠,羟苯乙酯,环十五内酯,羟基硬脂酸,十四烷基十八烷酸,十四烷基二十烷酸,十六烷基二十烷酸,羟苯丁酯,对羟基苯甲酸异丁酯,洗必泰葡萄糖酸盐,维生素E,卵磷脂,抗坏血酸棕榈酸酯,甘油硬脂酸,甘油油酸酯,BHT,柠檬酸。水:几乎所有护肤品成分第一位都是水。辛酸/癸酸三酸甘油酯:润滑剂、扩散剂,棕榈油/椰子油衍生物

Experimental process: jing and 3- methyl -2- methyl ethyl ketonesynthesizes by the benzene zong; Again the glacial acetic acidcatalysis produces 2, 3, 3 - trimethyl - 3H - yinduo; Again has thealkylate response production yinduo iodide after the methyl iodide;The iodide takes off molecular HI under NaOH to become freejier thealkali; Adds 5 - nitryls salicylic aldehydes in the ethyl alcohol forthe solvent under if to respond finally produces 6 '- the nitryl yinduolin spiral benzene and pinan; Through the infrared spectrum andthe ultimate analysis irrevocably proved its structure, and studiedthe annulus with to open the annulus the light to send changes colorthe performance, explained in different solvent medium ultravioletabsorption spectrometry solvent effect, and the comparisondiscoloration the response speed number difference, finally mixed itadds to the methyl methacrylate, the peroxidation benzoin formyl in the plexiglass, tested 6 '- the nitryl yinduolin spiralbenzene and pinan in the glass fatigue resistance, thethermostability.

实验过程:由苯肼和3-甲基-2-丁酮合成腙;再冰醋酸催化生成2 ,3 ,3—三甲基—3H—吲哚;再经过碘甲烷发生烷基化反应生成吲哚碘化物;碘化物在NaOH下脱去一分子HI成为费歇尔碱;在乙醇为溶剂下加5-硝基水杨醛与其反应最后生成6'—硝基吲哚啉螺苯并吡喃;通过红外光谱和元素分析确证其结构,并研究了环体与开环体的光致变色性能,解释了在不同溶剂介质中紫外吸收光谱的溶剂效应,并比较褪色反应速率数的差异,最后将其掺加到甲基丙烯酸甲酯,过氧化二苯甲酰有机玻璃中,测试6'—硝基吲哚啉螺苯并吡喃在玻璃中的抗疲劳性、热稳定性。

Rats in model control group were treated with distilled water while those in silibinin group were treated with 100 mg/kg silibinin. Meanwhile, 100 mL/L ethanol and hyperalimentation feed were given for 4 weeks. After animals were killed, TG, SOD, GSH and MDA levels were measured with liver suspension.

同时继续给予100 mL/L乙醇和高营养饲料,4周后在麻醉状态下处死大鼠,取大鼠肝块进行病理观察,测定三酰甘油、超氧化物歧化酶、还原性谷胱甘肽和丙二醛水平。

Results: The MBCs of ethanol, glutaraldehyde disinfectant, ShiKang disinfectant and quaternary ammonium disinfectant against multidrug-resistant Acinetobacter baumannii were 45%, 10000 mg/L, 6.3~12.5 mg/L and 100 mg/L, and the MBCs were 40%, 5000 mg/L, 3.1~6.3 mg/L and 50 mg/L Conclusion: MBC and MIC could represent the sensitive dose of multidrug-resistant Acmetoborter baumannu to disinfectants, and eight strains of multidrug-resistant Acinetobacter baumannii have certain resistance to some common disinfectants.

结果:乙醇、戊二醛消毒液、施康消毒液、季铵盐消毒剂对多重耐药鲍曼不动杆菌的MBC值分别为45%、10000 mg/L、6.3~12.5 mg/L、100 mg/L;MIC值分别为40%、5000 mg/L、3.1~6.3 mg/L、50 mg/L、50 mg/L。结论:MBC值和MIC值能基本反应多重耐药鲍曼不动杆菌对消毒剂的敏感剂量,8株多重耐药鲍曼不动杆菌对部分消毒剂产生一定程度的耐药性。

The levels of gastric wall mucus, nonprotein sulfhydryls and malondialdehyde were also measured in the glandular stomach of rats following ethanol administration.

测量了乙醇造模大鼠腺胃的胃壁粘液,非蛋白巯基和丙二醛的表达水平。

Water,decyloleate,propylene glycol,stearic acid,glyceryl stearate,peg-100 stearate,iris germanica(orris extract/cells),chamomilla recutita,arctium majus,prunus dulcis,ceteareth-3, Triethanolamine,phenoxyethanol,methylparaben,imidazolidinyl urea,carbomer,c12-13 alkyl lactate,disodium edta,propylparaben,glyceryl hydroxystearate,cetyl esters,ethylparaben,pentadecalactone,cera microcristallina,trihydroxystearin,butylparaben,hydroxystearic acid,isobutylparaben,chlorhexidine digluconate,tetradecyloctadecanoic acid,tetradecyleicosanoic acid,tocopherol,lecithin,ascorbyl palmitate,glyceryl oleate,citric acid

水,油酸癸酯,丙二醇,硬脂酸,甘油硬脂酸,聚乙二醇硬脂酸酯,鸢尾花提取物/活细胞,洋甘菊萃取,牛蒡提取物,甜杏仁油,鲸蜡硬脂醇醚,三乙醇胺,苯氧乙醇,羟苯甲酯,尿素醛,卡波姆,c12-13烷醇乳酸酯,乙酸乙二胺二钠,羟苯丙酯,甘油羟基硬脂酸酯,十六烷基酯,羟苯乙酯,环十五内酯,微晶蜡,三羟基硬脂精,羟苯丁酯,羟基硬脂酸,对羟基苯甲酸异丁酯,洗必泰葡萄糖酸盐,十四烷基十八烷酸,十四烷基二十烷酸,维生素E ,卵磷脂,抗坏血酸棕榈酸酯,甘油硬脂酸,柠檬酸水:几乎所有护肤品成分第一位都是水。油酸癸酯:滋润、柔肤剂,并常添加于多种化妆品中作为溶剂

Some technologies,including olefines from methanol,oxalates and ethylene glycol from carbon monoxide,carbon dioxide-based polymers,chemicals from the syngas prepared by biomass gasification,acetone and butanol by fermentation,and chemicals from acetylene,ethanol,glycerol,furfural,hydroxymethyl furfural and starch,were reviewed.

包括甲醇制烯烃,一氧化碳制草酸酯和乙二醇,乙炔化学品,二氧化碳聚合物,生物质气化合成化工产品,发酵法生产丙酮、丁醇,乙醇衍生化工产品,甘油合成化工产品,糠醛和羟甲基糠醛合成化工产品,淀粉合成化工产品等重要的石油替代化学品生产技术被介绍。

The identity of the gene encoding the mitochondrial K-activated acetaldehyde dehydrogenase K(+-ACDH of Saccharomyces cerevisiae has been confirmed. The gene is situated on the right arm of chromosome XV, bears the systematic name YOR374w and the deduced product shows significant homology to other members of the S.

中文摘要酵母菌醛类去氢酶4(YOR374w)是一种位在粒线体内的去氢酶,需要钾离子的活化,以及NAD+或NADP+当辅酶,在乙醇的代谢途径扮演很重要的角色,尤其是以乙醇当碳源的环境下。

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