乙醇酸

The results showed that temperature rise would inhibit their esterification capacity, ethyl caproate-producing capability of raw zymin of 1# high-temperature monascus improved with the prolong of the esterification time when ethanol concentration was 4 %vol and caproic acid content was 4 mL, and when ethanol concentration and caproic acid content was within proper range, caproic acid content had more effects on the formation of ethyl caproate by raw zymin than ethanol concentration.

结果表明，温度相对升高对其酯化力的形成有一定的抑制作用；高温型红曲1#酯化菌株粗酶制剂的酯化力在乙醇浓度为4 %vol、己酸含量为4 mL时，产生己酸乙酯的能力随酯化时间的延长而增强；在适宜的乙醇浓度和己酸含量范围内，己酸含量对酯化酶粗酶制剂己酸乙酯生成影响比乙醇含量的影响大。

The results showed that hexadecanoic acid diethanolamide and Daqing crude oil has favorable compatibleness, the binary system containing hexadecanoic acid diethanolamide(with the mass concentration of 0.2%) and HPAM(with the concentration of 1000mg/L)can produce ultralow interficial tensions 8.94×10~(-3mN/m against Daqing crude oil; the three compound combination system containing hexadecanoic acid diethanolamide(with the mass concentration of 0.2%) and HPAM(with the concentration of 1000mg/L)and Na_2CO_3(0.1%)can produce ultralow interficial tensions 6.34×10~(-4mN/m against Daqing crude oil.

其中，十六酸二乙醇酰胺与大庆四厂原油具有良好的配伍性，十六酸二乙醇酰胺0.2%、HPAM1000mg/L组成的二元驱油体系与大庆四厂原油可形成超低界面张力，最低可达到8.94×10~(-3)mN/m；十六酸二乙醇酰胺0.2%、HPAM1000mg/L、Na_2CO_31%组成的三元驱油体系与大庆四厂原油间的界面张力最低可达6.34×10~(-4)mN/m。

After esterification, the ethyl-2-chloro-3-phenylpropionate reacts with diethyl malonate under the catalysis of sodium ethylate, and we obtain the corresponding triethyl ester. The-benzylsuccinic acid is formed by the triethyl ester reacting with concentrate hydrochloric acid and taking place hydrolyzation and decarboxylation reaction at the same time. In order to avoid the formation of cinnamic acid, the sodium ethylate and diethyl malonate must be react sufficiently. The course has simple operation, inexpensive materials and better yield.

具体制备工艺为：首先以L-苯丙氨酸为原料采用重氮化方法得到-2-氯-3-苯基丙酸，再经酯化得到-2-氯-3-苯基丙酸乙酯后在乙醇钠催化作用下和丙二酸二乙酯缩合，发生SN2反应，得到相应的三乙酯，然后经水解和脱羧，得到-苄基丁二酸；在实验中乙醇钠要和丙二酸二乙酯充分反应，避免生成肉桂酸乙酯；该过程操作简单，原料便宜，产率较高，总收率可达到26.8%。

The ammonia was evaporated under decreasing pressure, and the precipitate was filtered off and the liquid was poured into hot saturated picric acid solution to get picrate with a yield of 85.0%. The optimum process starting from imidazole-4,5-dicarboxylic acid was: imidazole-4,5-dicarboxylic acid in acetic anhydride was refluxed to get imidazole-4-carboxylic acid, and the product was esterification in ethanol with a catalyzer of concentrated sulfuric acid to get ethyl imidazole-4-carboxylate, at last the compound above was reduced by LiAlH4 in ether at room temperature to get the target compound, the total yield of this route was 49.6%.

以4，5-二羧酸咪唑为原料的较佳工艺：1 脱羧反应：4，5-二羧酸咪唑40g，醋酐1200ml，回流10h，过滤并将滤液浓缩至干，所得固体加至50%的乙醇溶液回流，过滤并将滤液自然冷却过夜，过滤得固体；2 酯化反应：4(5)-羧酸咪唑50g，乙醇1000ml和浓硫酸60ml，加热回流2h，5%浓度NaOH溶液调节至pH＝8，减压浓缩至干，加入少量水回流，自然冷却过夜并过滤得固体；3 还原反应：LiAlH410g，乙醚300ml和4(5)-羧酸咪唑乙酯28g，常温反应1.5h，小心滴加25ml水后过滤，滤渣溶于300ml甲醇中并过滤，收集所得乙醚和甲醇滤液浓缩至干，将所得固体溶于300ml乙醇中加热回流，后将溶液浓缩至约30ml，冷却并过滤得固体，该路线总收率为49.6%。

Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate

公司宗旨：&平等互利，信誉至上，团结合作，友谊长久&乙二胺；二乙胺；三乙胺；二乙烯三胺；三乙烯二胺；三乙烯四胺；四乙烯五胺；五乙烯六胺；己内酰胺；二甲基甲酰胺；烯丙基胺；N，N二甲基苯胺；正丙胺；正丁胺；正辛胺；三聚氰胺；1，2丙二胺；一乙醇胺；二乙醇胺；三乙醇胺；碘化钾；氢氧化钾；高锰酸钾；甲苯；二甲苯；对氯甲苯；丙酮；丁酮；乙酰丙酮；醋酸乙酯；醋酸丁酯；Y-丁内酯；碳酸二甲酯；乙酰乙酸甲酯；三伏乙酰乙酸；三伏乙酰乙酸乙酯；甲醇；无水乙醇；异丙醇；丙二醇；丙三醇；丙炔醇；1.3丙二醇；木糖醇；冰醋酸；己醛酸；巯基乙酸；异辛酸；己二酸；三氟乙酸；乙二酸；对氨基苯乙酸；邻氯苦杏仁酸；DL-扁桃酸；无水哌嗪；六无哌嗪；糠醛；蓖麻油；乙二醛；戊二醛；多聚甲醛；异丙醚；苯甲醚；四氢吡咯；纯吡啶；1.2二氯乙烷；二氯甲烷；三氯甲烷；四氯化碳；水合肼；壬基酚；纯间甲酚；硒酚；苯酚；对叔丁基苯酚；钛白粉；铁粉；全糖粉；双酚A；偶氮二异丁腈；叠氮化钠；碳酸钠；氯化钠；三氧化二铁；氯化亚铜；氯化亚砜；D4；碳酸氢钠；氨水；氯化钾；无水亚硫酸钠；过硫酸铵；乙二醇丁醚；乙二醇乙醚；氯化钙；环己酮；环己烷；甲基叔丁基醚；碳酸钾；三氯化铁；硝酸钾；磷酸三钠；氧化锌；亚硝酸钠；氧化锑；酒石酸；OP-10；TX-10；粒碱；AES；苯甲酸钠；柠檬酸钠；偏硅酸钠；过硼酸钠；过碳酸钠；苯磺酸钠；亚氯酸钠；乌洛托品；尿素；盐酸；硫酸；乳酸；氨基磺酸；双氧水；碳酸氢铵

The optimum synthetic conditions of hexadecanoic acid diethanolamide used two-step method are as follows:(1)reaction temperature was 140℃, reaction time was 4.5hours and molar ratio of hexadecanoic acid to diethanolamide was 1:1.15.(2)reaction temperature was 80℃, molar ratio of hexadecanoic acid to diethanolamide was 1:1.55 and mass concentration of the catalyst was 0.8%, reaction time was 3 hours.

二步法合成十六酸二乙醇酰胺最佳合成工艺为：(1)反应温度140℃、反应摩尔比n十六酸∶n二乙醇胺=1∶1.15、反应时间4.5h；(2)反应温度80℃、反应总摩尔比n十六酸∶n二乙醇胺=1∶1.55、催化剂用量0.8%、反应时间3h。

The invention relates to a fabric nanometer following cleaning agent for obtaining TiO2/ZnO composite hydrosol, and relative production and cleaning method, wherein it uses butyl titanate and zinc acetate as predecessor, uses glacial acetic acid as catalyst and peptizer, uses water as solvent, uses absolute ethyl alcohol as the solvent of butyl titanate, and uses ethanolamine as deposit agent and supplies OH-, to be hydrolysed and polycondensated to form TiO2/ZnO composite hydrosol. And its components and mass percents are: butyl titanate at 1-15%; zinc diethyl at 1-12%; absolute ethyl alcohol at 1-20%; glacial acetic acid at 5-15%; and aminoethyl alcohol at 0.1-5%, and the left is water. The invention has lower cost and simple process.

本发明涉及一种可以得到TiO 2 /ZnO复合水溶胶的纺织品纳米后整理试剂及其制备工艺及对织物的整理方法，以钛酸丁酯和乙酸锌为前驱物，冰乙酸为催化剂和胶溶剂，水为溶剂，无水乙醇为钛酸丁酯的溶剂，乙醇胺为沉淀剂并提供OH -，经过水解、缩聚反应形成的TiO 2 /ZnO纳米溶胶整理剂，其组分和重量百分比含量如下：钛酸丁酯占1～15％；二水乙酸锌占1～12％；无水乙醇占1％～20％；冰乙酸占5％～15％；乙醇胺占0.1％～5％；水余量，具有耐洗性、无毒、无刺激、成本低廉、制作工艺简单可靠的优点，可实现对对织物的抗紫外、抗菌、抗静电功能整理。

In order to recycle extra caustic soda and increase purity of sebacic acid, the research work in this thesis includes: extra caustic soda recovery, purification of sebacic acid and determination of solubility of sebacic acid in water, ethanol, and ethanol aqueous solution.

但是，它的传统生产工艺中存在过量游离碱浪费，癸二酸产品纯度不高等问题。对此本文做了三方面的研究，包括改进癸二酸生产工艺回收过剩的游离碱；提纯癸二酸；测定癸二酸在乙醇、水、乙醇水溶液中溶解度。

In the preparation of tungstenic acid sol, H_2O_2 and ethanol can make the sol become more stability.

在钨酸溶胶的制备中，H_2O_2、乙醇的加入能增强钨酸溶胶的稳定性，当H_2O_2与钨酸的摩尔比为1：2，乙醇与钨酸体积比为1：2时，溶胶的保存时间较长，成膜质量较好。

The invention uses the fermentation liquor of one Escherichia coli generating polysialic acid as material, filters and removes thallus, adds some solvents as sodium chloride and alcohol into supernatant to deposit polysialic acid, dissolves the polysialic acid deposits via deionized water, filters to remove modified protein, uses alkali prolease to treat filtrate, complexes deposits via cetyl pyridinium chloride or cetyltrimethylammonium bromide, and dissociates, uses over alcohol to deposit polysialic acid, dissolves the deposits via ultra-pure water, grades and purifies via chromatography column, collects and dialyzes eluent, cools and dries to obtain polysialic acid.

本发明以一株产聚唾液酸大肠杆菌的发酵液为原料，经过过滤去除菌体，上清液加入适量氯化钠和乙醇等溶剂沉淀出聚唾液酸，聚唾液酸沉淀用去离子水溶解，再用过滤去除变性蛋白质，滤液经过碱性蛋白酶处理、氯代十六烷基吡啶或十六烷基三甲基溴化铵络合沉淀并解离后，再用过量乙醇沉淀出聚唾液酸，聚唾液酸沉淀用超纯水溶解，用层析柱进行分级纯化，收集洗脱液经过透析，冷冻干燥得聚唾液酸产品。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。