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In order to research the relations of carbon sources to structure of PHAs, six kinds of PHAs sample were synthesized by activated sludge with six different carbon sources respectively in the aerobic-anaerobic-anoxic process. Their structures were determined by 〓HNMR、〓CNMR and GC-MS. When the carbon source was acetate, the unit composition of PHAs was 93. 91mol% 3-hydroxybutanoic acid and 6. 09mol% 3-hydroxypentanoic acid ; When the carbon source was propionate, the unit composition of PHAs was 28. 66mol% HB, 63. 13mol%HV, 2. 55mol% 2-methy-3-hydroxy-butanoic acid (2MHB) and 5. 66mol% 2-methyl-3-hydroxypentanoic acid (2MHV); When the carbon source was 80% butyrate and 20% 1, 4-butanediol, the unit composition of PHAs was 65. 03mol% HB, 28. 06mol%HV, 1. 91mol%2MHB, 2. 69mol% 2MHV, 0.73mol% 4-hydroxy butanoic acid (4HB), 0.78mol% 4-methyl-3-hydroxy-pentanoic acid (4MHV), 0.80mol% 3-hydroxyhexanoic acid ; When the carbon source was 20% butyrate and 80% 1, 4-butanediol, the unit composition of PHAs was 61. 39mol% HB, 23. 01mol%HV, 4. 58mol%2MHB, 5. 97mol% 2MHV, 0.91mol% 4HB, 2. 37mol% 4MHV, 1. 77mol% HHx; When the carbon source was 60% pentanoate and 40%glucose, the unit composition of PHAs was 41. 24mol% HB, 58. 76mol%HV; When the carbon source was 60% benzoate and 40% glucose, the unit composition of PHAs was 65. 48mol% HB and 34. 52mol% HV.

为了研究不同碳源与产物PHAs结构的关系,采用好氧-厌氧-缺氧模式利用6种不同碳源培养活性污泥得到6种不同的PHAs样品,通过〓HNMR、〓CNMR和GC-MS谱图确定了这6种PHAs的单体成分和比例:以乙酸钠培养活性污泥得到的PHAs的单体组成是93.91mol%3-羟基丁酸和6.09mol%3-羟基戊酸;以丙酸钠培养活性污泥得到的PHAs的单体组成除28.66mol%HB、63.13mol%HV外,另外还有2.55mol%3-羟基2-甲基丁酸(2MHB)和5.66mol%3-羟基2-甲基戊酸(2MHV);以80%丁酸钠和20%1,4-丁二醇混合溶液培养活性污泥得到的PHAs含有七种单体组成:65.03mol%HB,28.06mol%HV,1.91mol%2MHB,2.69mol%2MHV,0.73mol%4-HB(4-羟基丁酸),0.78mol%4MHV(3-羟基-4-甲基戊酸),0.80%HHx(3-羟基己酸);以20%丁酸钠和80%1,4-丁二醇培养活性污泥所得到的PHAs含有与3#样品相同的七种单体,只是比例不同,分别是61.39mol%,23.01mol%,4.58mol%,5.97mol%,0.91mol%,2.37mol%,1.77mol%;以60%戊酸钠和40%葡萄糖培养活性污泥所得到的PHAs由HB和HV组成,比例是41.24 mol%∶58.76 mol%;以60%苯甲酸钠和40%葡萄糖培养活性污泥所得到的PHAs也由HB和HV组成,比例是65.48 mol%∶34.52 mol%。

Both the and DtV$ for the glycyl dipeptides increase with increasing molality of sodium acetate. The interactions between charged center or glycyl units of the peptide and ions dominate those between alkyl groups of the peptide and the ions. The interaction between the peptides and sodium acetate is mainly pairwise. The results were interpreted successfully by the cosphere overlap model.

结果表明:甘氨酰二肽的标准偏摩尔体积和标准偏摩尔转移体积均随乙酸钠浓度的增加而增大,溶液中离子与肽带电基团/甘氨酰基团(CH2CONH)之间的相互作用大于离子与肽的非极性基团间的相互作用,乙酸钠和甘氨酰二肽之间主要是对相互作用。

The questing for acidic middle-temperature electroless Nickel technology leads to the preferable prescription as follows:Proportion of Nickel Sulphate and Sodium Hypophosphate 0.36; Sodium Acetate 15g/L; Stabilizer A lmg/L(Stabilizer B Img/L for continual experiment); Composite complexing agent Lactic Acid 10ml/L and acetic acid 10 ml/L; Accelerator organic acid G 6g/L; pH value 5.0; Loading Capacity ldm2/L; Temperature 70C (Temperature 75C for continual experiment); Proportion of supplement for Nickel Sulphate and Sodium Hypophosphate 1:1.2; Testing the consumed ion of Nickel solution and supplement inspissations solution every 60min by the proportion of 15% fresh solution.

最后,通过研究得出最佳工艺配方为:硫酸镍与次亚磷酸钠的摩尔比为0.36;乙酸钠15g/L:稳定剂Almg/L(周期实验加稳定剂B10mg/L);复合络合剂组合为乳酸10ml/L+冰乙酸10ml/L:促进剂为有机酸G6g/L;pH值为5.0;装载量为1.0dm~2/L;施镀温度为70℃(周期实验为75℃):主盐与还原剂的添加比例1:1.2;每60分钟对镀后液进行镍离子浓度的测定并按镍离子的消耗量添加浓缩液,添加比例按开缸液的15%。

In this method, EDTA was used as complexant which can form 1∶1 complex with Cr〓, this complex carried negative charge and can be detected directly by UV absorbance at 200nm, therefore, the CrO〓 and Cr〓 can be separated and determined in one run.

采用乙酸钠-乙二胺四乙酸钠-CTAB-乙酸缓冲液体系,加入EDTA使Cr〓与其生成的1∶1络合物,带负电荷且具有紫外吸收,在200nm处可用直接紫外法检测。

This paper introduced a new preparative method of sodium diacetate within one step and the mate technique of SSDA .

本文采用一步法合成双乙酸钠,介绍了增效双乙酸钠的复配工艺,同时测试其防霉效果。

Sodium diacetate,which is the molecular composite of sodium acetate and acetic acid,is a new type of multifunctional addition agent in foods and forages.

乙酸钠乙酸钠与乙酸分子的复合物,是一种新型的多功能食品及饲料添加剂。

A new technology process of sodium diacetate production with glacial acetic acid and sodium carbonate in one reactor.

研究了以冰醋酸和碳酸钠一步合成双乙酸钠的工艺和反应设备,使双乙酸钠生产工艺更为简单合理,经济易行,而且产率达 97%以

In NF animals, the food intake was significantly lower than control animals in the period of 3h and 6h after infusion of sodium propionate, in the 3h infused with low concentration sodium acetate (1M), and in all of stages infused with high concentration sodium acetate (2M).

灌注VFA盐后血浆胰岛素水平均显著性升高,丙酸钠灌注组升高的程度又显著性高于乙酸钠灌注组,在3小时时,丙酸钠灌注组胰岛素水平迅速下降到灌注前的水平,而乙酸钠灌注组胰岛素的水平却仍然保持在高于对照组的水平,但统计不显著。

Plasma glucose significantly decreased at the time of after sodium propionate infusion, no changes occurs after the sodium acetate infusion.

乙酸钠无明显影响。与灌注前相比丙酸钠灌注组的血浆IGF-1水平灌注后上升差异显著,乙酸钠灌注组显著性下降(P<0.05)。

Changes of some metabolites and hormones after jugular infusion of sodium propionate or acetate in normal feeding or fasting water buffaloes The buffaloes were infused with sodium propionate or acetate in normal feeding or 24 hours fasting status.

灌注丙酸钠,葡萄糖水平不仅不升高,反而显著性地低于灌注前和同期对照组的水平,乙酸钠灌注对血糖无影响。灌注丙酸钠或乙酸钠后血浆IGF-1水平下降,但均无显著性差异。

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