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The dependence of concentration of free sodium hydroxide,hydrolyzation ratio of sodium chloroacetate,degree of substitutionand solution viscosity of product on reaction conditions in the synthesis of polyanionic cellulosein various alcohol mediums are studied.

研究了溶剂法合成聚阴离子纤维素过程中游离碱浓度、氯乙酸钠水解率和产品取代度及其溶液粘度与反应条件的关系。

Results showed that chloroacetic acid was the best reagent for esterification and the catalyst had satisfactory catalytic activity and selectivity.

实验结果表明,氯乙酸是最佳酯化剂,催化剂具有较强的活性及选择性。

Firstly, we studied the photocatalytic hydrogen evolution and decomposition of the pollutants over Pt/TiO_2 in the presence of chloroacetic acids.

首先,我们研究了氯代乙酸存在下Pt/TiO_2上光催化生成氢的反应。

Results The infra-red spectragram of the derivate showed the chitosan had been modified by chloroacetic acid.

结果修饰后的衍生物经红外图谱分析表明,壳聚糖已被氯乙酸所修饰。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先,以巴豆醛与乙硫醇为原料,在三乙胺的催化作用下高收率制得3-乙硫基丁醛;然后从乙酰乙酸甲酯出发,通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮,接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环,再通过皂化和脱羧反应生成中间体5-[2-丙基]-1,3-环己二酮;再与丙酸酐反应丙酰化,最后与0-3-氯-2-丙烯基羟胺肟化,得到目标化合物烯草酮。

The basic functionalized ionic liquid, 1 -butyl-3-methylimidazolium hydroxide OH, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基-3-甲基咪唑,研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

The basic functionalized ionic liquid, 1-butyl-3-methylimidazolium hydroxide, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基-3-甲基咪唑,研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

Knoevenagel condensation reaction between aromatic aldehyde, malononitrile or ethyl cyanoacetate is promoted by organocatalyst N-methylimidazole.

以1-甲基咪唑为有机小分子催化剂催化芳香醛与丙二腈或氰乙酸乙酯的Knoevenagel缩合反应,反应速度快,操作方便,产率高,后处理简单。

This paper is about the study of catalyst used in the dehydrogenation from diethanolamine to Iminodiacetic salt.

本课题围绕二乙醇胺催化脱氢生成亚氨基二乙酸盐所用的催化剂展开研究。

Methods: In alkaline condition, reaction between amino acids and phenylisothiocyanate formed a derivant of phenylisothiocyanate-amino acid. For RP-HPLC, the Diamonsil C18 column 250 mm×4.6 mm,5 μm) and binary gradient elution were used. The mobile phase A was 0.1 mol/L sodium acetate solution-acetonitrile (93∶7) and the mobile phase B was acetonitrile-water(80∶20). The detecting wavelength was 254 nm.

在碱性条件下,氨基酸与异硫氰酸苯酯反应,生成异硫氰酸苯–氨基酸的衍生物,采用 Diamonsil C18色谱柱(250 mm×4.6 mm,5 μm),用二元梯度洗脱方式,流动相A为0.1 mol/L乙酸钠–乙腈(93∶7),流动相B为乙腈–水(80∶20),检测波长254 nm。

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