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Formyl-3-acetyl-4-methyl-5-carbobenzoxypyrrole (6) was synthesized via the selective oxidation of 2,4-dimethyl-3-acetyl-5-carbobenzoxypyrrole (5), which was produced from acetylacetic benzylester (1) via nitrosation, reduction and addition-cyclization with acetylacetone. The total yield of the product was about 34%.

以乙酰乙酸苄酯(1)为原料,经过亚硝化、还原、与乙酰丙酮加成环化生成2, 4-二甲基-3-乙酰基-5-苄氧羰基吡咯(5),通过选择性氧化反应制得目标化合物2-甲酰基-3-乙酰基-4-甲基-5-苄氧羰基吡咯(6),反应的总收率约为34%。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺;NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢;NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

Seven compounds have been isolated from hard coral Acropora pulchra. These compounds are:pentadecoic acid, heptadecyl ester;(2)n-cetanol;(3)batyl alcohol;(4) N- [ 1 --2-hydroxyl--3,7-heptad-ecadienal] -hexadecanamide;(5)1 -0-hexanoyl-glycerol ester;(6)thymine;(7)uracil. Their structures were determined by IR, MS, HNMR, 13CNMR analysis.

从北海佳丽鹿角珊瑚Acropora pulchra乙醇提取液的乙酸乙酯部分分离出七个化合物,经IR、MS、~1HNMR、~(13)CNMR等波谱方法鉴定,其结构分别为:(1)十五酸十七酯,(2)正十六碳醇,(3)鲨肝醇,(4)N-1-羟基甲基-2-羟基—-3,7-十七碳二烯基十六酸酰胺,(5)1-正十六酸甘油酯,(6)胸腺嘧啶,(7)尿嘧啶。

The results show that the ethyl acetate extract of Alpinia oxyphylla Miquel possesses strongest DPPH radical scavenging activity and reducing power in a concentration-dependent manner.

在还原能力、清除DPPH自由基和羟自由基方面,乙酸乙酯提取物表现出了很强的抗氧化能力,呈现剂量依赖关系。

This property of the polymer particles was used to assay aminoacetic acid.

利用聚合物颗粒的这一性质测定氨基乙酸。

The Antioxidization of ascorbic acid ,malic acid,tartaric acid,citric acid,p bromomandelic acid,aminoacetic acid and nitrilotriacetic acid for lard was studied.

研究了抗坏血酸、苹果酸、酒石酸、柠檬酸、对溴苦杏仁酸、氨基乙酸、氨三酸等七种有机酸对猪油的抗氧化作用。

3 Effects of zinc levels on endogenous hormone and nitrogen metabolism in leaves of balsam pear The results showed that zinc application could increase IAA, GA〓, protein, nuclear contents and NRase activity, but decrease tryptophane, nitric nitrogen , free ammonic acids contents and RNase activity in leaves of plants.

1.3 锌对苦瓜叶片内源激素与氮代谢的影响结果表明:施锌可提高叶片吲哚乙酸、赤霉素、蛋白质、核酸含量以及硝酸还原酶活性;降低色氨酸、游离氨基酸和NO〓含量以及RNase活性。

This paper discusses the properties of Sodium Diacetate,a new antifungin,and its inhibition acting on normal mould.

研究了新型防霉剂双乙酸钠对常见霉菌的抑菌作用。

Objective: To observe the effect of Weixikang apozema on growth factor of acetic acid gastric ulcer rats.

目的:观察胃喜康煎剂对乙酸致胃溃疡大鼠细胞生长因子的影响。

Using levulinic acid and phenol as raw materials, hydrochloric acid as catalyst and thioglycolic acid as assistant catalyst, the synthesis technology of diphenolic acid, a new polymer material substitution for biphenol A, was investigated.

研究了以苯酚和新型平台化合物乙酰丙酸为原料,采用盐酸为催化剂、巯基乙酸为助催化剂催化合成高分子材料单体双酚酸的合成工艺。

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