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Absorbent cotton fibers were dissolved in trifluoroacetic acid,and then precipitated in the chitosan solution.

以三氟乙酸在无水条件下溶解脱脂棉纤维,在壳聚糖的醋酸溶液中析出。

Whole series of organic compounds, among them acetaldehyde, acetic acid, and acetic

对于整个系列的有机化合物,包括乙醛、乙酸

Two compounds were isolated from ethyl acetate extract of the fermentation of fungus 07-11,which obtained from the soil of Yunnan Province. They were identified as N-(4-hydroxy-2-methoxyphenyl)acetamide (1) and ergosta-7,22-diene-3,6-dione (2) respectively on the basis of spectral analyses and physical and chemical identifications.

从云南土壤真菌07-11号菌株的发酵液乙酸乙酯萃取物中分离得到2个化合物,通过理化鉴别和光谱测定,鉴定两化合物分别为N-(4-羟基-2-甲氧苯基)乙酰胺(1)和麦角甾7,22-二烯-3,6-二酮(2)。

Methods Protein in blood and urine was precipitated directly by acetonitrile with acetanilide was used as the internal standard using Agilent Zorbax SB-Aq column (250 mm×4.6 mm, 5 μm). The mixed solvents of water (triethylamine 0.12%, acetic acid 0.12%) and acetonitrile were used as the mobile phase to separate cephalosporins using gradient elution method at 1 mL/min and 254 nm.

以乙酰苯胺为内标,血液和尿液用乙腈直接沉淀蛋白,采用Agilent Zorbax SB-Aq(250 mm×4.6 mm, 5 μm)色谱柱,流动相选用水(含0.12%三乙胺和0.12%乙酸)和乙腈的混合溶剂梯度洗脱,流速1 mL/min,检测波长254 nm。

It was found that ethyl acetate was the optimal organic solvent.

结果表明,乙酸乙酯是最理想的有机溶剂。

The antimicrobial test and researched was done on wide distillation of different solvents on Terpenoid, polarity separation of ethanol distillable substance, thin layer chromatography of different polarities and distillation of amylase. The results showed that the active substance distilled by 95% ethanol and V methanol: toluene=3:1 had stronger antimicrobial activity on Agaricus blazei Murrill. The antimicrobial activity of ethyl acetate was stronger than wide distilling substance with ethanol, but the water part has not antimicrobial effect. Two straps of ethyl acetate phase(Rf0.57、Rf0.63)(0.1g/ml)had stronger antimicrobial activity on Agaricus blazei Murrill, the antimicrobial zone on Pseudomonas was 19.3mm. The bacteriostatic activity of chromatography strap of water phase was rather weaker, the water solution (0.5g/g) of amylase had better effect on pathogenic fungus of Agaricus blazei Murrill, its antimicrobial zone on Aspergillus niger, Citrinin, Trichoderma viride were 10.8 mm, 7.9 mm, 5.3 mm.

通过对日本凹顶藻以不同溶剂的粗提、乙醇提取物的极性分离、不同极性的薄层层析和多糖的提取,进行抗菌试验的研究,发现95%乙醇和V甲醇:甲苯为3∶1的提取的活性物质具有较强的抗姬松茸的病原细菌活性,乙酸乙酯相对病原细菌的抑菌强于乙醇的粗提物,而水相基本无抑菌效果,乙酸乙酯相的两个带(Rf0.57、Rf0.63)浓度为0.1g/ml具有较强抗姬松茸病原细菌的活性,对假单孢杆菌抑菌圈达到19.3mm,水相层析带的抑菌活性较弱,多糖的粗提物配成0.25g/g的水溶液对姬松茸病原真菌有较好的抑菌效果对黑曲霉、桔青霉和绿色木霉的抑菌圈分别达到10.8 mm、7.9 mm、5.3 mm。

The decisive influencing factor of viscosity in carboxyl-methylation was cross-linking reaction. Carboxyl-methylation was the main influencing factor of solubility and swelling capacity in modification of high content amylose starch. The structure and gelatinization property of different amylose content were analyzed with an Olympus Vanox BHS-2 multi-function optic microscope, and the results were as follows. The structure of ordinary cornstarch was different from the high amylose; gelatinization temperature and pH value of starch were affected deeply by amylose content, but had little difference between the gelatinization of high content amylose starch contained 50% and 70% amylose; pH value had much more effect than temperature on the gelatinization of high content amylose cross-linked starch. Monochloroacetic acid consumption, alcohol concentration and pH value influenced the starch carboxyl-methylation. When alcohol concentration was 60%, pH value 10, monochloroacetic acid/starch mass ratio 55%, the carboxyl-methylation of high amylose cross-linked cornstarch had the best result. With the In-Vitro digestibility model and biodegradation experiment, the digestibility and biodegradability of high amylose cornstarch and its modified starch were detected.

采用Brabande粘度测定仪和Olympus Vanox BHS-2型多功能光学显微镜等分析手段对链淀粉含量50%和70%的高链玉米淀粉及其交联和交联羧甲基化淀粉的结构和性质进行了表征和分析,结果表明,普通玉米淀粉结构与含链淀粉50%和70%高链玉米淀粉结构不同;高链淀粉比普通淀粉难糊化,高链改性淀粉糊化受pH值影响较大,受温度影响较小;淀粉的冻融稳定性、透光率、溶解度、膨胀度和粘度受链淀粉的含量和改性的影响,但是,链淀粉含量超过50%时,则链淀粉含量对淀粉的膨胀度和溶解度影响不大;改性淀粉性质的影响因素中,影响粘度主要因素是交联反应,影响透明度、溶解度和膨胀度主要因素是羧甲基化改性;一氯乙酸用量、反应时乙醇浓度及碱性条件都会影响高链淀粉及其交联淀粉的羧甲基化改性效果,制备羧甲基化改性淀粉的最佳工艺是在pH值为10的60%的乙醇浓度介质中按一氯乙酸/淀粉质量比为55%进行取代反应。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethyl malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effective base.

在这类催化反应中,碱的选择具有重要的影响:以K3PO4为碱, Pd2/L1催化体系在丙二酸二乙酯的α-芳基化中,富电子溴代芳烃显示较好的活性; Pd2/L1催化的乙酰乙酸乙酯α-芳基化时,以 K2CO3为碱,催化体系显示较好的活性,这个催化体系可控制反应得到α-芳基乙酰乙酸乙酯,而不是脱乙酰基的产物。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethy malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effectiv base.

在这类催化反应中,碱的选择具有重要的影响:以K3PO4为碱,Pd2/L1催化体系在丙二酸二乙酯的α-芳基化中,富电子溴代芳烃显示较好的活性;Pd2/L1催化的乙酰乙酸乙酯α-芳基化时,以K2CO3为碱,催化体系显示较好的活性,这个催化体系可控制反应得到α-芳基乙酰乙酸乙酯,而不是脱乙酰基的产物。

An agent for a protective film which comprises a liquid mixture of a urethane type compound, methyl ethyl ketone and ethyl acetate and a curing rate enhancing agent comprising an isocyanate type compound and ethyl acetate; and a method for forming a protective film which comprises applying the agent for a protective film on the outer surface of a mold (9) or on the region of the outer surface of the mold (9) except a specific portion as an article to be coated.

本发明提供了一种保护膜制剂和形成保护膜的方法,其中所述保护膜制剂含有聚氨酯型化合物、甲基乙基酮和乙酸乙酯的液体混合物与含有异氰酸酯型化合物和乙酸乙酯的固化增速剂;所述形成保护膜的方法包括将保护膜制剂涂布于模具(9)的外表面或涂布于模具(9)的外表面除了作为待涂布制品的特定部分以外的区域。

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