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The route include three steps: etherification, ammoniation and then oxidation. Factors such as chloracetate, reaction temperature on process were studied. And discussed the ionic liquid was recovered.

讨论了不同的氯乙酸酯和反应温度对醚化反应收率的影响,讨论了不同的二苯甲硫乙酸酯对氨解反应收率的影响,及离子液体的回收使用。

The relationship between glycosidic precursors and its aroma components was studied. The results showed: The dominant aroma constituents in aroma oil of jasmine tea include benzyl acetate, linalool, methyl antyranilate, cis-3-hexenyl benzoate, benzyl alcohol, indole, farnisene, methyl benzoate, methyl salicylate, geraniol, cis-3-hexenyl-acetate etc.; and the higher the concentration of these components is, the higher the quality of jasmine tea is.

结果表明:茉莉花茶香精油中,含量较高的有乙酸苄酯、芳樟醇、邻氨基苯甲酸甲酯、苯甲酸顺-3-己烯酯、苯甲醇、吲哚、法尼烯、苯甲酸甲酯、顺-3-己烯酯、水杨酸甲酯、橙花叔醇、乙酸顺-3-己烯酯、香叶醇;这些成分的含量随花茶品质的提高而增多;研究表明,花茶的高含量香气成分也是茉莉花中的主要赋香成分。

Reductive conversion of geraniol to citronellol is adopted as a model reaction, and several factors in the reaction are discussed using gas chromatography method. The influence of n-hexane and butyl acetate, as organic solvents, on biocompatibility was studied; the influence of methanol, ethanol, glycol, n-butanol and 1-hexanol, as energy substance, on the transformation efficiency was compared, respectively; the catalysis capabilities of Baker's yeast, XST-KO yeast, LP yeast, alcohol yeast, dry yeast, Saccharomyces cerevisiae, Angel yeast and Meishan yeast were discussed. It has been proved that biocompatibility of n-hexane are much better than that of butyl acetate, and the hexane has been demonstrated the most effective in terms of the influence on biotransformation, Baker's yeast has shown the highest tranformation efficiency among the eight yeast strains.

以香叶醇转化为香茅醇作为模型反应,通过气相色谱法进行定性和定量分析研究了影响该有机相生物转化反应的几个基本因素,考察了两种有机溶剂正己烷和乙酸丁酯对生物相容性的影响,选用甲醇、乙醇、乙二醇、正丁醇和l-己醇分别作为能量物质进行实验,比较其对转化的影响并探讨了Baker's酵母、XST-KO酵母、LP酵母、酒精酵母、假丝酵母、干酵母、安琪酵母和梅山酵母八种不同酵母作为生物催化剂对模型反应的催化能力,结果表明,正己烷作为有机溶剂,其生物相容性明显好于乙酸丁酯,更加有利于该生物转化反应进行;乙二醇作为能量物质,该模型反应转化率最高;而 Baker's酵母作为生物催化剂,对该模型反应的催化能力最强,最适合作为该模型反应的催化剂。

Propagules and buds of Elodea nuttallii and Potamogeton crispus were exposed to acetic acid concentrations from 1 to 16 mmol/L for 3 or 6 days, and then they were subsequently cultured in absence of acetic acid. Results showed P. crispus was more tolerant to acetic acid than E. nuttallii. At acetic acid concentration of 1 mmol/L, E.

研究了暴露于不同浓度的乙酸溶液后伊乐藻和菹草无性繁殖体的萌发和幼芽的生长状况。1mmol/L的乙酸能显著抑制伊乐藻幼芽的生长(P.05),但对其繁殖体的萌发无明显影响。

Both the and DtV$ for the glycyl dipeptides increase with increasing molality of sodium acetate. The interactions between charged center or glycyl units of the peptide and ions dominate those between alkyl groups of the peptide and the ions. The interaction between the peptides and sodium acetate is mainly pairwise. The results were interpreted successfully by the cosphere overlap model.

结果表明:甘氨酰二肽的标准偏摩尔体积和标准偏摩尔转移体积均随乙酸钠浓度的增加而增大,溶液中离子与肽带电基团/甘氨酰基团(CH2CONH)之间的相互作用大于离子与肽的非极性基团间的相互作用,乙酸钠和甘氨酰二肽之间主要是对相互作用。

The questing for acidic middle-temperature electroless Nickel technology leads to the preferable prescription as follows:Proportion of Nickel Sulphate and Sodium Hypophosphate 0.36; Sodium Acetate 15g/L; Stabilizer A lmg/L(Stabilizer B Img/L for continual experiment); Composite complexing agent Lactic Acid 10ml/L and acetic acid 10 ml/L; Accelerator organic acid G 6g/L; pH value 5.0; Loading Capacity ldm2/L; Temperature 70C (Temperature 75C for continual experiment); Proportion of supplement for Nickel Sulphate and Sodium Hypophosphate 1:1.2; Testing the consumed ion of Nickel solution and supplement inspissations solution every 60min by the proportion of 15% fresh solution.

最后,通过研究得出最佳工艺配方为:硫酸镍与次亚磷酸钠的摩尔比为0.36;乙酸钠15g/L:稳定剂Almg/L(周期实验加稳定剂B10mg/L);复合络合剂组合为乳酸10ml/L+冰乙酸10ml/L:促进剂为有机酸G6g/L;pH值为5.0;装载量为1.0dm~2/L;施镀温度为70℃(周期实验为75℃):主盐与还原剂的添加比例1:1.2;每60分钟对镀后液进行镍离子浓度的测定并按镍离子的消耗量添加浓缩液,添加比例按开缸液的15%。

The experimental results showed that in the acid condition the polymerization rate decreased in acetic acid media, and the contents of species Sia and Sib were increased.

实验表明:在酸性氛围下,当有乙酸化合物存在时,聚硅酸溶液中的硅酸组分与钼酸反应的速率总是要比不含乙酸时的大得多;溶液中存在的Sia和Sib形态均表现出不同程度的增加。

It demonstrated that the hydroxy organic acids substituted with-OH,-SH at α—C such as lactic acid, Hydroxy-acetic acid, mercapto-acetic acid, glyconic acid have good selectivity for separation of hematite and aegirine pka values of organic acids fall down because of the-I inductive effect of-OH or-SH, and lie at the pH range between two minerals point-zero-charge. As a result, the depression ability of them was enhanced, and a cyclo-pentyl chelate was formed when this organic acids acted with Fe〓 on the minerals surface.

发现在α位具有-OH、-SH等取代基的短链一元羧酸(乳酸、羟基乙酸、巯基乙酸,葡萄糖酸)对赤铁矿与钠辉石的浮选分离具有优良的选择性抑制作用,-OH、-SH的-I诱导效应导致有机酸的pKa值下降并落在两种矿物零电点之间,使其抑制性能增强,并与矿物表面的Fe〓形成稳定的五元螯合环。

In this paper the study on optimizing the esterification of cellulose and some character of CAB(the degree of substitution of cellulose, solubility, the thermal properties and molecular weight) was discussed. The mechanism of the esterification of cellulose in butyric acid/ acetic acid/ butyric anhydride which comprises the creation of the acetic butyric anhydride, acetyl cation and butyryl cation was investigated by the study of the effect of the content of the organic acid and anhydride on the degree of acetyl and butyryl substitution of cellulose.

最后本文根据纤维素在丁酸/乙酸/丁酸酐中的酯化反应中有机酸以及酸酐的添加量对最后产物纤维素醋酸丁酸酯中乙酯或者丁酯取代度的影响,提出纤维素在丁酸/乙酸/丁酸酐中的酯化反应经历一个混和酸酐以及乙酰碳正离子、丁酰碳正离子的生成过程。

In NF animals, the food intake was significantly lower than control animals in the period of 3h and 6h after infusion of sodium propionate, in the 3h infused with low concentration sodium acetate (1M), and in all of stages infused with high concentration sodium acetate (2M).

灌注VFA盐后血浆胰岛素水平均显著性升高,丙酸钠灌注组升高的程度又显著性高于乙酸钠灌注组,在3小时时,丙酸钠灌注组胰岛素水平迅速下降到灌注前的水平,而乙酸钠灌注组胰岛素的水平却仍然保持在高于对照组的水平,但统计不显著。

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