乙酸戊酯

Given the current complexity of industrial recovery of 3'-methyl-2'-butenyl 3, 3-dimethyl-pentenoate and the decomposition problems with 2-methyl-1-butene, research was conducted on a process for direct recycling of MBDP involving an ester exchange reaction of MBDP with either methanol, trimethyl orthoacetate, or solutions of methanol and trimethyl orthoacetate.

针对目前工业上回收3，3-二甲基－4-戊烯酸－3'-甲基－2'-丁烯酯工艺复杂、异戊烯大量分解问题，研究了MBDP直接返回循环使用工艺，MBDP与甲醇、原乙酸三甲酯或与甲醇原乙酸三甲酯混合溶液进行酯交换反应的回收新工艺，比较了四异丙基钛酸酯、甲醇钠、氢氧化钾用作酯交换催化剂的效果，筛选出回收MBDP&一锅煮&最佳工艺：按照n：n：n：n＝1.0：9.8：9.2：0.05物质的量比投料，74℃~78℃反应21h，MBDP转化为贲亭酸甲酯和异戊烯醇，单程转化率87.7%，用85%的磷酸中和甲醇钠，蒸出甲醇，直接用于合成贲亭酸甲酯。

Pentaerythrityl tetraacetate was synthesized from acetic acid and pentaerythrite, catalyzed by SO(superscript 2- subscript 4)/TiO2-La2O3 rare-earth solid superacid. Various factors affecting the reaction were discussed.

以稀土固体超强酸SO(上标 2-下标 4)/TiO2-La2O3为催化剂，乙酸和季戊四醇为原料合成季戊四醇四乙酸酯，并考察了影响反应的因素。

This reflected that EMP and HMP pathways and the tricarboxylic acid cycle were very important to the bioreduction.

表明糖酵解途径、磷酸戊糖途径和三羧酸循环的顺利进行对于面包酵母在有机介质中催化4-氯乙酰乙酸乙酯还原反应都是十分重要的。

The company mainly produces cinnamaldehyde, cinnamic acid, cinnamic alcohol, cinnamic nitriles,-bromo-cinnamic aldehyde, amyl cinnamic aldehyde, acetic acid Gui ester, cinnamic acid acetate, L-carnitine, coumarin , vitamin B1 and so on, one of cinnamon products only amounted to more than 100 kinds of quality and technical content are up to domestic advanced level, is expected to reach an annual output value of 10 billion yuan.

公司主要生产肉桂醛、肉桂酸、肉桂醇、肉桂腈、α-溴代肉桂醛、戊基肉桂醛、乙酸桂酯、肉桂酸乙脂、左旋肉碱、香豆素、维生素B1等，其中仅肉桂系列产品就达100多种，其质量及技术含量均达到国内先进水平，预计年产值可达10亿元人民币。

The company mainly produces benzaldehyde, cinnamic aldehyde, cinnamic acid, cinnamic alcohol, cinnamic nitriles,-bromo-cinnamic aldehyde, amyl cinnamic aldehyde, acetic acid Gui ester, cinnamic acid acetate, L-carnitine, coumarin, vitamin B1, etc., of which only cinnamon series reached more than 100 kinds of products, its quality and technical content are up to domestic advanced level, is expected to reach an annual output value of 10 billion yuan.

公司主要生产苯甲醛、肉桂醛、肉桂酸、肉桂醇、肉桂腈、α-溴代肉桂醛、戊基肉桂醛、乙酸桂酯、肉桂酸乙脂、左旋肉碱、香豆素、维生素B1等，其中仅肉桂系列产品就达100多种，其质量及技术含量均达到国内先进水平，预计年产值可达10亿元人民币。

Insertion of ethylacetate or DMF into 1-zircona-2-azacyclopent-3-ene complexes at 50 oC affords pyrroles in moderate yield when they quenched with KOH aqueous.

1-锆-2-氮-环戊-3-烯错合物在室温下可与乙酸乙酯或DMF进行插入反应，经由氢氧化钠水溶液水解后，可得到不错产率的比咯。

Solid superacid ; isoamyl acetate ; catalytic synthesis ; kinetic ; activation energy

固体超强酸；乙酸异戊酯；催化合成；动力学；活化能

The amphiphilic TMS-HZSM-5 and TMS-Hβ zeolites exhibited catalytic activity for hydrolysis of isoamyl acetate obviously superior to their parent zeolites.

两亲性TMS-HZSM-5和TMS-Hβ沸石在乙酸异戊酯相界面水解反应中表现出明显优于各自母体沸石的催化性能。

In the phase-boundary reactions of cyclohexene hydration and isoamyl acetate hydrolysis, these amphiphilic zeolite particles are oriented at the aqueous-organic phase boundary and exhibit catalytic activity obviously superior to the parent zeolites.

在环己烯水合及乙酸异戊酯水解的相界面反应中，两亲性沸石分布於水－油两相界面，并表现出明显高於各自母体沸石的催化活性。

Based on the reactive distillation technology, the as-prepared nanostructured manganese oxides are also used to catalyze the esterification reaction between acetic acid and isoamyl alcohol to synthesize isoamyl acetate.

动力学研究表明本实验的催化氧化反应遵循动力学规律r(来源：ABC70a8论文网www.abclunwen.com)_A=333.3×c_A~(1.76)。以所制备的纳米结构锰氧化物为催化剂，采用反应蒸馏技术进行了乙酸异戊酯的合成研究。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。