乙酸异戊酯

Eight kinds of solid acid catalysts for esterification of acetic acid and isopentyl alcohol are studied in this paper.

本文研究了8种固体酸催化剂催化乙酸与异戊醇的酯化反应，结果表明：FeCl3。

Mainly engaged in: Hydrogen-imide hydrochloride, o-chlorophenyl cyclopentanone, 3.4 dimethoxy ethyl benzene, butyn single potassium acid, potassium ethyl malonyl, Ding amide, amide isobutyraldehyde , allyl chloroacetate, isopropyl chloroacetate Benzyl aluminum, cyclopentene, cyanide-o-chlorophenyl, o-methyl chloride, sulfuric acid chloride, p-chlorophenol, imidazole, Pinacolone, one chlorine Pinacolone.

主要经营：盐酸氢亚胺、邻氯苯基环戊酮、3.4二甲氧基苯乙酯、丁炔二酸单钾盐、丙二酸单乙酯钾盐、丁酰胺、异丁酰胺、氯乙酸烯丙酯、氯乙酸苄酯异丙醇铝、环戊烯、邻氯苯氰、邻氯苯甲酯氯、硫酸氯、对氯苯酚、咪唑、频呐酮、一氯频呐酮。

Based on the analysis of the chromatogram of flavoring compositions of Taishan Tequ, 13 kinds of flavoring compositions including n-propanol, isoamyl alcohol, ethyl caproate, ethyl lactate, ethyl acetate, ethyl butyrate, caproic acid, acetic acid, butyric acid, acetaldehyde, acetal, total acids and total esters were determined as the chromatogram skeleton compositions of Taishan Tequ. The physiochemical indexes of Taishan Tequ could be under proper control through the stipulation of the content range of the above flavoring compositions, which is an effective way to liquor quality improvement and stability and has greatly improved the blending techniques of Taishan Tequ.

以泰山特曲酒香气成分色谱分析结果为基础，确定了正丙醇、异戊醇、己酸乙酯、乳酸乙酯、乙酸乙酯、丁酸乙酯、己酸、乙酸、丁酸、乙醛、乙缩醛、总酸、总酯这13种香味成分作为泰山特曲的色谱骨架成分来控制成品酒理化指标，并制订了控制范围，使泰山特曲的勾兑技术有了飞跃的发展，成为提高与稳定产品质量的有效方法。

Major procurement of goods: a three-chlorosilanes, dichloromethane, AE activity ester, 3-iodine Silane, special acid, pentyl chloride, triethylamine, thiadiazole, tetrazolylazo acid, 2 - Acetamide, tetrahydrofuran, the four-guanidine, isopropanol, five phosphorus trichloride, sodium vary bitter, acid, sodium phenylacetate, 6-2 silicon n-amine, Ethylacetoacetate , Methyl isobutyl ketone, potassium dihydrogen phosphate, aluminium oxide, DL methionine, N, N-dimethylaniline, NN-diethyl aniline, 4 sodium EDTA, Anhydrous sodium sulfate, ammonium sulfate, potassium sulfate, sodium acetate, sodium carbonate, DMC, formic acid, sodium chloride medicinal, oxalate, protopine, acetone, alcohol, acetic acid, vinegar Ethyl, butyl acetate, methanol, ethanol (anhydrous, industrial, medicinal), formaldehyde, Ye Jian (30%), hydrochloride (industrial-grade, refined grade, reagent level), sulfate (98%), Ammonia, calcium carbonate, chlorine dioxide, 6 - APA ,7-ACA ,7-ADCA ,7-ANCA, sulbactam, ceftazidime activity ester, Deng salt (hydroxymethyl-K, acid precursors Potassium, sodium dihydrogen methyl), resin, the enzyme, water treatment agent, Xiao Mo agent, demulsifier, flocculants, activated carbon, all kinds of medicinal materials, All kinds of additives

三甲基一氯硅烷、二氯甲烷、AE活性酯、三甲基碘硅烷、特戊酸、特戊酰氯、三乙胺、噻二唑、四氮唑乙酸、二甲基乙酰胺、四氢呋喃、四甲基胍、异丙醇、五氯化磷、异辛酸钠、苯乙酸、苯乙酸钠、六甲基二硅胺烷、乙酰乙酸乙酯、甲基异丁酮、磷酸二氢钾、三氧化二铝、DL蛋氨酸、N，N-二甲基苯胺、NN-二乙基苯胺、乙二胺四乙酸四钠、无水硫酸钠、硫酸铵、硫酸钾、醋酸钠、碳酸钠、碳酸二甲酯、甲酸、药用氯化钠、草酸、片碱、丙酮、正丁醇、冰醋酸、醋酸乙酯、醋酸丁酯、甲醇、乙醇、甲醛、液碱（30％）、盐酸（工业级、精制级、试剂级）、硫酸（98％）、氨水、碳酸钙、二氧化氯、6－APA、7－ACA、7－ADCA 、7－ANCA、舒巴坦、头孢他啶活性酯、邓盐(羟甲基钾、前体酸钾、二氢甲基钠)、树脂、生物酶、水处理剂、消沫剂、破乳剂、絮凝剂、活性碳、各种药用辅料、各种添加剂

The results showed that there were 8 kinds of aliphatic, 5 kinds of esters, 2 kinds of aldehydes, 2 kinds of nitrogen sulfur heterocyclic rings and one kind of hydrocarbon, alcoholics, ketone, lactones respectively in the analyzed 21 kinds of aroma components, and the content of furfural,β-methyl valeric acid, palmitic acid, nicotine, neohytadiene were higher, next were acetyl ethyl propionate, caleric acid, phenyl ethyl acetate, hydroxylic diethyl succinate.

结果表明，在分析出的21种香气成分中，分别有脂肪酸类8种，酯类5种，醛类2种，氮硫杂环类2种，烃类、醇类、酮类、内酯类各l种，其中相对含量较高的物质成分是糠醛、β-甲基戊酸、十六碳酸、烟碱、新植二烯，其次是乙酰丙酸乙酯、异戊酸、苯乙酸乙酯、羟基丁二酸二乙酯等。

Given the current complexity of industrial recovery of 3'-methyl-2'-butenyl 3, 3-dimethyl-pentenoate and the decomposition problems with 2-methyl-1-butene, research was conducted on a process for direct recycling of MBDP involving an ester exchange reaction of MBDP with either methanol, trimethyl orthoacetate, or solutions of methanol and trimethyl orthoacetate.

针对目前工业上回收3，3-二甲基－4-戊烯酸－3'-甲基－2'-丁烯酯工艺复杂、异戊烯大量分解问题，研究了MBDP直接返回循环使用工艺，MBDP与甲醇、原乙酸三甲酯或与甲醇原乙酸三甲酯混合溶液进行酯交换反应的回收新工艺，比较了四异丙基钛酸酯、甲醇钠、氢氧化钾用作酯交换催化剂的效果，筛选出回收MBDP&一锅煮&最佳工艺：按照n：n：n：n＝1.0：9.8：9.2：0.05物质的量比投料，74℃~78℃反应21h，MBDP转化为贲亭酸甲酯和异戊烯醇，单程转化率87.7%，用85%的磷酸中和甲醇钠，蒸出甲醇，直接用于合成贲亭酸甲酯。

Isoamyl chloroacetate is synthesized from chloroacetic acid and isoamyl alcohol with mordenite as catalyst and benzene as water carrying agent under the irradiation of microwave.

研究了微波辐射作用下丝光沸石催化氯乙酸与异戊醇的酯化反应。

In four flavor models, isoamyl alcohol model and ethyl acetate model have good capacity for simulation and prediction, whereas acetaldehyde model and diacetyl model do not.

在建立的4个风味物质模型中，异戊醇和乙酸乙酯模型的仿真能力和预测能力都比较强，双乙酰和乙醛模型的仿真能力和预测能力都比较差，需要进一步研究。

In the phase-boundary reactions of cyclohexene hydration and isoamyl acetate hydrolysis, these amphiphilic zeolite particles are oriented at the aqueous-organic phase boundary and exhibit catalytic activity obviously superior to the parent zeolites.

在环己烯水合及乙酸异戊酯水解的相界面反应中，两亲性沸石分布於水－油两相界面，并表现出明显高於各自母体沸石的催化活性。

Based on the reactive distillation technology, the as-prepared nanostructured manganese oxides are also used to catalyze the esterification reaction between acetic acid and isoamyl alcohol to synthesize isoamyl acetate.

动力学研究表明本实验的催化氧化反应遵循动力学规律r(来源：ABC70a8论文网www.abclunwen.com)_A=333.3×c_A~(1.76)。以所制备的纳米结构锰氧化物为催化剂，采用反应蒸馏技术进行了乙酸异戊酯的合成研究。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。