乙酸基

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

Reduction of 2-bromodifluoromethyl substituted propargyl vinyl ether afforded the difluorovinyl propargyl ether, which rearranged to the corresponding allene bearing a gem-difluoromethene in the mid-aliphatic chain.

第三部分，在碱性条件下，α-氟烷基乙酸乙酯与炔丙醇反应制备了一系列的氟烷基取代的炔丙基烯基醚，并研究了它的Claisen重排反应，得到了2，4-不饱和的氟烷基酮。

The results show that the ethyl acetate extract of Alpinia oxyphylla Miquel possesses strongest DPPH radical scavenging activity and reducing power in a concentration-dependent manner.

在还原能力、清除DPPH自由基和羟自由基方面，乙酸乙酯提取物表现出了很强的抗氧化能力，呈现剂量依赖关系。

The studies are significant to propose the synthetic methodology of benzothiazole derivatives,broaden the application of the metal complexes of benzothiazoles.It is practical value of the research in preparation of phenylacetic acid from metal-catalyized carbonylation.The thesis consists of four chapters.

本论文研究了苯并噻唑衍生物及其钴、铑金属配合物的合成，并研究了两类金属配合物的羰基化催化性能，提供了合成苯并噻唑衍生物的可行路线，拓宽了苯并噻唑金属配合物的应用范围，催化羰基化合成苯乙酸的研究具有重要的实用价值。

The main results are as the following: 1. Different reagents are used to modify the 568nm-emission QDs and there influences on the optical qualities of QDs are discussed. A good method of modification by which the excellent optical qualities of QDs are kept is found. 2. The water-soluble QDs were linked to the antibodies using the coupling reagents ethyl-3- carbodiimide and N-hydroxysuccinimide.

具体包括的内容如下： 1讨论了不同修饰剂及它们的组合对量子点表面进行修饰后，量子点光学性质的影响，发现对于最大激发波长为568 nm的量子点，应用巯基十一酸与巯基乙酸钠组合对其修饰后，得到的水溶性量子点保持了脂溶性量子点的优良光学性质，其量子点产率相对于其他修饰剂或组合也比较高。

In contrast to the previous work in which the ILs were used as solvents,[14,15,21] we observed that when this IL was used in a catalytic amount, the Knoevenagel condensation between ethyl cyanoacetate or malononitrile and carbonyl compounds (Scheme 1) could be performed with high efficiency.

和之前离子液体被用作溶剂的工作作为对比，[14，15，21]我们发现使用催化剂量的这种离子液体时，氰基乙酸乙酯或丙二腈和羰基化合物之间的Knoevenagel缩合(图示1)可以体现出高效率。

The basic functionalized ionic liquid, 1 -butyl-3-methylimidazolium hydroxide OH, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基－3-甲基咪唑，研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

The basic functionalized ionic liquid, 1-butyl-3-methylimidazolium hydroxide, was prepared and used to catalyze the Knoevenagel condensation of aromatic aldehydes with malononitrile or ethyl cyanoacetate.

合成了碱性功能化离子液体氢氧化1-丁基-3-甲基咪唑，研究了将其作为催化剂催化芳香醛和丙二氰、氰基乙酸乙酯的Knoevenagel缩合反应。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行，获得了很高的收率；而对于杂环芳醛、α，β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合，需在50~65℃下进行，也取得了很高的收率；对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行，获得中等以上的收率。

Was synthesized from cyanoacetic acid and diethylamine via DCC coupling under mild conditions.

中间体5 的制备由氰基乙酸在二环己基碳二亚胺作用下经酰胺化一步制得，条件温和，收率较高，避免使用剧毒的氰化钠。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。