乙酰甲基

Ingredients: Rose oil, rose fruit Oil, clove flower oil, deionized water, isopropyl myristate, glycerol, propylene glycol, polyethylene glycol -400, central PDMS, poly dimethyl siloxane, PDMS alcohol, polyacrylamide, C13-14 iso-paraffin, octoic acid / capric Acid Triglyceride, lauryl alcohol -7, hydroxyethyl acrylate, acryloyldimethyltaurate copolymer, squalane, poly sorbate esters -60, PEG-20 sorbitan laurate, panthenol, allantoin, methyl p-hydroxybenzoate, diazolidiny1 urea, 3-iodo-2-propynyl-butyl-carbamate, essence.

产品成分：玫瑰精油、玫瑰果油、丁香花油、去离子水、肉豆蔻酸异丙酯、甘油、丙二醇、聚乙二醇-400、环聚二甲基硅氧烷、聚二甲基硅氧烷、聚二甲基硅氧烷醇、聚丙烯酰胺、C13-14 异链烷烃、辛酸/癸酸甘油三酯、月桂醇醚-7、羟乙基丙烯酸酯、丙烯酰二甲基牛磺酸钠聚物、角鲨烷、聚山梨酸酯类-60、PEG-20 失水山梨醇月桂酸酯、泛醇、尿囊素、对羟基苯甲酸甲酯、双咪唑烷基脲、碘代丙炔基丁基甲氨酸酯、香精。

Methods 4-Hydroxybenzonitrile (2) as the starting material was transformed to 4-hydroxy-thiobenzamide (3) via thioformylation. And ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate (4), which was synthesized via cyclization from 3, was treated with hexamethylenetetramine to generate the intermediate ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate (5). The target compound febuxostat (1) was obtained from 5 by etherification, cyanidation, hydrolysis.

以羟基苯腈为原料，经硫代甲酰化得到对羟基硫代苯甲酰胺(3)，3经环合得到2-（4-羟基苯基）－4-甲基－噻唑－5-羧酸乙酯(4)，4与乌洛托品反应，得到中间体2-（3-甲酰基－4-羟基苯基）－4-甲基－噻唑－5-羧酸乙酯(5)，之后再经醚化、氰化、水解得到目标产物(1)。

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷，包括：γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3，4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3，4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

Products: 3 - benzoyl-ethyl acrylate (97% min), acyl phosphorus acid methyl ester (98% min), P acyl three ethyl acetate (98% min), a phosphorus acid acyl The ethyl esters (98% min), 3 - bromine -1,3,4,5 - tetrahydrocannabinol -2 H-1-benzo-Aza Zhuo -2, 1 - naphthalene-tetrahydrocannabinol (98% min), 3,5 - dimethyl benzoyl chloride (99% min), 3,5 - dichloro benzoyl chloride (97% min), the ethyl benzoyl chloride (99% min), a TCA Ester (99.5% min), o-benzoyl methyl benzene (99% min), 4 - phenyl benzophenone (99% min): glacial acetic acid (99% min), methanol (99% min), liquid chlorine (99.5% min), caustic soda (30% min), isopropyl alcohol (99% min), anthranilic acid (99% min), dichloroethane (99% min ), Chunben (99% min), toluene 99% min

3-苯甲酰基丙烯酸乙酯（97%min）、磷酰基乙酸三甲酯（98%min）、磷酰基乙酸三乙酯（98%min）、磷酰基乙酸甲酯二乙酯（98%min）、3-溴-1，3，4，5-四氢-2H-1-苯并氮杂卓-2酮、1-四氢萘酮（98%min）、3，5-二甲基苯甲酰氯（99%min）、3，5-二氯苯甲酰氯（97%min）、对乙基苯甲酰氯（99%min）、氯乙酸甲酯（99.5%min）、邻苯甲酰基苯甲酸甲酯（99%min）、4-苯基二苯甲酮

Methacryloyloxydecyl-2-thiouracil-5-carboxylate was synthesized from the reaction of thiouracil with diethyl ethoxymethylene malonate and ω-hydroxy-decyl-methacrylate.

以硫脲、乙氧基次甲基丙二酸二乙酯和甲基丙烯酸ω-羟癸酯为主要原料合成了一种新的粘接性单体10-甲基丙烯酰氧癸基－2-硫脲嘧啶－5-羧酸酯。

Spiral Spirobifluorene acetylated is oxidated by m-chloroperoxybenzoic acid and hydrolyzed by sodium hydroxide ,obtaining 2,2 '- dihydroxy -9,9'- spiral Spirobifluorene .Through nitrification,Reduced by hydrazine hydrate, we may get the 2,2 '- diamino -9,9'- spiral Spirobifluorene which are characterizated by IR, 1H-NMR !

L-酒石酸和乙醇酯化得到酒石酸二乙酯，将保护羧基保护起来，然后用碘甲烷在2，3-位上两个甲基，得到2，3-二甲氧基-酒石酸二乙酯，再用氢氧化钠将其水解，得到2，3-二甲氧基-酒石酸，用五氯化磷将羧基酰化，得到2，3-二甲氧基- 1，4-丁二酰氯，经过与二环己胺反应，得到拆分配体2，3-二甲氧基–N，N，N'，N'-四环己丁二酰胺。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

Methyl 6-acylnaphthalene from 2-methylnaphthalene was synthesized via acylation using acetic anhydride and propionyl chloride as the acylating agents with catalyst aluminum trichloride in homogeneous liquid phase system.

为制备重要的化合物2-甲基6-酰基萘，提高酰化产物的收率和纯度，以2-甲基萘为原料，分别研究了乙酸酐和丙酰氯为酰化剂时的酰化反应，对酰化反应的产物进行了GC、FT-IR和GC-MS表征；对酰化反应的影响因素进行了研究。

To study the relationship between the "tail" structure and the characteristics of Gemini surfactants, a new gemini surfactant CH(subscript 2s)-αω-Bis (dehydroabietyihydroxypropyltetramethylethyldiammonium Chloride) here s=2, has been synthesized. Dehydrogenated rosin as hydrophobic "tails" in the structure. The affections of reacttants ratio, reaction temperature and time on the yield of aimed compound have been discussed.

研究了Gemini表面活性剂中疏水&尾巴&结构对性质的影响，以脱氢松香酸和环氧氯丙烷为原料合成了中间体3-脱氢松香酰氧－2-羟丙基氯，再与四甲基乙二胺反应，得到1种以脱氢松香酰基为疏水链&尾巴&的对称Gemini型双季铵盐阳离子表面活性剂：二氯化－N，N'-二（3-脱氢松香酰氧－2-羟丙基）四甲基乙二胺。

To study the relationship between the hydrophobic "tail" structure and thecharacterizations of Gemini surfactants, a new gemini surfactant CsH2s-α,ω-bis(dehydroabietylhydroxypropylteteramethylethylammonium Chloride),here s=2, wassynthesized. Dehydrogenated rosin as hydrophobic "tails" in the structure. The impact factorsin the two steps are discussed.

为研究gemini表面活性剂中疏水&尾巴&结构对性质的影响，本论文以脱氢松香酸和环氧氯丙烷为原料合成了中间体3-脱氢松香酰氧-2-羟丙基氯，再与四甲基乙二胺反应，得到一种以脱氢松香酰基为疏水链&尾巴&的对称gemini型双季铵盐阳离子表面活性剂：二氯化-N，N′-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。