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乙酰甲基

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The hydrogen bonding of 1:1 complexes formed between acetamide and three kinds of isomers of picolines have been completely investigated using B3LYP method at various basis set levels from 6-31G to 6-31+G and 6-31++G. The results show that the interaction energies of hydrogen bond complexes between acetamide and picoline isomers have great effects on the values of h_.

2采用密度泛函理论等方法研究了乙酰胺分子分别与甲基吡啶三种异构体分子以1:1的比例形成的氢键络合物,从B3LYP/6-31G到6-31++G基组水平进行了优化,利用结合能数据讨论了焓对作用系数的差异。

The synthesis of nalbuphine hydrochloride from thebaine as starting material was through following processes:oxidation,high-pressure hydrogenation,acetylation,removing methyl of 3-methoxy,hydrolysis,condensation,reduction and finial salification.

以蒂巴因为起始原料,经氧化、高压氢化、乙酰化、氰化、脱3-位甲氧基的甲基、水解、缩合、还原、成盐,合成了盐酸纳布啡,总收率达18。

The model system confirmed the presence of 2-acetyl thiazole and 5, 6-perhydro-2, 4, 6-trimethyl-1, 3, 5-dithiazine in the odor of prawn as there were a large amount of acetaldehyde and H〓S present.

本文以模拟体系证明两类对虾挥发性组分中的2-乙酰基噻唑和5.6-二氢2.4.6-三甲基,1.3.5-二噻嗪的存在,对于该化合物产生的途径以及其质谱裂解规律进行了探讨。

Permethylation analysis, periodate oxidation,Smith degradation, acetolysis and partial acid bydrolysis revealed the main chains of XP as mannose of (1-6)-linkages and its side chains were mannose of (1-2)linkages.

甲基化分析、过碘酸盐氧化、Smith降解、乙酰解和部分酸水解显示XP的主链是1→6连接的甘露糖,侧链是1→2连接的甘露糖。1H及13CNMR谱表明所有糖苷键均为a型,结合元素分析XP基本是酵母甘露多糖和蛋白质以及锌的络合物。

These new ionic liquid-supported acetylacetone catalysts were used for the oxidation of the intermediates of Vitamin E (2,3,5-trimethylphenol and 3,5,5-trimethylcyclohex-3-en-l-one). It not only checked the rationality of the design, but also established the base for the green oxidation of corresponding reactions.

论文进一步将此类离子液体支载乙酰丙酮金属催化剂应用于维生素E中间体三甲基苯酚和β—异佛尔酮的氧化过程,一方面检验了催化剂设计过程及结果的可靠性,另一方面为相关氧化反应的绿色化改造提供相关的基础。

Polyimide/nano carborundum composite films were made from pyromellitic dianhydride、4, 4'-aminodiphenyl ether、N, N'-dimethyl acetamide and nanometer carborundum.

以均苯四甲酸二酐、4,4'-二氨基二苯醚、N,N'-二甲基乙酰胺为原料,经化学合成反应制备了聚酰亚胺/纳米碳化硅复合薄膜。

AIM: To determine the distribution and frequency of functionally important allelic variants in the cytochromes P450 2C19, arylamine N-acetyltransferase 2 (NAT2), and thiopurine S-methyltransferase genes in the Han Chinese population and compare them with those of other ethnic populations.

目的: 了解细胞色素P450(cytochromes P450,CYP)2C19,N-乙酰基转移酶2(arylamine N-acetyltransferase 2,NAT2)和硫嘌呤甲基转移酶(thiopurine S-methyltransferase,TPMT)基因常见的遗传多态性在河南地区汉族人群中的分布及其频率。

Thermodynamic properties of PSf - DMAc - alcohols ternary systems are studied, the binodal is calculated. Cloud point curves from light scattering experiment verify the calculation results; The agreement between the cloud point curves and the binodal is quite well.

文章摘要:对聚砜-二甲基乙酰胺-醇类非溶剂构成的制膜体系的热力学特性进行了研究,计算出这些体系的双结点线,并用这些醇类非溶剂通过光散射法进行浊点滴定实验,浊点曲线与双结点线基本重合,验证了双结点线的计算结果。

Discussion on membrane formation mechanismBased on the Flory-Huggins theory, Phase equilibrium equations of PVDF/DMAc/water ternary system were wrote out, and the binodal and spinodal lines in the phase diagrams of the system were obtained via numerical calculation. Combined the kinetic description and the thermodynamic phase diagram, membrane formation process were analyzed, which prepared the theoretical foundation for the further membrane formation mechanism research.

论文主要从如下四个方面展开:(1)PVDF疏水膜成膜分相机理探讨基于Flory-Huggins理论推导了三元制膜体系凝胶分相组成的线性表达式,并通过&浊点法&测定了PVDF/N,N-二甲基乙酰胺/水/成膜体系的凝胶边界线组成,通过对实验数据的拟合,得到了简捷直观的线性表达式,ln(φ_1)/(φ_3)=bln(φ_2)/(φ_3)+a,误差小于3%。

The structure of products was characterized by means of infrared spectra, wide-angle X-ray diffraction and differential scanning caloriimetry and the effect of deacetylation in course of konjac glucomannan carboxy methylation was analyzed.

运用红外光谱、广角X-射线衍射和示差扫描量热法表征产物结构并探讨脱乙酰基对KGM羧甲基改性的影响。

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And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47:5 法老对约瑟说,你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法,同时,采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。

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