乙酰氯

Tebufenpyrad, a new high effective pyrazoleamide acaricide , was synthesized from 1-methyl-3-ethyl-4-chloro-5-pyrazolecarbon acid and 4-t-butylbenzylamine, the raw material are propionyl pyruvic ethyl ester and 4-t-butyl benzylchloride.

吡螨胺是一种新型、高效的吡唑酰胺类杀螨剂，本文以中间体1-甲基-3-乙基-4-氯-5-吡唑甲酸和4-叔丁基苄胺合成，起始原料丙酰丙酮酸乙酯和4-叔丁基苄氯，总收率为61.23%。

The results indicate that the optimized sulfonylation reaction time is 4 h, the materiel rate of chlorosulfonic acid and 2-chloroimidazo[1,2-α]pyridine is 1.2 : 1, with ethylamine the yield increasing from 15.4% to above 70%; the optimized ammonolysis reaction time is 3 h and the reaction temperature is 27℃, with the acetonitrile yield increasing from 60.1% to above 79.6%.

实验结果表明，磺酰化反应的最佳反应时间为4 h，氯磺酸与2-氯咪唑并[1，-α]吡啶的用量比为1.2：1，加入三乙胺可将收率由15.4%提高到70%以上；氨解反应的最佳反应时间为3 h，反应温度为27 ℃，加入乙腈可将收率由60.1%提高到79.6%；方案经改进后，总反应时间缩短3 h，收率提高了5.5%。

Water,Hydrogenated Polyisobutene,Cyclohexasiloxane,Glycerin,Alcohol Denat,Cetearyl Alcohol,PEG-20,Petrolatum,C13-14 Isoparaffin,Zea Mays Oil,Tocopheryl Acetate,Hydroxypropyl Tetrahydropyrantriol,Hydrolyzed Soy Protein,CI 14700/Red 4,Phenoxyethanol,Adenosine,PEG-100 Stearate,Ethylparaben,Triethanolamine,Polyacrylamide,Malus Domestica Stem Cell Culture,CI 19140/Yellow 5,Dimethyl Isosorbide,Dimethicone,Dimethiconol,Limonene,Xanthan Gum,Pentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate,Linalool,2-Oleamido-1,3-Octadecanediol,Capryloyl Salicylic Acid,Acrylates/C10-30 Alkyl Acrylate Crosspolymer,Passiflora Edulis Seed Oil,Disodium EDTA,Castanea Sativa Seed Extract,Butyrospermum Parkii· Cetyl Alcohol,Butylene Glycol,Octyldodecanol,Cetearyl Glucoside,Methylparaben,Citronellol,Prunus Armeniaca Kernel Oil,Laureth-7,Coumarin,Oryza Sativa Bran Oil,Glyceryl Stearate,Fragrance

水，甘油，氢化聚异丁烯，液体石蜡/矿油，丁二醇，环己硅氧烷，鲸蜡醇，甘油硬脂酸酯，棕榈油，玉米胚芽油，PEG-100硬脂酸酯，白蜂蜡/蜂蜡，肉豆蔻醇肉豆蔻酸酯，石蜡，香精，腺苷，苧烯，山梨醇，CI 14700，CI 19140，稻糠油，杏仁油，EDTA二钠，羟丙基四氢吡喃三醇，苯氧乙醇，聚乙二醇-14M，异十六烷，氢氧化钠，辛基十二醇，季戊四醇四（双-t-丁基羟基氢化肉桂酸）酯，山梨坦三硬脂酸酯，水解大豆蛋白，卡波姆，鸡蛋果籽油，苹果果实提取物，欧洲栗籽提取物，异山梨醇酐二甲醚，聚山梨醇酯-80，辛酰水杨酸，2-油酰胺基-1，3-十八烷二醇，氯苯甘醚，麦芽糖醇，香豆素，黄原胶，微晶蜡，丙烯酰胺/丙烯酰基二甲基牛磺酸钠共聚物，丙二醇，芳樟醇，香茅醇，玉米油，羟苯丙酯，羟苯甲酯

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明，磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应，可以在颗粒表面引入少量羧基；磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应，可以在颗粒表面接枝不同分子链长度的末端羟基；磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基；磁性聚丙烯酸甲酯颗粒通过乙二胺或1，6己二胺的胺解反应可以得到表面氨基，继而与一氯乙酸反应可以引入亚胺二乙酸基团。

Amino-6-methoxy Benzothiazole 99%、2-Amino Benzothiazole 99%、Veratraldehyde 99%、Veratric Acid 99%、1,2- Dimethoxy Benzene 99%、6-Nitroveratric Acid 97%、2,5-Dichlorobenzoic Acid 99%、4-Chloro-3-Nitrobenzoic Acid 99%、 3-Nitrobenzole Acid 98%、p-Methoxybenzoie Acid 99%、Anisole 99.5%、p-Methoxyacetophenonc 99%、(2'-Chloroethyl) Benzene 99%、(2'-Bromoethyl) Benzene 99%、N,N-Diethyi-m-Toiuamide 99%、Aminoacetonitrile Hydrochloride 98%、 Alkyl Diphenyl Phosphate Estrel 98%、5-Chloro-2-benzothiazolone 99%、6-bromo-2-naphthol 98%、6-Nitro-Veretric Acid Estrel 97%、4-chloro phenoxyaeetic 99

2-氨基-6-甲氧基苯骈噻唑、2-氨基苯骈噻唑、藜芦醛、藜芦酸、藜芦醚、6-硝基藜芦酸、2，5-二氯苯甲酸、3-硝基-4-氯苯甲酸、3-硝基苯甲酸、对甲氧基苯甲酸、苯甲醚、对甲氧基苯乙酮、β-氯代苯乙烷、β-溴代苯乙烷、N，N-二乙基间甲苯甲酰胺、氨基乙腈盐酸盐、磷酸二苯月桂酯、5-氯-2-苯骈噻唑酮、6-溴-2-萘酚、6-硝基藜芦酸甲酯、4-氯苯氧乙酸

Purified water, euphorbia cerifera wax, glyceryl stearate, ammonium acrylates copolymer, butylene glycol, copernica cerifera wax, stearic acid, sucrose acetate isobutyrate, acrylates copolymer, bentonite, tromethamine, hexylene glycol, silk amino acids, cholesterol, glycine, synthetic wax, ethylhexyl glycerin, alanine, PEG-9 dimethicone, nylon-6, lecithin, silica, simethicone, caprylyl glycol, xanthan gum, propylene glycol, isostearic acid, sodium laureth-12 slfate, ceteareth-20, polyvinyl alcohol, sodium chloride, sodium acetate, disodium EDTA, benzyl alcohol, chlorphenesin, phenoxyethanol, methylparaben, ethylparaben, propylparaben, butylparaben, isobutylparaben, may contain /- mica, iron oxides (CI 77491, CI 77492, CI 77499), titanium dioxide (CI 77891), ferric ferrocyanide (CI 77150), ultramarines (CI 77007), blue 1 lake (CI 42090), bronze powder (CI 77400), aluminum powder (CI 77000), bismuth oxychloride (CI 77163), carmine (CI 75740), chromium hydroxide green (CI 77289), chromium oxide greens (CI 77288), yellow 5 lake CI 19140

水，小烛树蜡，硬脂酸甘油酯，丙烯酸铵共聚物，1，3-丁二醇，巴西棕榈蜡，硬脂酸，异丁酸醋酸蔗糖酯，丙烯酸酯共聚物，蒙脱土，二吡喃乙酸乙酯胺，已烯醇，丝氨酸，胆固醇，甘油，合成蜡，异丁基甘油，丙胺酸，PEG-9二甲基硅油，尼龙-6，卵磷酯，硅粉，硅氧烷，癸酰基乙二醇，汉生胶，丙二醇，异硬脂酸，月桂基醚-12硫酸钠，十六十八醇醚-20，聚乙烯醇，氯化钠，醋酸钠，EDTA二钠，苯氧乙醇，氯代苯酚，卞醇，尼泊金甲酯，尼泊金乙酯，尼泊金丙酯，尼泊金丁酯，尼泊金异丁酯，[可能还含有云母，铁黑(CI 77491， CI 77492， CI 77499)，钛白粉(CI 77891)，氰化亚铁(CI 77150)，靛蓝(CI 77007)，蓝1号(CI 42090)，青铜粉(CI 77400)，铝粉(CI 77000)，氯氧化铋(CI 77163)，洋红色素(CI 75740)，氢氧化铬绿(CI 77289)，氧化铬绿(CI 77288)，黄5号(CI 19140)]文章来自网络，不代表本网站立场，版权归原作者所有，转载请注明出处！

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

A GC headspace injection method for the determination of residual organic solvents such as methanol, ethanol, acetonitrile, dichloromethane, ethylacetate, 4 methyl 2 pentanone, toluene, DMF, chloroform and tetrahydrofuran in tazobactam was established.

建立了气相色谱顶空进样法测定三唑巴坦中甲醇、乙醇、乙腈、二氯甲烷、乙酸乙酯、甲基异丁基酮、甲苯、N ，N′-二甲基甲酰胺、氯仿和四氢呋喃等有机溶剂的残留量。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料，设计合成了六个三脚架结构的化合物，其合成路线如下：三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1)，然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3)，然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

To study the relationship between the hydrophobic "tail" structure and thecharacterizations of Gemini surfactants, a new gemini surfactant CsH2s-α,ω-bis(dehydroabietylhydroxypropylteteramethylethylammonium Chloride),here s=2, wassynthesized. Dehydrogenated rosin as hydrophobic "tails" in the structure. The impact factorsin the two steps are discussed.

为研究gemini表面活性剂中疏水&尾巴&结构对性质的影响，本论文以脱氢松香酸和环氧氯丙烷为原料合成了中间体3-脱氢松香酰氧-2-羟丙基氯，再与四甲基乙二胺反应，得到一种以脱氢松香酰基为疏水链&尾巴&的对称gemini型双季铵盐阳离子表面活性剂：二氯化-N，N′-二(3-脱氢松香酰氧-2-羟丙基)四甲基乙二胺。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。