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乙酰基

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Rosolic acid reacted with acetic anhydride to synthesize rosolic acid -triacelate ester [tri(4-acetoxy) phenyl methane] under reflux condition.

以玫红酸、醋酸酐为原料,采用加热回流法合成了玫红酸三乙酸酯[三(4-乙酰氧基)苯基甲烷]。

The ligand of the chiral Schiff base and acetylacetone vanadium are subjected to complexation in situ, hydrogen peroxide is taken as an oxidant, aryl alkyl thioether asymmetric oxidation reaction is catalyzed in a toluene or dichloromethane solution under low temperature or room temperature, enantioselectivity of chiral sulphoxide is 72 percent to 95 percent ee, and yield is 42 percent to 83 percent.

将上述手性西佛碱配体与乙酰丙酮氧钒原位络合,采用双氧水为氧化剂,在甲苯或二氯甲烷溶液中低温至室温下催化芳基烷基硫醚不对称氧化反应,手性亚砜的对映选择性为72%-95%ee,产率为42%-83%。

A series of ABEPS were synthesized from long chain fatty acids, benzene, polyglycol and 1, 3-propane sultone by the procedure of Friedel-Crafts acylation, Huang-Minlon reduction, Williamson and sulfonation reaction, and these compounds had never been reported in the past time.

以长链羧酸、苯、多缩乙二醇和丙烷磺内酯为初始原料,依次经Friedel-Crafts酰基化反应、Huang-Minlon还原、Blank反应、Williamson成醚以及磺化反应等过程,合成了系列未见报道的ABEPS。

Here, we show that human HSF1 is inducibly acetylated at a critical residue that negatively regulates DNA binding activity.

在本文中,我们讲述了人类热休克因子1负性调节DNA结合活性的重要残基被诱导乙酰化的过程。

Such changes in thiols by allyl sulfurs may also account for the observed hyperphosphorylation of specific cell cycle proteins and the histone hyperacetylation that has been correlated with suppressed tumor cell proliferation.

这些烯丙基硫化物引起的硫醇的改变同时也可以使特异性细胞周期蛋白过磷酸化及组蛋白过乙酰化,从而抑制肿瘤细胞增殖。

The alkylation of a-methylene of PhSO2CH2COPh with alkyl halides catalyzed by quaternary ammonium base resin in 50% aqueous sodium hydroxide solution was investigated.

本文以季铵碱树脂作为聚合物固载的相转移催化剂,在50%氢氧化钠水溶液中催化α-苯磺酰基苯乙酮(1)的α-亚甲基的烷基化反应。

The main by-product s and their separation and recovery technologies were discussed for cyclohexanone gas-phase Beckmann rearrangement.

探讨环己酮肟气相Beckmann重排主要副产物及其分离回收方法,研究1-氮杂-2-乙氧基-1-环庚烯、1,3,4,5-四氧吖庚因-2-酮及其同分异十句体等副产物回收利用生成已内酰胺的方法。

However, relatively lower column utilization limits its application to the complex proteome isolation. In case of binding biotin molecules to a specific kind of functional groups existed in protein structure, and flowing the digested peptides over the affinity column in which avidin has been immobilized, biotinylated peptides can be selectively separated and the complicated system is simplified.

因此根据需要,变换生物素试剂与蛋白质反应的作用位点,就可以选择性地分离出不同的目标肽段,从而大大提高亲和色谱柱的使用效率,降低亲和分离的成本;结合乙酰化同位素标记技术,还可以建立多种针对不同目标肽段的特色定量分析方法,ICAT即是将同位素标记与蛋白质巯基生物素化亲和分离成功结合的一个范例。

From the investigation into the visible spectra and performances on textile of these azo dyes, as acid dye, it was found that these dyes had deep coloring effects on dyeing wool or silk, and five of which could dye wool into black one at 3% o. w. f., especially the diazo dye derived from 2, 8-diamino-10-methoxy-5, 10-dihydrophenophosphazine 10-oxide and acet-J-acid, it could not only dye wool into black one but each fastness of the obtained dyed sample was good.

对这些已知结构的染料进行浸染染色,结果发现,它们作为酸性染料,在羊毛及丝绸纤维上染色时,能够获得比一般偶氮染料不宜获得的深色效应,其中5支染料得到黑色染样,尤其由2,8-二氨基-10-甲氧基-5,10-二氢磷杂吖嗪与乙酰J-酸形成的双偶氮染料得到黑色染样,其各项牢度都比较理想。

In this thermodynamic study, the minimum requirements in molar fraction of the solvents (x3) on the azeotropic feed plate are: 0.20 for N,N-dimethylformamide, 0.36 for 2-ethoxyethanol, 0.40 for 1-pentanol and 0.66 for butyl propionate,.

在这个热力学研究中,共沸混合物喂料盘上各溶剂摩尔分数最小值(x3)分别是:N,N-二甲基甲酰胺:0.20;2-乙氧基乙醇:0.36;1-戊醇:0.40;丙酸丁酯:0.66。

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However, as the name(read-only memory)implies, CD disks cannot be written onorchanged in any way.

然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

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